Water Reservoirs in Small Planetary Bodies: Meteorites,Asteroids, and Comets

Asteroids and comets are the remnants of the swarm of planetesimals from which the planets ultimately formed, and they retain records of processes that operated prior to and during planet formation. They are also likely the sources of most of the water and other volatiles accreted by Earth. In this review, we discuss the nature and probable origins of asteroids and comets based on data from remote observations, in situ measurements by spacecraft, and laboratory analyses of meteorites derived from asteroids. The asteroidal parent bodies of meteorites formed \(\leq 4\) Ma after Solar System formation while there was still a gas disk present. It seems increasingly likely that the parent bodies of meteorites spectroscopically linked with the E-, S-, M- and V-type asteroids formed sunward of Jupiter’s orbit, while those associated with C- and, possibly, D-type asteroids formed further out, beyond Jupiter but probably not beyond Saturn’s orbit. Comets formed further from the Sun than any of the meteorite parent bodies, and retain much higher abundances of interstellar material. CI and CM group meteorites are probably related to the most common C-type asteroids, and based on isotopic evidence they, rather than comets, are the most likely sources of the H and N accreted by the terrestrial planets. However, comets may have been major sources of the noble gases accreted by Earth and Venus. Possible constraints that these observations can place on models of giant planet formation and migration are explored.     

Gas-rich meteorites: Probes for particle environment and dynamical processes in the inner solar system

The discovery in the early sixties of precompaction solar wind irradiation records in the gas-rich meteorites opened up the possibility of studying the solar activity at different epochs in the distant past. Subsequent studies in several meteorites have led to the discovery of the precompaction records of irradiation of constituent grains by solar wind, solar flare and galactic cosmic ray particles. There are also microcraters resulting from their collisions with interplanetary dust grains. Analyses of these records and their observed similarity with those found in the lunar samples led to the hypothesis that the precompaction records in individual components of these meteorites were imprinted while they were residing in the near surface region of their parent bodies, most probably the asteroids. Although the asteroids are the most plausible candidates for the parent bodies of gas-rich meteorites, there exist certain dynamical arguments which tend to favor a cometary origin in certain cases. Also, recent studies indicate that in the case of gas-rich carbonaceous chondrites solar flare irradiation of grains may have occurred prior to formation of the parent bodies.In this review we summarize the significant advances that have taken place in the multi-disciplinary studies (petrography, chemistry, and radiation effects) of the gas-rich meteorites and critically evaluate the present state of our knowledge regarding the origin and evolution of the gas-rich meteorites. The information on the spatial and temporal variations in the interplanetary radiation and particle fluxes, obtained from the analysis of precompaction irradiation records in these meteorites is presented and further studies in certain specific topics are suggested for resolving some of the unsolved problems.     

Isotopes in comets: Implications from Cr in carbonaceous chondrites

According to their chemical composition, rich in volatile compounds, comets are thought to be primitive materials. They may provide prime samples for the study of nucleosynthetic components of the solar system and of the processes occurring during the formation of the outer planets. Their origin is largely a matter of conjecture. Chromium isotopic measurements in carbonaceous chondrites illustrate how the non-volatile part of cometary material can be investigated both for isotopic heterogeneity and for the extinct nuclide ⁵³Mn. Questions like the possible presence of ²⁶Al as a heat source can also be addressed by these measurements.     

