Modeling gas exchange in a closed plant growth chamber.

Fluid transport models for fluxes of water vapor and CO2 have been developed for one crop of wheat and three crops of soybean grown in a closed plant growth chamber. Correspondence among these fluxes is discussed. Maximum fluxes of gases are provided for engineering design requirements of fluid recycling equipment in growth chambers. Furthermore, to investigate the feasibility of generalized crop models, dimensionless representations of water vapor fluxes are presented. The feasibility of such generalized models and the need for additional data are discussed.     

Evolution of the Martian water cycle.

The current Martian water cycle is extremely asymmetric, with large amounts of vapor subliming off a permanent north polar water ice cap in northern summer, but with no apparent major source of water vapor in the southern hemisphere. Detailed simulations of this process with a three-dimensional circulation model indicate that the summertime interhemispheric exchange (Hadley cell) is very much stronger than transport by eddies in other seasons. As a result, water ice would be distributed globally were it not for the buffering action of regolith soil adsorption which limits the net flux of water vapor off the north polar cap to amounts that are insignificant even on the scale of thousands of years. It has been suggested that the polar layered deposits are the result of exchange on these long time scales, driven by changes in Martian orbital parameters. We therefore are conducting simulations to test the effect of varied orbital parameters on the Martian water cycle. We find that when the perihelion summer pole is charged with a polar water ice cap, large quantities of water are quickly transfered to the aphelion summer pole, setting up an annual cycle that resembles the present one. Thus, the adsorptivity of the Martian regolith may be in the narrow range where it can limit net transport from the aphelion but not the perihelion pole.     

Transport phenomena and crystal growth of the GeSe-Xenon system for different gravitational conditions

Previous chemical vapor transport experiments of the GeSe-GeI₄ system performed under reduced gravity conditions /1/ yielded crystals of considerably improved surface and bulk morphology. In addition, the mass transport rates observed in microgravity environment were significantly greater than predicted. A quantitative thermodynamic analysis of the solid-gas phase reactions of the GeSe-GeI₄ system revealed the multi-component, multi-reaction nature of the vapor phase /2/. Continued transport studies on ground of the GeSe-GeI₄ system in the presence of inert gases provided experimental evidence for the existence of a boundary layer /2/ and its thickness dependence on GeI₄ pressure in closed tube systems. Systematic transport rate measurements for different orientations of the density gradient relative to the gravity vector demonstrated the effects of ampoule inclination on mass flux /3/. Based on a computational model for simultaneous chemical vapor transport, sublimation, and Stefan flow /3/, the excellent agreement of predicted with ground-based experimental mass transport rates over wide pressure ranges /3/ confirmed the validity of the model and the discrepancy between observed and expected transport rates of the GeSe-GeI₄ system in microgravity.     

The cold summer mesopause

One of the most characteristic features of the summer mesopause at high latitudes is the very low temperature. Earlier measurements have shown temperatures in the range down to 135 K around 86 km altitude, whereas the most recent $\text{in situ}$ measurements have revealed temperatures still much lower than that in a rather wide altitude region. The reasons for these low temperatures are to be found in the dynamics of the strato- and mesospheres. Upwinds and gravity wave activity over the summer hemisphere cause efficient cooling of the atmosphere.Also other effects are caused by the updrafts. The vertical transport velocity for important minor constituents is increased, which for instance causes the concentration of water vapor around the mesopause to be enhanced by large factors. This situation is of major importance for the possibility of forming noctilucent clouds (NLC).NLC are believed to be composed of small water ice particles, which because of the low temperatures can be formed on existing condensation nuclei. Two of the main questions regarding the formation of NLC concern the water vapor budget of the upper mesosphere and the origin of the condensation nuclei.This paper gives a general introduction to mesospheric physics and composition. Some results from recent satellite and rocket experiments are reviewed and the campaign layout and the performed experiments within the MAP project CAMP are described. The results from the different experiments are presented in four accompanying papers on CAMP results.     

