Quenched Carbonaceous Composite: a laboratory analog for carbonaceous material in the interstellar medium.

We review the properties of Quenched Carbonaceous Composite (QCC), a residue produced from a hydrocarbon plasma, and the properties of its derivatives. A. Sakata and his colleagues have shown that QCC has a 220 nm absorption band, visible fluorescence matching the extended red emission seen in reflection nebulae, and infrared absorption bands that correspond to the infrared emission features in reflection nebulae, HII regions, and planetary nebulae. These properties make QCC a strong candidate material as a laboratory analog to the carbonaceous material in the interstellar medium. QCC is distinguished from the PAH hypothesis in that (1) it is a condensate composed of aromatic and aliphatic molecules, as well as radicals; (2) it exhibits a 220 nm absorption that is very similar in wavelength to the 217 nm absorption in the interstellar medium; (3) it exhibits visible fluorescence consistent with that seen in reflection nebulae; and (4) the bands at 7.7 and 8.6 microns are caused by ketone bands in oxidized QCC. The aromatic component in QCC is thought to be typically 1-4 rings, with the majority being about 1-2 rings.     

Carbonaceous materials in cometary environments: the case of the 3-4 micrometers bands.

We present in this paper a simulation of cometary spectra between 3 and 4 micrometers performed by using the optical properties of various carbon-based materials measured at different temperatures in the range 300-520 K. In our computations we have used new laboratory data obtained for hydrogenated amorphous carbon (HAC) grains and three kinds of polycyclic aromatic hydrocarbons (PAHs). All these materials show significant features in the near IR region; however, only the synthetic spectra obtained from HAC grains show a satisfactory agreement with the profile of the cometary bands.     

Present situation in the identification of polycyclic aromatic hydrocarbons

Recently, the interpretation given to the so-called “unidentified” infrared emission bands has drastically improved. These bands are attributed to the fundamental vibrations of large molecules known in organic chemistry as Polycyclic Aromatic Hydrocarbons (PAH's). In this paper, we review the main arguments which led to this conclusion and focus our attention to some recent IR and UV spectroscopic studies which allow us to interpret further the main characteristics of astronomical spectra.     

Ultraluminous infrared galaxies: Starburst vs. AGN

We have obtained ISOPHOT-S low resolution mid-infrared spectra of a sample of 60 Ultraluminous Infrared Galaxies (ULIRGs). We use the strength of the ‘PAH’ mid-infrared features as a discriminator between starburst and AGN activity, and to probe for evolutionary effects. Observed ratios of PAH features in ULIRGs differ slightly from those in lower luminosity starbursts. We suggest that such PAH ratio changes relate to the conditions in the interstellar medium in these galaxies, and in particular to extinction.     

Spectroscopic properties of polycyclic aromatic hydrocarbons (PAHs) and astrophysical implications.

PAHs (polycyclic aromatic hydrocarbons) are probably present as a mixture of neutral and ionized species and are responsible for the set of infrared emission bands in the 2-15 microns regions, which are observed in many different objects like reflection and planetary nebulae and external galaxies. PAHs are suggested to be the most abundant free organic molecules and ubiquitous in space. PAHs might also exist in the solid phase, included in interstellar ices in dense clouds. A complex aromatic network is expected on interstellar grains in the diffuse interstellar medium. The existence of an aromatic kerogen-like structure in carbonaceous meteorites and its similarity with interstellar spectra suggests a link between interstellar matter and primitive Solar System bodies.     

Impacts of the PAH size and the radiation intensity on the IR features of illuminated dust within the reflection nebulae

Interstellar dust grains are illuminated in the reflection nebulae. Under conditions of the PAH size and the intensity of the interstellar radiation field, we follow their impact on the PAH aromatic infrared bands using the numerical DustEM code. For a dust model consisting of PAH, amorphous C and amorphous silicate, the PAH size varies in a range from 0.31 to 4.9 nm while the radiation intensity varies by a scale factor from 0.1 to 10⁴. Various trends of the results show the effect of varying both the PAH size and the radiation intensity on the strength of the aromatic mid-IR bands. Through small PAH sizes less than 0.7 nm, the grain temperature distribution of PAHs shows a small variation within 2–3 K at low radiation intensity while it increases to 15 and 8 K for PAH⁰ and PAH⁺, respectively, at higher radiation intensity. In final the variability in these results reveals the evolution of the dust grains under the physical space conditions of the reflection nebulae. In the mid-IR region, the contributions of PAH⁰ and PAH⁺ in the total SED intensity agree with the proportions of these PAHs observed in some reflection nebulae having higher radiation intensities.     

Search for ultraviolet shuttle glow

The Space Shuttle Columbia flown in January 1986 carried two ultraviolet experiments (UVX) designed to observe very weak diffuse emission from various astronomical sources at wavelengths below 3200 Å with moderate spectral resolution. Such observations are extremely sensitive to the presence of any shuttle induced ultraviolet glow, since the wavelength range, 1200–3200 Å, includes strong emission lines or bands of species such as O, NO, and OH which are predicted to radiate strongly by models of the shuttle glow. The UVX spectrometers are sensitive to emission features as faint as 0.1 Rayleighs. Emissions from O₂, O and NO are detected and shown to be consistent with an atmospheric origin.     