Origin,age, and composition of meteorites

This paper attempts to bring together and evaluate all significant evidence on the origin of meteorites.The iron meteorites seem to have formed at low pressures. Laboratory evidence shows that the absence of a Widmanstätten pattern in meteorites with > 16% Ni cannot be attributed to high pressures, but to supercooling or an unusually fast cooling rate for these meteorites, which prevented the development of a pattern. The presence of tridymite in the Steinbach siderophyre provides further, direct proof that the Widmanstätten pattern can form at pressures less than 3 kb. Neither diamond, nor cliftonite, nor cohenite are reliable pressure indicators in meteorites. Diamonds were formed by shock while cliftonite may have been derived from a cubic carbide such as Fe₄C. Cohenite is apparently stabilized by kinetic rather than thermodynamic factors. Several lines of evidence suggest that the irons come from more than one parent body, perhaps as many as four.The frequency of pallasites is perfectly consistent with an origin in the transition zone between core and mantle of the parent body. Hybrid meteorites such as Brenham are not necessarily derived from the metal-silicate interface, but probably resulted from dendrite growth in the solidifying melt.Ordinary chondrites definitely are equilibrium assemblages rather than chance conglomerates. According to the best available evidence, Prior's rules seem to be valid. The metal particles in chondrites differentiated into kamacite and taenite in their present location, rather than in a remote earlier environment. Trace element abundances in ordinary and carbonaceous chondrites suggest that these meteorites accreted from two types of matter: an undepleted fraction that separated from its complement of gases at low temperatures, and a depleted fraction that lost its gases at high temperatures. These two fractions of primitive meteoritic matter are tentatively identified with the matrix and chondrules-plus-metal, respectively. New restrictive limits are placed on the iron-silicate fractionation in chondrites. No direct evolutionary path exists that connects the currently accepted solar abundances of Fe and Ni and the observed Fe/Si and Ni/Si ratios in chondrites. Apparently the solar abundance of iron is in error. The iron-silicate fractionation seems to have occurred while chondritic matter was in a more strongly reduced state than its present one.The U-He and K-Ar ages of hypersthene chondrites are systematically shorter than those of bronzite chondrites. Short ages are correlated with shock effects, and it seems that the hypersthene chondrites suffered reheating and partial-to-complete outgassing 0.4 AE ago. The cosmic-ray exposure ages of all classes of meteorites cluster distinctly, indicating that the meteorites were produced in a few discrete major collisions rather than by a quasi-continuum of smaller ones. The dates of the principal breakups are: irons, 0.6 and 0.9 AE; aubrites, 45 m.y.; bronzite chondrites, 4 m.y.; hypersthene chondrites, 0.025, 3, 7–13, and 16–31 m.y. All four clusters of hypersthene chondrites show evidence of severe outgassing 0.4 AE ago, which implies that most or all hypersthene chondrites come from the same parent body.As already noted by Signer and Suess, two distinct types of primordial gas occur in meteorites. Differentiated meteorites always contain unfractionated gas, while relatively undifferentiated meteorites contain fractionated gas. The former component is invariably associated with shock effects, and seems to have been derived from the solar wind. The latter component is correlated with other volatiles and seems to be a truly primitive constituent of meteoritic matter. Isotopic anomalies in the fractionated gas suggest that meteoritic matter was irradiated with 10¹⁷ protons/cm² at a very early stage of its history.There is very little doubt that most, if not all, meteorites come from the asteroid belt rather than from the moon. The orbits and geocentric velocities of stony meteorites resemble those of the Apollo asteroids (most of which are former members of the asteroid belt that have strayed into terrestrial space), but disagree strongly with the calculated orbits and velocities for lunar ejecta. Öpik's conclusions about the difficulty of accelerating lunar debris to escape velocity represent a further argument against a lunar origin of stony meteorites.The most likely parent bodies of the meteorites are the 34 asteroids which cross the orbit of Mars. Collisional debris from these objects will remain in Mars-crossing orbits, and perturbations by Mars will inject some fraction of this material into terrestrial space. Most of the Mars asteroids, comprising 98% of the mass and 92% of the cross-section, belong to three Hirayama families (Phocaea, Desiderata, and Aethra), and an additional, previously unrecognized family. These families were apparently produced by disruption of parent asteroids ca. 104, 105, and 46 km in diameter. The size distribution and light curves of asteroids indicate that the larger asteroids are original accretions, rather than collision fragments. There is no reason to believe that the meteorites ever resided in bodies larger than Ceres (d = 770 km).Various theories on the origin of the meteorites are critically reviewed in the light of the preceding evidence. Wood's theory, which postulates a high-temperature and a low-temperature variety of primordial matter, is in best accord with the evidence. Apparently the asteroids accreted from varying proportions of these two types of material, and were then heated by extinct radioactivity produced in the early irradiation.     