Validation on MERSI/FY-3A precipitable water vapor product

The precipitable water vapor is one of the most active gases in the atmosphere which strongly affects the climate. China's second-generation polar orbit meteorological satellite FY-3A equipped with a Medium Resolution Spectral Imager (MERSI) is able to detect atmospheric water vapor. In this paper, water vapor data from AERONET, radiosonde and MODIS were used to validate the accuracy of the MERSI water vapor product in the different seasons and climatic regions of East Asia. The results show that the values of MERSI water vapor product are relatively lower than that of the other instruments and its accuracy is generally lower. The mean bias (MB) was ?0.8 to ?12.7?mm, the root mean square error (RMSE) was 2.2–17.0?mm, and the mean absolute percentage error (MAPE) varied from 31.8% to 44.1%. On the spatial variation, the accuracy of MERSI water vapor product in a descending order was from North China, West China, Japan -Korea, East China, to South China, while the seasonal variation of accuracy was the best for winter, followed by spring, then in autumn and the lowest in summer. It was found that the errors of MERSI water vapor product was mainly due to the low accuracy of radiation calibration of the MERSI absorption channel, along with the inaccurate look-up table of apparent reflectance and water vapor within the water vapor retrieved algorithm. In addition, the surface reflectance, the mixed pixels of image cloud, the humidity and temperature of atmospheric vertical profile and the haze were also found to have affected the accuracy of MERSI water vapor product.     

Convective flow structure in a growth ampoule

The hydrodynamic aspects of physical vapor transport processes in growth ampoules are considered experimentally. The apparatus consists of a horizontal cylinder filled with air and subjected to a constant horizontal temperature gradient. The apparatus is made transparent by using a glass cylinder coated with a thin film of SnO₂ which is used as a heater by passing a constant electrical current through it. The cylinder has inside diameter D=18.3 mm and length L=90mm. The Rayleigh number is varied between 444 and 1425. A Laser-Doppler anemometer is used to obtain the velocity field along the axis and various diameters of the cylinder. The 3-D convective structure obtained by flow visualisation and confirmed by velocity measurements is illustrated. The influence of the boundary conditions on the flow structure is examined and experimental results are compared to 2-D computations.     

蒸气在铜表面冷凝的可视化实验

通过建立蒸气冷凝过程的可视化实验装置,在地面重力条件下对蒸气在铜表面的冷凝情况进行实验.采用高速摄像仪对蒸气在铜表面上发生的冷凝过程进行观测,并对比分析了H₂O,R141b以及FC-72蒸气的冷凝情况.研究发现水蒸气在冷凝过程中一些大液滴在合并周围小液滴后会发生回弹现象,从而清理掉周边区域的小液滴.随着冷凝的进行,被清理掉小液滴的区域又会重新生成小液滴.这种回弹现象相当于延长了滴状冷凝的时间,从而起到强化冷凝换热效果.R141b及FC-72在光滑铜表面上均未发生滴状冷凝.在加大过冷度后,冷凝器内残留的空气还会在冷凝液膜上冷凝成小水滴,产生滴膜共存现象.水蒸气在铜表面冷凝过程中,滴状冷凝转换成膜状冷凝后热流量降低约20%,因此需要对铜表面进行改性处理,降低其表面能,从而强化冷凝换热.      

Global monitoring of tropospheric water vapor with GPS radio occultation aboard CHAMP

The global positioning system radio occultation (GPS RO) technique provides a powerful tool for atmospheric sounding which requires no calibration, is not affected by clouds, aerosols or precipitation, and provides an almost uniform global coverage. The paper deals with application of GPS RO measurements from CHAllenging Minisatellite Payload (CHAMP) for the retrieval of tropospheric water vapor profiles. CHAMP RO data are available since 2001 with up to 200 high resolution atmospheric profiles per day. We introduce a new direct method for water vapor retrieval from GPS RO data. Additionally, a 1Dvar algorithm is used for this purpose. The so derived CHAMP water vapor profiles are validated with radiosonde data on a global scale. Here, both methods come to statistically comparable results revealing a negative bias of less than 0.1 g/kg and a standard deviation of less than 1 g/kg specific humidity in the mid troposphere. Potentials of CHAMP RO retrievals for monitoring the mean tropospheric water vapor distribution on a global scale are presented.     

Water vapor in the stratosphere: Preliminary results of the LIMS experiment aboard NiMBUS 7

The validation status of the LIMS (Limb Infrared Monitor of the Stratosphere) measurements in the water vapor channel is presented in a brief form. The agreement with other water vapor data taken in correlative balloon underflights is encouraging for this stage of the processing. Future efforts will be made to resolve remaining discrepancies so that operational reduction can begin. Preliminary maps for atmospheric layers between 50 mb and 1 mb show a fairly smooth water vapor field in the summer hemisphere.     