Organic solids produced from simple C/H/O/N ices by charged particles: applications to the outer solar system.

CH4, CO, and CO2 are all potential one-carbon molecular repositories in primitive icy objects. These molecules are all found in the Comet Halley coma, and are probable but, (except for CH4 detected on Triton and Pluto) undetected subsurface constituents in icy outer solar system objects. We have investigated the effects of charged particle irradiation by cold plasma discharge upon surfaces of H2O:CH4 clathrate having a 200:1 ratio, as well as upon ices composed of H2O plus C2H6 or C2H2 (sometimes plus NH3) which are also plausible constituents. These materials color and darken noticeably after a dose 10(9) - 10(10) erg cm-2, which is deposited rapidly (< or = 10(4) yr.) in solar system environments. The chromophore is a yellowish to tan organic material (a tholin) which we have studied by UV-VIS reflection and transmission, and IR transmission spectroscopy. Its yield, -1 C keV-1, implies substantial production of organic solids by the action of cosmic rays and radionuclides in cometary crusts and interiors, as well as rapid production in satellite surfaces. This material shows alkane bands which Chyba and Sagan have shown to well match the Halley infrared emission spectrum near 3.4 microns, and also bands due to aldehyde, alcohol and perhaps alkene/aromatic functional groups. We compare the IR spectral properties of these tholins with the spectra of others produced by irradiation of gases and ices containing simple hydrocarbons.     

The natural background at shuttle altitudes

Optical measurements made from the Space Shuttle include several sources of emission, each modified according to viewing configuration, Shuttle altitude, solar activity, local time, and latitude. These sources include the atmospheric emissions and emissions of non-terrestrial origin (such as stellar, interstellar, and interplanetary), together with any contamination emission induced by the Shuttle itself. In order to make astronomical observations from the Shuttle, the observer needs good information on the intensities and spectral characteristics of these various sources. In this paper we present a model spectrum for one of these components, the natural airglow background. The spectrum is modeled over a wavelength range extending from the extreme ultraviolet to the near infrared. This model is based on our present knowledge of the upper atmosphere. The effect of different viewing configurations is illustrated, together with day to night variations. The results synthesized here assume an ideal vehicle in the sense that no contaminant emissions are induced by the Shuttle and payload. These spectra therefore represent a baseline which can be used to locate unanticipated or non-ambient features.     

Structure and UV absorption of QCCs: carbonaceous dust analogues.

"Quenched Carbonaceous Composites (QCCs)" are carbonaceous interstellar dust analogues synthesized in the laboratory from a hydrocarbon plasma. We produced new types of carbonaceous condensates from the ejecta of plasma with mixtures of methane and hydrogen as source gases. We find that QCC with an absorbance peak at 220 nm is composed of onion-like spherules, and QCCs with an absorbance peak at 230-240 nm are composed of polyhedral particles. The onion-like QCC contains aromatic hydrogen bonds, and it shows the 3.3 and 11.4 micrometers absorption bands. The QCC with an absorbance peak at 230-240 nm is composed of ribbons with bent graphitic layers. This suggests that the carrier of the interstellar 220 nm extinction band might also be an emitter of the interstellar diffuse emission bands.     

The extreme ultraviolet explorer

The Extreme Ultraviolet Explorer (EUVE) Mission is described. The purpose of this mission is to search the celestial sphere for astronomical sources of extreme ultraviolet (EUV) radiation (100–1000Å). The search will be accomplished with the use of three EUV telescopes, each sensitive to different bands within the EUV band. A fourth telescope will perform a high sensitivity search of a limited sample of the sky in a single EUV band. In six months, the entire sky will be scanned at a sensitivity level comparable to existing surveys in other more traditional astronomical bandpasses. A substantial number of EUV sources such as hot white dwarfs and stellar coronae are certain to be discovered given our current knowledge. More uncertain is what entirely new classes of objects will be discovered as EUV sources. A moderate resolution (～ 5Å) spectroscopy option is being considered which would cover the band from 80 to 600Å. This instrument would be capable of providing spectra of at least the 100 brightest EUV sources and would be utilized entirely on a Guest Investigator basis.     

Spectroscopy of the extreme ultraviolet background radiation

Observations in the far ultraviolet and soft x-ray bands suggest that the interstellar medium contains several components of high temperature gas and should be emitting in the extreme ultraviolet. Indeed diffuse radiation has been detected in the extreme ultraviolet with photometric instruments, but no spectral measurements exist below 520Å. We have designed a unique grazing incidence spectrometer to study the diffuse emission between 80 and 650Å with 10 to 20Å resolution. The instrument was launched on a Black Brant sounding rocket from White Sands Missile Range on April 22, 1986. Our preliminary analysis shows the expected geocoronal and interplanetary HeI 584Å emission, and possibly other features which may originate in the hot ionized interstellar gas. Flux limits to these possible emission lines are compatible with previous broad band measurements.     

