Performance characteristics of lithium-ion cells for NASA's Mars2001 Lander application

NASA requires lightweight rechargeable batteries for future missions to Mars and the outer planets that are capable of operating over a wide range of temperatures, with high specific energy and energy densities. Due to the attractive performance characteristics, lithium-ion batteries have been identified as the battery chemistry of choice for a number of future applications, including Mars rovers and landers. The Mars 2001 Lander (Mars Surveyor Program MSP 01) will be one of the first missions which will utilize lithium-ion technology. This application will require two lithium-ion batteries, each being 28 V (eight cells), 25 Ah and 8 kg. In addition to the requirement of being able to supply at least 200 cycles and 90 days of operation on the surface of Mars, the battery must be capable of operation (both charge and discharge) at temperatures as low as -20°C. To assess the viability of lithium-ion cells for these applications, a number of performance characterization tests have been performed, including: assessing the room temperature cycle life, low temperature cycle life (-20°C), rate capability as a function of temperature, pulse capability, self-discharge and storage characteristics, as well as mission profile capability. This paper describes the Mars 2001 Lander mission battery requirements and contains results of the cell testing conducted to-date in support of the mission,     

Aerospace lithium solid polymer batteries

Lockheed Martin Missiles and Space and Ultralife Batteries, Inc. are developing batteries for spacecraft and launchers based on Li-ion solid-polymer-electrolyte cell technology. These cells utilize a carbon anode, a manganese dioxide cathode and a solid polymer electrolyte. Electrode and electrolyte layers are thin and flexible. The electrode assembly is easily fabricated into thin, flat prismatic shapes using ordinary lamination techniques and is hermetically sealed in thin foil packaging. Cells ranging in capacity from 4 Ah to 50 Ah have been designed and are in development testing. The packaged cells have specific energies in excess of 100 Wh/kg. Prototype 30 volt batteries have also been designed and are being assembled and tested along with the critical battery cell charge management controllers needed to recharge all cells to full capacity while preventing overvoltage damage. The major results of this development effort are reviewed and the key issues for advancing this technology to flight qualification demonstrations are discussed     

Hubble performance on-orbit

A summary of the Hubble Space Telescope (HST) nickel-hydrogen (NiH/sub 2/) battery performance from launch to the present. Over the life of HST vehicle configuration, charge system degradation and failures, together with thermal design limitations, have had a significant effect on the capacity of HST batteries. Changes made to the charge system configuration to protect against power system failures and to maintain battery thermal stability resulted in undercharging of the batteries. This undercharging resulted in decreased usable battery capacity as well as battery cell voltage/capacity divergence. This cell divergence was made evident during on-orbit battery capacity measurements by a relatively shallow slope of the discharge curve following the discharge knee. Early efforts to improve battery performance have been successful. On-orbit capacity measurement data indicates increases in the usable battery capacity of all six batteries as well as improvements in the battery cell voltage/capacity divergence. Additional measures have been implemented to improve battery performance, however, failures within the HST Power Control Unit (PCU) have prevented verification of battery status.     

Advanced lithium ion battery charger

A lithium ion battery charger has been developed for four and eight cell batteries or multiples thereof. This charger has the advantage over those using commercial lithium ion charging chips in that the individual cells are allowed to be taper charged at their upper charging voltage rather than be cutoff when all cells of the string have reached the upper charging voltage limit. Since 30-60% of the capacity of lithium ion cells may be restored during the taper charge, this charger has a distinct benefit of fully charging lithium ion batteries by restoring all of the available capacity to all of its cells     

Hubble Space Telescope at twelve years of age

The Hubble Space Telescope was deployed from the Space Shuttle Discovery into a 380-mile high Earth orbit on April 25, 1990. It subsequently made outstanding astronomical discoveries with its 8-foot (2.4-meter) telescope and other scientific instruments. Critical to the successful observations was continuous availability of power from its solar arrays during sunlit periods, and from nickel-hydrogen batteries when the satellite was in the Earth's shadow. The adopted nickel-hydrogen batteries were carefully selected and tested to confirm their depth-of-discharge and operating temperature that delivered the longest life in charge/discharge cycling service. These batteries had a design life of 7 years. At 12 years after launch the Hubble batteries have delivered more charge/discharge cycles than any other batteries in low-Earth orbit. However, the Hubble batteries have been subjected to many unexpected stresses, and peculiar reductions in battery capacity have been observed. Battery replacement requires a costly trip to the Hubble Space Telescope by astronauts, so the remaining useful life of the batteries must be predicted. Already in four servicing missions, astronauts have replaced or modified optics, solar arrays, a power control unit, and various science packages. A fifth servicing mission is scheduled in 2004. This paper discusses battery charging hardware and software controls, history of battery events in Hubble, cell performance model and spare battery tests, and capacity walkdown.     