Farming in space: environmental and biophysical concerns.

The colonization of space will depend on our ability to routinely provide for the metabolic needs (oxygen, water, and food) of a crew with minimal re-supply from Earth. On Earth, these functions are facilitated by the cultivation of plant crops, thus it is important to develop plant-based food production systems to sustain the presence of mankind in space. Farming practices on earth have evolved for thousands of years to meet both the demands of an ever-increasing population and the availability of scarce resources, and now these practices must adapt to accommodate the effects of global warming. Similar challenges are expected when earth-based agricultural practices are adapted for space-based agriculture. A key variable in space is gravity; planets (e.g. Mars, 1/3 g) and moons (e.g. Earth's moon, 1/6 g) differ from spacecraft orbiting the Earth (e.g. Space stations) or orbital transfer vehicles that are subject to microgravity. The movement of heat, water vapor, CO2 and O2 between plant surfaces and their environment is also affected by gravity. In microgravity, these processes may also be affected by reduced mass transport and thicker boundary layers around plant organs caused by the absence of buoyancy dependent convective transport. Future space farmers will have to adapt their practices to accommodate microgravity, high and low extremes in ambient temperatures, reduced atmospheric pressures, atmospheres containing high volatile organic carbon contents, and elevated to super-elevated CO2 concentrations. Farming in space must also be carried out within power-, volume-, and mass-limited life support systems and must share resources with manned crews. Improved lighting and sensor technologies will have to be developed and tested for use in space. These developments should also help make crop production in terrestrial controlled environments (plant growth chambers and greenhouses) more efficient and, therefore, make these alternative agricultural systems more economically feasible food production systems.     

Tomographic determination of the spatial distribution of water vapor using GPS observations

With the advent of the GPS navigation system, a promising ground based technique has been introduced which makes it possible to estimate the amount of water vapor in the troposphere from operational GPS networks at relatively low additional costs. While the estimation of the integrated amount is currently well established, the determination of the spatial water vapor distribution and its temporal variation are still a major challenge. To account for the vertical resolution, several tomographic approaches were pursued. We developed the software package AWATOS (atmospheric water vapor tomography software) which is based on the assimilation of double differenced GPS observations. Applying a least-squares inversion, the inhomogeneous spatial distribution of water vapor is determined. An extensive investigation has been carried out in Switzerland. GPS measurements are performed by the dense permanent Swiss national GPS network AGNES of the Swiss Federal Office of Topography (swisstopo). A total of 40 equally distributed water vapor profiles have been estimated on an hourly basis. For the purpose of validation, 22 radiosonde profiles were used at the GPS and meteorological station Payerne. Furthermore, data of the numerical weather model aLMo (alpine model in Switzerland, MeteoSwiss) were compared with the tomographic results. An overall good agreement of the three methods with an rms of better than 1.6 g/m³ absolute humidity was achieved. The results show that AGNES can be used as a dedicated network for the purpose of GPS-tomography, using a horizontal resolution of approximately 50 km and height layers of 300–500 m thickness in the lower troposphere.     

Determination of window frequency in the millimeter wave band in the range of 58° north through 45° south over the globe

The radiosonde data available from British Atmospheric Data Centre (BADC) for the latitudinal occupancy of 58° north through 45° south were analyzed to observe the variation of temperature and water vapor density. These two climatological parameters are largely assumed to be the influencing factors in determining the millimeter wave window frequencies over the chosen range of latitudes in between the two successive maxima occurring at 60 and 120 GHz. It is observed that between temperature and water vapor density, the later one is influencing mostly in determining the window frequency. It is also observed that the minima is occurring at 75 GHz through 94 GHz over the globe during the month January–February and 73 GHz through 85 GHz during the month July–August, depending on the latitudinal occupancy. It is observed that the large abundance of water vapor is mainly held responsible for shifting of minima towards the low value of frequencies. Hence, it is becoming most important to look at the climatological parameters in determining the window frequency at the place of choice.     

The problem of indirect sounding of high clouds

Remote sounding of high cloud top temperatures by passive methods is a difficult venture due to the semitransparency of the clouds. Window channel measurements often overestimate the cloud top temperature. In this study it is experimentally shown and supported by theoretical considerations that water vapor channels, which are originally intended to sense the high tropospheric water vapor content, are more suitable than window channels. In addition, it is shown that measurements in the H₂O rotational band are superior to 6.3 μm channels due to higher intensity of the outgoing radiation and less contribution by scattering by cloud particles.     