The D/H Ratio in Chondrites

The statistical distribution of all available published D/H ratios of carbonaceous chondrites is presented. The possible interpretations of this distribution are reviewed at the global scale of the solar system planetary objects and at the scale defined by the carbonaceous meteorites. New issues concerning the chemical origin of the deuterium enrichment in solar system water and organic molecules are put into light by this exercise. This distribution is a robust constraint on the origin of water on Earth. This revised version was published online in August 2006 with corrections to the Cover Date.     

Cometary dynamics

The modern theory of cometary dynamics is based on Oort's hypothesis that the solar system is surrounded by a spherically symmetric cloud of 10¹¹ to 10¹² comets extending out to interstellar distances. Dynamical modeling and analysis of cometary motion have confirmed the ability of the Oort hypothesis to explain the observed distribution of energies for the long-period comet orbits. The motion of comets in the Oort cloud is controlled by perturbations from random passing stars, interstellar clouds, and the galactic gravitational field. Additionally, comets which enter the planetary region are perturbed by the major planets and by nongravitational forces resulting from jetting of volatiles on the surfaces of the cometary nuclei. The current Oort cloud is estimated to have a radius of 6 to 8 × 10⁴ AU, and to contain some 2 × 10¹² comets with a total mass of 7 to 8 Earth masses. Evidence has begun to accumulate for the existence of a massive inner Oort cloud extending from just beyond the orbit of Neptune to 10⁴ AU or more, with a population up to 100 times that of the outer Oort cloud. This inner cloud may serve as a reservoir to replenish the outer cloud as comets are stripped away by the various perturbers, and may also provide a more efficient source for the short-period comets. Recent suggestions of an unseen solar companion star or a tenth planet orbiting in the inner cloud and causing periodic comet showers on the Earth are likely unfounded. The formation site of the comets in the Oort cloud was likely the extended nebula accretion disc reaching from about 15 to 500 AU from the forming protosun. Comets which escape from the Oort cloud contribute to the flux of interstellar comets, though capture of interstellar comets by the solar system is extremely unlikely. The existence of Oort clouds around other main sequence stars has been suggested by the detection by the IRAS spacecraft of cool dust shells around about 10% of nearby stars.     

The observational data base on the motion and evolution of comets and asteroids

Current observational data base on the motion of comets and asteroids is reviewed. Particular attention is paid to the absolute and relative abundances of different dynamical types of objects, and to the time intervals between their first and last observations. The latter quantity, ranging from two days to two milliennia for individual objects, is the dominant measure of the accuracy of the orbit determination. Distribution of the tracking times of comets (distinguished by dynamical age: new, long-period, Halley type, Jupiter family) and asteroids (distinguished by stability: Apollos, Amors, main-belt asteroids, outer librators, outer unstable objects) are reconstructed. The peculiar shapes of individual distributions can be explained by the complex mechanisms of discoveries, rediscoveries, orbit computations, follow-up observations and backward identifications. A comparison is also made with the dynamical data base on meteoroids, as regards the accuracy of their orbits.The cumulative tracking times (170000 yr for all 7600 objects with known orbits taken together) are compared with the lifetimes and occurrence rates of different events of evolutionary significance. Only in the case of short-period comets the evolution is rapid enough to render observable a variety of important changes, ranging from drastic transformations of orbits to disruption or total outgassing. For asteroids, only minor cratering collisions which do not result in detectable changes of their orbits are covered by the whole observational history.Expected future improvements of observing and data-handling techniques are outlined. With these in view, the size and character of the data to become available by the end of this century are predicted. Dynamical types of objects, which are currently known in only one or a few examples, are pointed out. Apparently, other types of rare occurrence and short survival time still escape detection. A list of easiest targets of short-duration spacecraft missions is presented.The deficiencies of current statistics due to observational selection; the broad variety of regimes of motion occupied by widely differing proportional representations of the known objects; and demands for suitable targets of future spacecraft missions make it highly desirable to maintain the present rapid rate of augmentation of the data base for the years to come.Recent passages of two comets — 1983d IRAS-Araki-Alcock and 1983e Sugano-Saigusa-Fujikawa — near the Earth indicate that both the collision rate given in Table VIII and the contribution of long-period comets to it may have been slightly underestimated. The appropriate adjustment of the log-t values by less than — 0.10 has no effect of the general conclusions, however.The success of the orbiting observatory IRAS in detecting faint interplanetary objects lends better promises for the increase of the number of known objects (in particular comets) than anticipated in Section 6 and estimated in Table IX. Obviously, the outcome will largely depend on the implementation, time coverage and degree of exploitation of similar projects in the near future.     

