THE CONVECTIVE EFFECT ON THE MORPHOLOGICAL INSTABILITY OF KNbO3 CRYSTALS

Experimentally, it was observed that there were various morphologies of KNbO3 crystals in different regions of the melt of Li2B4O7 and KNbO3 mixture in Pt loop heater. Dendrites grew in the central area of the melt, the diffusive-advective region,in which the temperature gradient is negligible; whereas crystals with smooth sur face were observed in the marginal area, the diffusive-convective region, with large temperature gradient. Based on the solute concentration over the KNbO3 crystal surface examined by electronic probe analysis, it was proved that the combinative effect of buoyancy and surface tension convection induced by temperature gradient enhanced the homogeneity of the solute concentration around KNbO3 crystals and thus their morphological stability.     

Macrosegregation during crystal growth in horizontal bridgman boat

This paper is devoted to direct numerical simulation of the fluid flow and macrosegregation in horizontal Bridgman systems. Results concerning the fluid flows at Pr=0 and Pr=0.015 are given for various values of Gr and in situation where the melt-crystal interface is at rest. Practical laws concerning the behaviour of the mass transport and the level of inhomogeneity in the cavity are derived. The effects of some parameters such as Gr, Sc and the pulling speed on the concentration repartition in the two phases melt and crystal are studied and the average concentration in the crystal is shown for various situations.     

INTERFACIAL MASS TRANSPORT IN OXIDE CRYSTAL GROWTH

A space high temperature in situobservation instrument (SHITISOI) is dedicated to visualize and record the whole growth process of oxide crystal in high temperature melts and solutions. Model experiments using transparent liquids such as KNbO3,Li2B4O7+KNbO3 were chosen to investigate effects of interracial mass transport in oxide crystal growth. For the scaling of the coupled velocity, heat and concentration fields in KNbO3 crystal growth, a rotating crystal growth process was performed and the widths of interfacial concentration, heat and momentum transition zones (The "boundary layers") are obtained, which are 7.5×10-a, 8.6×10-2 and 4.4×10-1 cm,respectively. Hence one can expect that interfacial concentration gradient will be confined to a narrow layer and in region of major concentration change at the in terface. In order to study a mechanism based on the interfacial mass transport resulting from hydrodynamics, the growth of KNbO3 grain in high temperature Li2B4O7 and KNbO3 solutin was studied. The result shows that the pivotal feature in the KNbO3 crystal growth is the initiated by KNbO3 solute surface tension gra dient which is caused by the slow diffusion of KNbO3 solutes. Direct comparison of the model predictions and experimental observed phenomena demonstrate the predictive capability of this model.     

Gravitational influence on binary alloy melt equilibria

Micro- and macrosegregation, the nonuniform redistribution of solute during solidification, are common to both casting and welding, processes of fundamental importance in materials engineering. In multicomponent crystal growth where solid/liquid density differences are appreciable gravity-induced separation can lead to significant spatial variations in resulting ingot composition. In fact, this phenomenon is also operative in liquid/liquid systems such as monotectic alloys exhibiting a liquid miscibility gap, where buoyancy-driven flows can result in a sometimes unwanted separation of phases upon cooling through the miscibility dome.     

在空间微重力下生长碲镉汞晶体

本文叙述了我国首次在空间微重力下进行的碲镉汞(MCT)晶体生长试验及一些观测结果。生长是从熔体进行的。在空间90min的加热时间内,将MCT多晶试样熔化,然后随炉冷却,最后在地面上再结晶。于是,生长出约3cm长的晶体,其表面光滑.结构致密,无孔洞,由1～3个大晶粒组成,其中单晶占74%。X射线能量色散分析(EDS)表明,其径向组分均匀性优于±0.02,其中约1cm长的一段晶体的径向组分均匀性优于±0.01。电学特性与地面上生长的样品基本相同。     