Retrieval of the change of precipitable water vapor with zenith tropospheric delay in the Chinese mainland

As a preliminary step for assessing the impact of global positioning system (GPS) refractive delay data in numerical weather prediction (NWP) models, the GPS zenith tropospheric delays (ZTD) are analyzed from 28 permanent GPS sites in the Chinese mainland. The objectives are to estimate the GPS ZTD and their variability in this area. The differences between radiosonde precipitable water vapor (PWV) and GPS PWV have a standard deviation of 4 mm in delay, a bias of 0.24 mm in delay, and a correlation coefficient of 0.94. The correlation between GPS ZTD and radiosonde PWV amounts to 0.89, indicating that the variety of tropospheric zenith delay can reflect the change of precipitable water vapor. The good agreement also guarantees that the information provided by GPS will benefit the NWP models. The time series of GPS ZTD, which were derived continuously from 2002 to 2004, are used to analyze the change of precipitable water vapor in Chinese mainland. It shows that the general trend of GPS ZTD is diminishing from the south-east coastland to the north-west inland, which is in accordance with the distribution of Chinese annual amount of rainfall. The temporal distribution of GPS ZTD in the Chinese mainland is that the GPS ZTD reaches maximum in summer, and it reaches minimum in winter. The long term differences between the observational data sources require further study before GPS derived data become useful for climate studies.     

Effect of vapor condensation on ascending performance of stratospheric airship

This paper reports a numerical investigation on the effects of water vapor condensing inside the air bag of a stratospheric airship on its ascending performance. The kinetic and thermal model considering vapor condensation was established, based on which a computer program was written in Fortran. The simulation results show that the vapor condensation remarkably affects the kinetic and thermal characteristics of the stratospheric airship in the ascent process. During the ascent process below 11 km, a large amount of latent heat is released when the water vapor in the air inside the air bag of the stratospheric airship condenses, which results in the increase of the temperature and the reduction of the weight of the air in the air bag, causing the airship to speed up, the accelerated expansion of the helium, and the decrease of the helium temperature in the helium bag. When the flight altitude is higher than 11 km, the effect of vapor condensation on the kinetic and thermal characteristics of the stratospheric airship is negligible because vapor is virtually nonexistent in the air.     

The limb infrared monitor of the stratosphere (LIMS) experiment: Temperature and nitrogen dioxide results

The Limb Infrared Monitor of the Stratosphere (LIMS) is a 6 channel scanning radiometer which measures the infrared emission by the earth's limb. These measurements are inverted to yield distributions of temperature, ozone, water vapor, nitric acid and nitrogen dioxide. The instrumentation and its orbital performance are briefly described. Retrievals of temperature and nitrogen dioxide are presented, with a discussion of their precision. Comparisons to in-situ rocket and balloon measurements are used to assess their accuracy. Special mention is made of the temperature data supplied for the FGGE II-b data sets. Results for ozone, water vapor and nitric acid are presented in companion papers.     

地外撞击球粒的成因探讨：以K／T界面事件为例

本文对KTB地层中富含尖晶石的地外撞击球粒的成份、矿物组成、构造特点等进行了系统研究,通过陨石消熔模拟实验的分析,以及陨石消融成因模式和撞击汽云凝聚成因模式的对比研究,认为该类球粒在成因上既有消融成因的球粒,又有撞击汽云凝聚成因的球粒,并且可能同时存在另外一种成因机制的球粒．     

Vapor compression distiller and membrane technology for water revitalization.

Water revitalization for a space station can consist of membrane filtration processes and a distillation process. Water recycling equipment using membrane filtration processes was manufactured for ground testing. It was assembled using commercially available components. Two systems for the distillation are studied; one is an absorption type thermopervaporation cell and the other is a vapor compression distiller. Absorption type thermopervaporation able to easily produce condensed water under zero gravity was investigated experimentally and through simulated calculation. The vapor compression distiller was studied experimentally and it offers significant energy savings for evaporation of water.     

Time distribution of the precipitable water vapor in central Saudi Arabia and its relationship to solar activity

Water vapor is the most important greenhouse gas. It plays a major role in the dynamics of atmospheric circulation, radiation exchange within the atmosphere, and climate variability. Knowledge of the distribution of water vapor is important for understanding climate change and global warming.