Cometary Refractory Grains: Interstellar and Nebular Sources

Comets are heterogeneous mixtures of interstellar and nebular materials. The degree of mixing of interstellar sources and nebular sources at different nuclear size scales holds the promise of revealing how cometary particles, cometesimals, and cometary nuclei accreted. We can ascribe cometary materials to interstellar and nebular sources and see how comets probe planet-forming process in our protoplanetary disk. Comets and cometary IDPs contain carbonaceous matter that appears to be either similar to poorly-graphitized (amorphous) carbon, a likely ISM source, or highly labile complex organics, with possible ISM or outer disk heritage. The oxygen fugacity of the solar nebula depends on the dynamical interplay between the inward migration of carbon-rich grains and of icy (water-rich) grains. Inside the water dissociation line, OH^? reacts with carbon to form CO or CO₂, consuming available oxygen and contributing to the canonical low oxygen fugacity. Alternatively, the influx of water vapor and/or oxygen rich dust grains from outer (cooler) disk regions can raise the oxygen fugacity. Low oxygen fugacity of the canonical solar nebula favors the condensation of Mg-rich crystalline silicates and Fe-metal, or the annealing of Fe-Mg amorphous silicates into Mg-rich crystals and Fe-metal via Fe-reduction. High oxygen fugacity nebular conditions favors the condensation of Fe-bearing to Fe-rich crystalline silicates. In the ISM, Fe-Mg amorphous silicates are prevalent, in stark contrast to Mg-rich crystalline silicates that are rare. Hence, cometary Mg-rich crystalline silicates formed in the hot, inner regions of the canonical solar nebula and they are the touchstone for models of the outward radial transport of nebular grains to the comet-forming zone. Stardust samples are dominated by Mg-rich crystalline silicates but also contain abundant Fe-bearing and Fe-rich crystalline silicates that are too large (?0.1 μm) to be annealed Fe-Mg amorphous silicates. By comparison with asteroids, the Stardust Fe-bearing and Fe-rich crystalline silicates suggests partial aqueous alteration in comet nuclei. However, aqueous alteration transforms Fe-rich olivine to phyllosilicates before Mg-rich olivine, and Stardust has Mg-rich and Fe-rich olivine and no phyllosilicates. Hence, we look to a nebular source for the moderately Fe-rich to nearly pure-Fe crystalline silicates. Primitive matrices have Mg-Fe silicates but no phyllosilicates, supporting the idea that Mg-Fe silicates but not phyllosilicates are products of water-rich shocks. Chondrule-formation is a late stage process in our protoplanetary disk. Stardust samples show comet 81P/Wild 2 formed at least as late to incorporate a few chondrules, requiring radial transport of chondrules out to perhaps >20 AU. By similar radial transport mechanisms, collisional fragments of aqueously altered asteroids, in particular achondrites that formed earlier than chondrules, might reach the comet-forming zones. However, Stardust samples do not have phyllosilicates and chondrules are rare. Hence, the nebular refractory grains in comet 81P/Wild 2, as well as other comets, appear to be pre-accretionary with respect to asteroid parent bodies. By discussing nebular pathways for the formation of Fe-rich crystalline silicates, and also phyllosilicates and carbonates, we put forth the view that comets contain both the interstellar ingredients for and the products of nebular transmutation.     