A microcontroller-based intelligent battery system

State-of-charge indication for a secondary battery is becoming increasingly important for battery-operated electronics. Consumers are demanding fast charging times, increased battery lifetime, and fuel gauge capabilities. All of these demands require that the state of charge within a battery be known. One of the simplest methods employed to determine state of charge is to monitor the voltage of the battery. However, this method alone is not a good indicator of battery energy, since both NiMH and NiCd batteries have voltage-versus-energy curves that are essentially flat. This paper presents a more effective method of determining the state of charge in secondary cell batteries. A NiMH battery is used as our test vehicle, since it is one of the more difficult batteries to determine state of charge. This method monitors the battery's temperature, voltage, and discharge/charge rate. A microcontroller then manipulates the information, using look-up tables to determine the state of charge. Also, by modifying the look-up tables, this technique can be employed in many other battery technologies and is not limited to NiMH     

Thin-film Li-LiMn2O4 batteries

Thin-film rechargeable Li-LiMn₂O₄ batteries have been fabricated and characterized. Following deposition by electron beam evaporation of LiMn₂O₄, the amorphous as-deposited cathode films 1 cm² in area by 0.3to 4-μm thick were annealed at 700°C to 800°C in oxygen in order to form the crystalline spinet phase. The specific capacity of the cells between 4.5 V to 3.8 V ranged from 50 μAh/mg to 120 μAh/mg. When cycled over this range, the batteries exhibited excellent secondary performance with capacity losses as low as 0.001% per cycle. On charging to 5.3 V, a plateau with a median voltage of 5.1 V was observed. The total charge extracted between 3.8 V to 5.3 V corresponded to about 1 Li/Mn₂ O₄     

蒸发循环系统制冷剂量对系统性能影响的试验分析

制冷系统性能与制冷工质充注量的多少密切相关,随时间的推移,制冷剂多少总会泄漏,系统制冷剂总量会减少,性能会降低。制冷剂的减少会导致压缩机转速加快,制冷剂冷凝压力降低、蒸发温度升高、过热量加大。     

Global avionics in the future

The following topics are discussed: new batteries for old airplanes; new charge controls for lengthening battery life; fast methods for batteries charging; AC conductance measurement based battery testing; pulse power; bipolar lead-acid batteries vs supercapacitors; Ni electrode cells for spacecraft; worn-out battery disposal; recycling technology; vehicle batteries cost; high energy content batteries; and energy storage for electric utilities     

Need and effect of reconditioning of nickel/hydrogen batteries

There has been a debate about the need for reconditioning nickel/hydrogen batteries in geosynchronous satellites. A study was done as part of life cycling, to determine the necessity of reconditioning and its effect on the cell performance. A 36 Ah nickel/hydrogen cell was put on a GEO simulated cycling at 15°C without reconditioning up to four eclipse seasons. The effect of reconditioning on the fifth and sixth eclipse seasons was studied. The study has conclusively proven the need for reconditioning and has shown the benefits of a high rate reconditioning. It has also been possible to draw some conclusions about the effect of a long duration trickle charge on the positive electrode     

Charge equalization for series-connected batteries

A novel nondissipative charge equalization circuit is proposed for charge equalization control of series-connected batteries. Each battery associates with a subcircuit, which is essentially a buck-boost converter acting as a current diverter to redistribute the excessive energy from more affluent batteries to the hungry ones. By dynamically redistributing the charging current, charge equalization can be achieved more quickly and efficiently. The applicability of this approach is confirmed by experiments.     

Electric-vehicle batteries

Electric vehicles that can't reach trolley wires need batteries. In the early 1900's electric cars disappeared when owners found that replacing the car's worn-out lead-acid battery costs more than a new gasoline-powered car. Most of today's electric cars are still propelled by lead-acid batteries. General Motors in their prototype Impact, for example, used starting-lighting-ignition batteries, which deliver lots of power for demonstrations, but have a life of less than 100 deep discharges. Now promising alternative technology has challenged the world-wide lead miners, refiners, and battery makers into forming a consortium that sponsors research into making better lead-acid batteries. Horizon's new bipolar battery delivered 50 watt-hours per kg (Wh/kg), compared with 20 for ordinary transport-vehicle batteries. The alternatives are delivering from 80 Wh/kg (nickel-metal hydride) up to 200 Wh/kg (zinc-bromine). A Fiat Panda traveled 260 km on a single charge of its zinc-bromine battery. A German 3.5-ton postal truck traveled 300 km with a single charge in its 650-kg (146 Wh/kg) zinc-air battery. Its top speed was 110 km per hour     

Fast equalization for large lithium ion batteries

Slight differences between the series connected cells in a lithium ion (Lilon) battery pack can produce imbalances in the cell voltages, and this greatly reduces the charge capacity. These batteries cannot be trickle-charged like a lead acid battery since this would slightly overcharge some cells and may cause these cells to ignite. Therefore, an electronic equalizer (EQU) should be used to balance the cell voltages individually. The targeted EQU described herein can be connected to any cell via a set of sealed relays to provide much faster equalization and higher efficiency than previous methods.     