U.V. astronomy with balloons

Balloon platforms are becoming more and more reliable as carriers of infrared and UV equipment. The balloon environment offers conditions of lower emissivity and higher transparency of the atmosphere. Precise photometric and spectroscopic measurements can be made in all spectral interval exceeding 1950 Å. Stabilized and unexpensive gondola are now available. Thus, high and low resolution spectra can be obtained for numerous stars. Accurate UV-multiband photometry and spectrophotometry are possible for stars members of large galactic clusters. A stabilized astronomical gondola was carrying a Schmidt photographic camera with UV microchannel plate image converter-intensifier. Systematic surveys of the galactic plane and the galactic poles are in progress. The quality of the UV image is good enough to allow a fine morphological analysis of the large galaxies, to detect a large number of nuclei of galaxies and nebulosities.     

Probable interstellar MgX (X = CN, NC, CCH, CC, C3N, NCCC, CCNC, C4H, and C4): A DFT study

The geometries, dipole moments, and rotational constants for several magnesium compounds and their anions were calculated by using the B3LYP/Aug-cc-pVTZ method. The rotational constants of linear forms have been derived to be used for laboratory experiment and astronomical observation.     

The 2.5 to 5 microns spectrum of comet Halley from the IKS instrument of Vega

Results of the 2.5–5 micron spectroscopic channel of the IKS instrument on Vega are reported and the data reduction process is described. H₂O and CO₂ molecules have been detected with production rates of 10³⁰ s⁻¹ and 1.5 10²⁸ s⁻¹ respectively. Emission features between 3.3 and 3.7 microns are tentatively attributed to CH - bearing compounds - CO is marginally detected with a mixing ratio CO/H₂O 0.2. OH emission and H₂O - ice absorption might also be present in the spectra.     

Status of the Hard X-ray Modulation Telescope Project

The Hard X-ray Modulation Telescope (HXMT) is China's first astronomical satellite. It will perform a broad band (1-250keV) scan survey and do pointed observations of X-ray sources to study their spectra and multi-wavelength temporal properties. The pre-flight models of the satellites have been finished, and the flight models are in production. The expected launch date of HXMT is in late 2015.      

Possible evidence of hydrocarbons released by the nucleus of Halley's comet.

After subtracting the intense dust-scattered continuum from the original spectra transmitted by the Vega 2 three-channel spectrometer, a broad-band emission emerges in the 342-375 nm spectral range when the cometocentric projected distance p is smaller than 5000 km. This newly detected emission varies as p-1, which implies that the involved molecule(s) has a parent-type behavior. The emission band presents four peaks at 347, 356, 364 and 373 nm. It is tentatively identified as being due to phenanthrene, a three-cycle aromatic condensed hydrocarbon. A determination of the gQ product, where g is the fluorescence quantum efficiency and Q the production rate gives gQ = 1.2 x 10(25). If g = 0.012, it comes Q = 1 x 10(27) s-1. The detection of phenanthrene in Halley's inner coma is an important argument in favor of a similarity of composition between cometary material and interstellar matter. It supports the hypothesis that comets have kept trace of the interstellar composition through the solar system formation epoch.     

XANES analysis of organic residues produced from the UV irradiation of astrophysical ice analogs

Organic residues formed in the laboratory from the ultraviolet (UV) photo-irradiation or ion bombardment of astrophysical ice analogs have been extensively studied for the last 15 years with a broad suite of techniques, including infrared (IR) and UV spectroscopies, as well as mass spectrometry. Analyses of these materials show that they consist of complex mixtures of organic compounds stable at room temperature, mostly soluble, that have not been fully characterized. However, the hydrolysis products of these residues have been partly identified using chromatography techniques, which indicate that they contain molecular precursors of prebiotic interest such as amino acids, nitrile-bearing compounds, and amphiphilic compounds. In this study, we present the first X-ray absorption near-edge structure (XANES) spectroscopy measurements of three organic residues made from the UV irradiation of ices having different starting compositions. XANES spectra confirm the presence of different chemical functions in these residues, and indicate that they are rich in nitrogen- and oxygen-bearing species. These data can be compared with XANES measurements of extraterrestrial materials. Finally, this study also shows how soft X rays can alter the chemical composition of samples.     

Thin structure of temporal profiles of solar flares January 15, 17 and 20, 2005 by data of AVS-F apparatus onboard CORONAS-F satellite

The count rate temporal profiles and energy spectra of the solar flares January 15, 17, 20 2005 in hard X-ray and gamma energy bands by data of AVS-F apparatus onboard CORONAS-F satellite are discussed. The energy spectra of these solar flares contain positron line and neutron capture line. Solar flares of January 17 and 20 spectra also contain some nuclear lines. Thin structure with characteristic timescales of 33–92 s is presented on flares temporal profiles in energy bands corresponding to the observed spectral features, which are confirmed by periodogram analysis (confidence level is 99%).