Cometary Dust

This review presents our understanding of cometary dust at the end of 2017. For decades, insight about the dust ejected by nuclei of comets had stemmed from remote observations from Earth or Earth’s orbit, and from flybys, including the samples of dust returned to Earth for laboratory studies by the Stardust return capsule. The long-duration Rosetta mission has recently provided a huge and unique amount of data, obtained using numerous instruments, including innovative dust instruments, over a wide range of distances from the Sun and from the nucleus. The diverse approaches available to study dust in comets, together with the related theoretical and experimental studies, provide evidence of the composition and physical properties of dust particles, e.g., the presence of a large fraction of carbon in macromolecules, and of aggregates on a wide range of scales. The results have opened vivid discussions on the variety of dust-release processes and on the diversity of dust properties in comets, as well as on the formation of cometary dust, and on its presence in the near-Earth interplanetary medium. These discussions stress the significance of future explorations as a way to decipher the formation and evolution of our Solar System.     

Cometary Deuterium

Deuterium fractionations in cometary ices provide important clues to the origin and evolution of comets. Mass spectrometers aboard spaceprobe Giotto revealed the first accurate D/H ratios in the water of Comet 1P/Halley. Ground-based observations of HDO in Comets C/1996 B2 (Hyakutake) and C/1995 O1 (Hale-Bopp), the detection of DCN in Comet Hale-Bopp, and upper limits for several other D-bearing molecules complement our limited sample of D/H measurements. On the basis of this data set all Oort cloud comets seem to exhibit a similar ratio in H₂O, enriched by about a factor of two relative to terrestrial water and approximately one order of magnitude relative to the protosolar value. Oort cloud comets, and by inference also classical short-period comets derived from the Kuiper Belt cannot be the only source for the Earth's oceans. The cometary O/C ratio and dynamical reasons make it difficult to defend an early influx of icy planetesimals from the Jupiter zone to the early Earth. D/H measurements of OH groups in phyllosilicate rich meteorites suggest a mixture of cometary water and water adsorbed from the nebula by the rocky grains that formed the bulk of the Earth may be responsible for the terrestrial D/H. The D/H ratio in cometary HCN is 7 times higher than the value in cometary H₂O. Species-dependent D-fractionations occur at low temperatures and low gas densities via ion-molecule or grain-surface reactions and cannot be explained by a pure solar nebula chemistry. It is plausible that cometary volatiles preserved the interstellar D fractionation. The observed D abundances set a lower limit to the formation temperature of (30 ± 10) K. Similar numbers can be derived from the ortho-to-para ratio in cometary water, from the absence of neon in cometary ices and the presence of S₂. Noble gases on Earth and Mars, and the relative abundance of cometary hydrocarbons place the comet formation temperature near 50 K. So far all cometary D/H measurements refer to bulk compositions, and it is conceivable that significant departures from the mean value could occur at the grain-size level. Strong isotope effects as a result of coma chemistry can be excluded for molecules H₂O and HCN. A comparison of the cometary ratio with values found in the atmospheres of the outer planets is consistent with the long-held idea that the gas planets formed around icy cores with a high cometary D/H ratio and subsequently accumulated significant amounts of H₂ from the solar nebula with a low protosolar D/H. This revised version was published online in June 2006 with corrections to the Cover Date.     

The Origin and Evolution of the Asteroid Belt��Implications for Vesta and Ceres

Vesta and Ceres are the largest members of the asteroid belt, surviving from the earliest phases of Solar System history. They formed at a time when the asteroid belt was much more massive than it is today and were witness to its dramatic evolution, where planetary embryos were formed and lost, where the collisional environment shifted from accretional to destructive, and where the current size distribution of asteroids was sculpted by mutual collisions and most of the asteroids originally present were lost by dynamical processes. Since these early times, the environment of the asteroid belt has become relatively quiescent, though over the long history of the Solar System the surfaces of Vesta and Ceres continue to record and be influenced by impacts, most notably the south polar cratering event on Vesta. As a consequence of such impacts, Vesta has contributed a significant family of asteroids to the main belt, which is the likely source of the HED meteorites on Earth. No similar contribution to the main belt (or meteorites) is evident for Ceres. Through studies of craters, the surfaces of these asteroids will offer an opportunity for Dawn to probe the modern population of small asteroids in a size regime not directly observable from Earth.     

