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YU Wei* LU Xue-qin LU Wan-bing HAN Li FU Guang-sheng College of Physics Science Technology Hebei University Baoding China 《中国航空学报》2006,19(Z1)
Nanocrystalline (nc) 3C-SiC films on the Si substrate were prepared by the helicon wave plasma enhanced chemical vapor deposi-tion (HW-PECVD) technique. With the SiH4-CH4 gas flow ratio changing, the films exhibit different photoluminescence (PL) character-istics. Under the stoichiometric condition, the PL peak redshift from 470 nm to 515 nm is detected with the increase of excitation wave-length, which can be attributed to the quantum confinement effect radiation of 3C-SiC nanocrystals of different sizes. However, the ap-pearance of an additional PL band at 436 nm in Si-rich film might be sourced back to the excess of Si defect centers in it. This is also the case for C-rich film for its PL band lying at 570 nm. The results above quoted indicate an important influence of gas flow ratio on the PL properties of the SiC films providing an effective guidance for analyzing the luminescence mechanism and exploring the high-efficiency light emission of the SiC films. 相似文献
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DU Xin-kang WANG Tian-min WANG Cong CHEN Bu-liang ZHOU Long 《中国航空学报》2007,20(2):140-144
Some fundamental studies on the preparation, structure and optical properties of NbN films were carried out. NbN thin films were deposited by DC reactive magnetron sputtering at different N2 partial pressures and different substrate temperatures ranging from –50 ℃ to 600 ℃. X-ray diffraction analysis (XRD) and scanning electron microscopy (SEM) were employed to characterize their phase com- ponents, microstructures, grain sizes and surface morphology. Optical properties inclusive of refractive indexes, extinction coefficients and transmittance of the NbN films under different sputtering conditions were measured. With the increase in the N2 partial pressure, δ-NbN phase structure gets forming and the grain size and lattice constant of the cubic NbN increasing. The deposited NbN film has relatively high values of refractive index and extinction coefficient in the wavelength ranging from 240 nm to 830 nm. Substrate tem- perature exerts notable influences on the microstructure and optical transmittance of the NbN films. The grain sizes of the δ-NbN film remarkably increase with the rise of the substrate temperature, while the transmittance of the films with the same thickness decreases. Ultra-fine granular film with particle size of several nanometers forms when the substrate is cooled to –50 ℃, and a remarkable aug- mentation of transmittance could be noticed under so low a temperature. 相似文献
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CHENG Xing-hua QIAO Liang BI Xiao-fang* School of Materials Science Engineering Beijing University of Aeronautics Astronautics Beijing China 《中国航空学报》2006,19(Z1)
In an attempt of being used as buffer layers and electrodes for the textured BaTiO3 (BTO) ferroelectric thin films, highly (100)-oriented LaNiO3 (LNO) thin films of different thicknesses were deposited directly on Si (100) substrate with radio-frequency (RF) magnetron sputtering method. It is observed that the substrate temperatures and the film thicknesses bring main influences on the micro-structures and orientation of the thin film. The effects of the thicknesses and substrate temperatures on the orientation of the films were studied on the LNO films of different thicknesses. The highly (100)-oriented LNO thin films were obtained at the substrate temperature of 600 ℃. The existence of epitaxially grown BTO films indicates that the oriented LNO thin films obtained in this work could be used as a buffer layer for epitaxial growth. 相似文献
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DING Wen-ge* YU Wei ZHANG Jiang-yong HAN Li FU Guang-sheng College of Physics Science Technology Hebei University Baoding China 《中国航空学报》2006,19(Z1)