US Army small fuel cell development program

This presentation includes results of fuel cell research activities sponsored by the US Army for the last three years, It outlines current efforts and future plans. The soldier's increasing power demands dictate that alternatives to batteries be exploited wherever possible. Fuel cells promise significant advantages in terms of weight, coupled with cost and/or logistics benefits. Considerable progress has been made in reducing size and weight of proton exchange membrane (PEM) fuel cells. The supply of hydrogen to PEM fuel cells has been one of the key barriers to introducing fuel cells to the military. The discussion will focus on several approaches being pursued     

Advanced lithium ion solid polymer electrolyte battery development

Lockheed Martin Missiles & Space (LMMS), Ultralife Batteries, Inc. (UBI), Eagle Picher Technologies, LLC (EPT), Sandia National Laboratories (SNL) and Rentech, Inc. (RTI) are developing lithium ion solid polymer electrolyte (Li-ion SPE) batteries. Under a new Advanced Technology Program (ATP), this team will develop new high-energy density cells and batteries for space and portable electronics applications. These new batteries will utilize new high-energy density anode and cathode active materials developed by SNL and RTI. UBI will incorporate these new materials into an optimized Li-ion SPE electrode laminate. EPT will develop batteries for aerospace applications based on this electrode laminate technology while LMMS will design the battery charge management controller and provide system expertise     

Perspective on ultracapacitors for electric vehicles

Recent advances in performance of chemical double layer capacitors (DLC) with aqueous and non-aqueous electrolytes have made it possible to seriously consider them for commercialization. Non-aqueous (organic) carbon based laboratory monopolar devices have recently met key U.S. Department of Energy (DoE) mid-term specifications (> 5 WNkg, >500 W/kg and >100,000 life cycles) for load-leveling electric vehicles batteries. All DLC technologies currently under development by DoE are discussed. Each technology has distinct advantages and none are clear winners at this time. A study has been completed by the General Electric Company on the interface electronics needed to best utilize the energy of capacitors for load-leveling batteries. System costs are presented based on this study, several battery technologies, and capacitor projections     

Portable power source needs of the future Army-batteries and fuelcells

This paper describes the US Army's future needs for silent portable power in the area of batteries and fuel cells. These needs will continue to increase as a result of the introduction of newer types of equipment, the increasing digitization of the battlefield, and future integrated Soldier Systems. Current battery programs are aimed at improved, low-cost primary batteries, and rechargeable batteries with increased energy densities. The Army fuel cell program aimed at portable systems capable of the order of 150 W is also described     

Losses for Frequency Diversity Waveform Systems

The use of a frequency diversity waveform to improve target detectability by reducing the fluctuation loss is a well-established technique. The diversity gain is commonly computed under the assumptions of a matched filter processor and the independent fluctuation of the target from channel to channel. Sometimes these conditions are not met and the full diversity gain cannot be obtained. In order to accurately compute the attainable diversity gain, it is necessary to calculate losses that occur only for diversity waveforms. The losses that have been considered are 1) unknown target velocity loss, 2) dependent samples due to small channel-to-channel frequency spacing, 3) linear envelope detector law loss, and 4) constant false alarm rate (CFAR) lpss.     

Advanced materials for next generation NiMH portable, HEV and EVbatteries

While Ovonic NiMH batteries are already in high volume commercial production for portable applications, advances in materials technology have enabled performance improvements in specific energy (100 Wh/kg), specific power (600-1000 W/kg), high temperature operation, charge retention, and voltage stability. Concurrent with technology advances, Ovonic NiMH batteries have established performance and commercial milestones in electric vehicles, hybrid electric vehicles, as well as scooter, motorcycle and bicycle applications. As important as these advances, significant manufacturing cost reductions have also occurred which allow continued growth of NiMH technology. In this paper, advances in performance, applications and cost reduction are discussed with particular emphasis on the improved proprietary metal hydride and nickel hydroxide materials that make such advances possible     

Aerospace and military battery applications

This paper gives a review of the papers presented at the IEEE 17th Annual Battery Conference on Applications and Advances, Long Beach, CA, USA, 2002. The topics covered are: Li batteries for satellites, capacity fade of Li-ion cells cycled at different temperatures, Ni-H/sub 2/ battery lifetime, batteries for Mars-exploring vehicles, Li-ion cell performance enhancement at low temperatures, navy service batteries, and US Army man portable applications and mobile power challenges.