On the Organic Refractory Component of Cometary Dust

Cometary nuclei consist of ices intermixed with dust grains and are thought to be the least modified solar system bodies remaining from the time of planetary formation. Flyby missions to Comet P/Halley in 1986 showed that cometary dust is extremely rich in organics (∼50% by mass). However, this proportion appears to be variable among different comets. In comparison with the CI-chondritic abundances, the volatile elements H, C, and N are enriched in cometary dust indicating that cometary solid material is more primitive than CI-chondrites. Relative to dust in dense molecular clouds, bulk cometary dust preserves the abundances of C and N, but exhibits depletions in O and H. In most cases, the carbonaceous component of cometary particles can be characterized as a multi-component mixture of carbon phases and organic compounds. Cluster analysis identified a few basic types of compounds, such as elemental carbon, hydrocarbons, polymers of carbon suboxide and of cyanopolyynes. In smaller amounts, polymers of formaldehyde, of hydrogen cyanide and various unsaturated nitriles also are present. These compositionally simple types, probably, are essential "building blocks", which in various combinations give rise to the variety of involatile cometary organics. This revised version was published online in June 2006 with corrections to the Cover Date.     

Formation and Processing of Organics in the Early Solar System

Until pristine samples can be returned from cometary nuclei, primitive meteorites represent our best source of information about organic chemistry in the early solar system. However, this material has been affected by secondary processing on asteroidal parent bodies which probably did not affect the material now present in cometary nuclei. Production of meteoritic organic matter apparently involved the following sequence of events: Molecule formation by a variety of reaction pathways in dense interstellar clouds; Condensation of those molecules onto refractory interstellar grains; Irradiation of organic-rich interstellar-grain mantles producing a range of molecular fragments and free radicals; Inclusion of those interstellar grains into the protosolar nebula with probable heating of at least some grain mantles during passage through the shock wave bounding the solar accretion disc; Agglomeration of residual interstellar grains and locally produced nebular condensates into asteroid-sized planetesimals; Heating of planetesimals by decay of extinct radionuclides; Melting of ice to produce liquid water within asteroidal bodies; Reaction of interstellar molecules, fragments and radicals with each other and with the aqueous environment, possibly catalysed by mineral grains; Loss of water and other volatiles to space yielding a partially hydrated lithology containing a complex suite of organic molecules; Heating of some of this organic matter to generate a kerogen-like complex; Mixing of heated and unheated material to yield the meteoritic material now observed. Properties of meteoritic organic matter believed to be consistent with this scenario include: Systematic decrease of abundance with increasing C number in homologous series of characterisable molecules; Complete structural diversity within homologous series; Predominance of branched-chain isomers; Considerable isotopic variability among characterisable molecules and within kerogen-like material; Substantial deuterium enrichment in all organic fractions; Some fractions significantly enriched in nitrogen-15; Modest excesses of L-enantiomers in some racemisation-resistant molecules but no general enantiomeric preference. Despite much speculation about the possible role of Fischer-Tropsch catalytic hydrogenation of CO in production of organic molecules in the solar nebula, no convincing evidence for such material has been found in meteorites. A similarity between some meteoritic organics and those produced by Miller-Urey discharge synthesis may reflect involvement of common intermediates rather than the operation of electric discharges in the early solar system. Meteoritic organic matter constitutes a useful, but not exact, guide to what we shall find with in situ analytical and sample-return missions to cometary nuclei. This revised version was published online in June 2006 with corrections to the Cover Date.     