The hydrogenated amorphous silicon nitride (SiNx) thin films embedded with nano-structural silicon were prepared and the micro-structures at the interface of silicon nano-grains/SiNx were identified by the optical absorption and Raman scattering measurements. Characterized by the exponential tail of optical absorption and the band-width of the Raman scattering TO mode, the disorder in the interface region increases with the gas flow ratio increasing. Besides, as reflected by the sub-gap absorption coefficients, the density of interface defect states decreases, which can be attributed to the structural mismatch in the interface region and also the changes of hy-drogen content in the deposited films. Additional annealing treatment results in a significant increase of defects and degree of disorder, for which the hydrogen out-diffusion in the annealing process would be responsible. 相似文献
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采用磁过滤直流真空阴极弧沉积技术在硅片、不锈钢片基体上制备了类金刚石(DLC)膜。检测结果表明,膜中存在着微米级的大颗粒分布,膜厚为290nm,sp3键的含量为62.23%。所制备的薄膜具有典型的DLC膜Raman光谱特征,耐磨性能优良,膜与基体的结合性能良好。 相似文献
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热障涂层杨氏模量和泊松比的测试 总被引:1,自引:0,他引:1
为了降低航空发动机热端部件的温度,空气等离子喷涂已被广泛地应用。为确定热障涂层的残余应力、结合力、断裂韧性、疲劳裂纹扩展速率等性能和特性,需要知道其杨氏模量和泊松比。因为涂层厚度非常薄且使用时是结合在基体上的,所以需要一个能够在原处测量涂层的杨氏模量和泊松比的方法。采用等离子喷涂工艺在GH150高温合金上喷涂了MCrAIY和陶瓷层,利用一种改进的悬臂梁方法测量了热障涂层的杨氏模量和泊松比。这种无损测试方法为测定其他薄膜材料的杨氏模量和泊松比提供了借鉴。 相似文献
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IBAD法沉积TiN薄膜的机械和耐腐性 总被引:4,自引:0,他引:4
用离子束辅助沉积(IBAD)方法在医用不锈钢317L基底上沉积TiN陶瓷薄膜。通过X射线衍射(XRD)和俄歇电子能谱(AES)分析研究了薄膜的微结构;测试了薄膜的耐磨性及薄膜与基底的附着力:运用电化学腐蚀的方法检测了薄膜在Hank’s模拟体液中的耐腐蚀性能。研究结果表明:用高、低能氮离子束兼用的IBAD方法沉积TiN多晶薄膜后,材料表面结构和性能发生明显改变。表面硬度和耐磨性有明显提高,在Hank’s模拟体液中显示出更强的抗腐蚀能力。 相似文献
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赝火花脉冲电子束烧蚀制备纳米薄膜 总被引:1,自引:1,他引:1
类似于脉冲激光束烧蚀法制备薄膜 ,利用纳秒赝火花脉冲电子束与靶材料相互作用 ,通过靶材料的瞬间熔化、蒸发或以团簇抛出的方式 ,在低温衬底上重新成核、凝结 ,得到了与靶材的化学计量比相同的薄膜。讨论了材料烧蚀和沉积过程中出现的诸多现象 ,并给出高分辨电子显微镜、X射线衍射、光电子能谱分析等方法的测试结果。研究表明 ,由于赝火花脉冲电子束高功率密度 (10 9W cm2 )的瞬态烧蚀作用 ,为研究和制备多元素氧化物薄膜、难熔金属多层膜或氧化物 金属多层膜提供了一种新手段 相似文献
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LI Hong-bo* ZHENG Yong-ting ZHOU Li-juan HAN Jie-cai Center for Composite Materials Harbin Institute of Technology Harbin China 《中国航空学报》2006,19(Z1)
The feasibility was demonstrated to fabricate h-BN-SiC ceramics through combustion synthesis of the mixture of boron carbide and silicon powders under 100 MPa nitrogen pressure. The mass fraction of BN and SiC in the combustion products were found to be 72 % and 28 % respectively. The thermodynamics of the synthesis reaction and the adiabatic combustion temperature were calculated on the theoretical ground. The bending strengths of the ceramics were measured to be 65.2 MPa at room temperature and 55 MPa at 1350 ℃. The phase composition and microstructure of the combustion products were identified by X-ray diffraction (XRD) and scanning electron microscopy (SEM). 相似文献
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Diamond-like carbon (DLC) films are deposited by the Hall ion source assisted by the mid-frequency unbalanced magnetron sput-tering technique. The effects of the substrate voltage bias, the substrate temperature, the Hall discharging current and the argon/nitrogen ratio on the DLC film’s performance were studied. The experimental results show that the film’s surface roughness, the hardness and the Young’s modulus increase firstly and then decrease with the bias voltage incrementally increases. Also when the substrate temperature rises, the surface roughness of the film varies slightly, but its hardness and Young’s modulus firstly increase followed by a sharp decrease when the temperature surpassing 120 ℃. With the Hall discharging current incrementally rising, the hardness and Young’s modulus of the film decrease and the surface roughness of the film on 316L stainless steel firstly decreased and then remains constant. 相似文献
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Wang Wenwen Wang Tianmin 《中国航空学报》2007,20(5):464-468
作为一种功能薄膜,透明导电氧化物(TCO)薄膜在飞行器的抗原子氧(AO)涂层和太阳能电池领域有着巨大的应用价值。ZnO:Al(ZAO)和In2O3:Sn(ITO)薄膜是目前研究和应用最广泛的TCO。本文对ITO薄膜和ZAO薄膜进行了不同通量的AO辐照。通过对辐照前后样品的X射线衍射、扫描电镜及霍耳效应的表征及测试,研究了AO辐照对这两种TCO薄膜的结构、性能及电学特性的影响。研究表明AO辐照对ZAO薄膜表面有明显的侵蚀作用,但对其结构和导电性能没有明显影响。对于ITO薄膜,随着AO通量的增大,其载流子浓度逐渐下降从而导致了电阻率的提高,电阻率的最大变化达到了21.7%。 相似文献
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向远博%刁训刚%郝雷%顾宝霞 《宇航材料工艺》2008,38(5)
采用多弧离子镀制备了具有不同色彩的Cr/Cr2O3薄膜,利用紫外-可见光分光光度计研究了薄膜在可见和红外波段的光谱特性,利用SEM进行薄膜表面结构和形貌的分析,利用四探针测阻仪测试了样品的方块电阻,利用红外发射率测量仪测试了样品的红外发射率。结果表明:Cr/Cr2O3薄膜具有丰富的色彩,在可见光区有明显的反射峰,可见光区光谱特性主要受膜厚的影响,方块电阻随膜厚增加而有变大,样品的红外发射率主要取决于金属层,平均红外发射率最小降至0.371。 相似文献