Dust Near The Sun

We review the current knowledge and understanding of dust in the inner solar system. The major sources of the dust population in the inner solar system are comets and asteroids, but the relative contributions of these sources are not quantified. The production processes inward from 1 AU are: Poynting-Robertson deceleration of particles outside of 1 AU, fragmentation into dust due to particle-particle collisions, and direct dust production from comets. The loss processes are: dust collisional fragmentation, sublimation, radiation pressure acceleration, sputtering, and rotational bursting. These loss processes as well as dust surface processes release dust compounds in the ambient interplanetary medium. Between 1 and 0.1 AU the dust number densities and fluxes can be described by inward extrapolation of 1 AU measurements, assuming radial dependences that describe particles in close to circular orbits. Observations have confirmed the general accuracy of these assumptions for regions within 30° latitude of the ecliptic plane. The dust densities are considerably lower above the solar poles but Lorentz forces can lift particles of sizes < 5 μm to high latitudes and produce a random distribution of small grains that varies with the solar magnetic field. Also long-period comets are a source of out-of-ecliptic particles. Under present conditions no prominent dust ring exists near the Sun. We discuss the recent observations of sungrazing comets. Future in-situ experiments should measure the complex dynamics of small dust particles, identify the contribution of cometary dust to the inner-solar-system dust cloud, and determine dust interactions in the ambient interplanetary medium. The combination of in-situ dust measurements with particle and field measurements is recommended.     

The Silicate Material in Comets

Silicates in comets appear to be a mix of high-temperature crystalline enstatite and forsterite plus glassy or amorphous grains that formed at lower temperatures. The mineral identifications from the 10 and 20 μm cometary spectra are consistent with the composition of anhydrous chondritic aggregate IDPs. The origin of the cometary silicates remains puzzling. While the evidence from the IDPs points to a pre-solar origin of both crystalline and glassy components, the signatures of crystalline silicates appear in the spectra of young stellar objects only at a late evolutionary stage, when comets are the likely source of the dust. This revised version was published online in June 2006 with corrections to the Cover Date.     

Diversity of Comets: Formation Zones and Dynamical Paths

The past dozen years have produced a new paradigm with regard to the source regions of comets in the early solar system. It is now widely recognized that the likely source of the Jupiter-family short-period comets (those with Tisserand parameters, T > 2 and periods, P, generally < 20 years) is the Kuiper belt in the ecliptic plane beyond Neptune. In contrast, the source of the Halley-type and long-period comets (those with T < 2 and P > 20 years) appears to be the Oort cloud. However, the comets in the Oort cloud almost certainly originated elsewhere, since accretion is very inefficient at such large heliocentric distances. New dynamical studies now suggest that the source of the Oort cloud comets is the entire giant planets region from Jupiter to Neptune, rather than primarily the Uranus-Neptune region, as previously thought. Some fraction of the Oort cloud population may even be asteroidal bodies formed inside the orbit of Jupiter. These comets and asteroids underwent a complex dynamical random walk among the giant planets before they were ejected to distant orbits in the Oort cloud, with possible interesting consequences for their thermal and collisional histories. Observational evidence for diversity in cometary compositions is limited, at best. This revised version was published online in June 2006 with corrections to the Cover Date.     

Organic constituents of the carbonaceous chondrites

From a brief discussion of forms of meteorite carbon it is concluded that almost all the carbon in the carbonaceous chondrites is present as organic matter. Attempts to extract and identify this organic matter are then reviewed. It is shown that only 25 per cent has been extracted and only about 5 per cent chemically characterized. Of this 5 per cent most is a complex mixture of hydroxylated aromatic acids together with various hydrocarbons of the paraffin, naphthene and aromatic series. Small amounts of amino acids, sugars and fatty acids also are present. The possible chemical nature of the major fraction is discussed. It is suggested to be a mixture of high-molecular weight aromatic and hydrocarbon polymers.Possible sources of contamination of the meteorites are described and evidence indicating a general lack of organic contaminants is presented. It is concluded that most of the organic constituents are indigenous to the meteorites and are extra terrestial in origin. Synthetic processes for the compounds are mentioned and it is concluded that the organic material is probably of abiogenic origin.A brief review on studies of organized elements contained within the meteorites is presented. Difficulties of identification are discussed and photographs of some micro-structures of several carbonaceous chondrites are presented. No final conclusion about the nature of these objects is possible, but some appear to be various indigenous organic and mineral structures, while others are terrestrial contaminants.Contribution from the Chemistry Section, Space Science Division of Jet Propulsion Laboratory.     

The Contributions of Comets to Planets, Atmospheres, and Life: Insights from Cassini-Huygens, Galileo, Giotto, and Inner Planet Missions

Comets belong to a group of small bodies generally known as icy planetesimals. Today the most primitive icy planetesimals are the Kuiper Belt objects (KBOs) occupying a roughly planar domain beyond Neptune. KBOs may be scattered inward, allowing them to collide with planets. Others may move outward, some all the way into the Oort cloud. This is a spherical distribution of comet nuclei at a mean distance of ～50,000 AU. These nuclei are occasionally perturbed into orbits that intersect the paths of the planets, again allowing collisions. The composition of the atmosphere of Jupiter—and thus possibly all outer planets—shows the effects of massive early contributions from extremely primitive icy bodies that must have been close relatives of the KBOs. Titan may itself have a composition similar to that of Oort cloud comets. The origin and early evolution of its atmosphere invites comparison with that of the early Earth. Impacts of comets must have brought water and other volatile compounds to the Earth and the other inner planets, contributing to the reservoir of key ingredients for the origin of life. The magnitude of these contributions remains unknown but should be accessible to measurements by instruments on spacecraft.     

Cosac, The Cometary Sampling and Composition Experiment on Philae

Comets are thought to preserve the most pristine material currently present in the solar system, as they are formed by agglomeration of dust particles in the solar nebula, far from the Sun, and their interiors have remained cold. By approaching the Sun, volatile components and dust particles are released forming the cometary coma. During the phase of Heavy Bombardment, 3.8--4 billion years ago, cometary matter was delivered to the Early Earth. Precise knowledge on the physico-chemical composition of comets is crucial to understand the formation of the Solar System, the evolution of Earth and particularly the starting conditions for the origin of life on Earth. Here, we report on the COSAC instrument, part of the ESA cometary mission Rosetta, which is designed to characterize, identify, and quantify volatile cometary compounds, including larger organic molecules, by in situ measurements of surface and subsurface cometary samples. The technical concept of a multi-column enantio-selective gas chromatograph (GC) coupled to a linear reflectron time-of-flight mass-spectrometer instrument is presented together with its realisation under the scientific guidance of the Max-Planck-Institute for Solar System Research in Katlenburg-Lindau, Germany. The instrument's technical data are given; first measurements making use of standard samples are presented. The cometary science community is looking forward to receive fascinating data from COSAC cometary in situ measurements in 2014.     

Hydrocarbons in terrestrial samples and the Orgueil meteorite

Meteorites contain extraterrestrial carbonaceous materials. The Alais, Orgueil, Tonk, and Ivuna meteorites resemble in their carbon, free sulfur, and non-metamorphosed mineral contents, densities, and general appearances certain organic-rich terrestrial sediments. Structural and isotopic determinations of carbon compounds in the Orgueil chondrite indicate that these compounds are primarily indigenous. Physically and chemically the benzene extractable carbonaceous materials from the Orgueil and certain near-surface terrestrial sediments are similar. Mass spectrometric type analyses of the alkanes from an Orgueil fragment, terrestrial sediments and organisms are statistically indistinguishable at the 95 per cent confidence level. Theoretical considerations and experimental data are presented, and these permit an assessment of the potential and reliability of hydrocarbons as biological indicators. Based on the production and preservation or organic substances in terrestrial environments, alkanes in the Alais, Orgueil, Tonk, and Ivuna (Type I) carbonaceous chondrites could retain the best evidence of organisms that may have lived on a parent body of meteorites.A portion of the research reported in this article was supported by the National Aeronautics and Space Administration under Contract No. NASw 508.