微重力条件下红外材料的空间生长

根据近年红外材料在空间生长的研究概况,分析了涵盖熔体、气相、液相外延和分子束外延等生长方法及各个方法生长红外材料的基本原理,在地面生长遇到的问题,以及在空间微重力环境中进行红外材料生长的优势.同时基于中国利用熔体法在天宫二号上已经进行的ZnTe:Cu晶体的空间生长科学实验及地基实验结果,通过对空间和地面实验结果进行对比,提出了在超高真空环境下,利用分子束外延方式生长高性能、大尺寸红外材料的可能性,以及未来在空间微重力条件下进行红外材料生长的研究方向及具体应用.      

微重力与电磁场对凝固过程的影响

欧洲空间局两项材料领域课题MICAST和CETSOL均涉及微重力科学相关研究.通过等轴晶柱状晶转变（CET）分析了微重力环境对材料凝固过程的影响;介绍了一项在地面施加行波电磁场的标准（Benchmark）凝固实验,其温度场演化及微观凝固组织和浓度偏析均展示了磁控受迫对流对金属材料凝固过程的显著作用.      

Solidification of GeSi solid solution in near-zero-G conditions

In summary, it should be stated that the existing theories of segregation during directional crystallization which consider mass transport in melt due only to either concentration diffusion or convective stirring (or both) cannot account for solute segregation picture observed in solid solution crystals which have been obtained aboard Apollo-Soyuz orbital complex. To do this, some other, new models are required.     

NUMERICAL MODELLING OF VELOCITY AND TEMPERATURE DISTRIBUTIONS OF THE BUOYANCY CONVECTION EFFECT IN KNbO3 MELT

Numerical modelling of velocity and temperature fields in high-temperature KNbO3 melt of a loop-shaped Pt wire heater is carried out by using the commercial com putational code ANSYS for the mathematical solution of the governing equations.Based on the experimental boundary conditions and the Boussinesq approximation,the numerical modelling of a steady and two-dimensional model is applied to study the process under consideration of the buoyancy-driven convection condition. The result is compared with the previous experimental and theoretical data obtained in our laboratory, and the former is in agreement with the latter. Thus a theoretical guide for reasonable growth conditions is provided by studying in depth the real fluid flow effects in the crystal growth from the melt.     

Convective motions in liquid metals for material processings. Numerical simulation of oscillation regimes and effect of rotation

The paper is concerned with the numerical simulation and the analysis of some kinds of flow regimes which can develop in Bridgman and Czochralski systems for material processings. The flows in the liquid phase are investigated considering two-dimensional and axisymmetric models. The time-dependent regimes were studied for a zero-Prandtl-number fluid layer confined inside a two-dimensional cavity of aspect ratio (length-to-height) A=4, involving a stress-free upper surface and submitted to a horizontal temperature gradient. The range of Grashof number was varied up to the conditions at which the flow goes from oscillatory to chaotic type behaviours. The combined influence of the temperature gradients and of the rotations of the crucible and of the seed/crystal was investigated for a Czochralski model. The axisymmetric regimes were studied for a Pr_m=0.015 liquid melt confined inside a cylindrical crucible of aspect ratio (height-to-radius) A_m=2, and coupled to a viscous encapsulant liquid layer (10<Pr_e<1200) of aspect ratio A_e=0.5. A number of steady and (transient) time-dependent flow patterns are identified.     

Protein crystal growth--microgravity aspects.

Protein crystals, grown under reduced gravity conditions, are either superior or inferior in their structural perfection than their Earth-grown counterparts. A reduction of the crystals' quality due to low-gravity effects on the growth processes cannot be understood from existing models. In this paper we put forth a rationale which predicts either advantages or disadvantages of microgravity growth. This rationale is based on the changes in the effective solute and impurity supply rates in microgravity and their effects on the intrinsic growth rate fluctuations that arise from the coupling of bulk transport to nonlinear interfacial kinetics and cause severe inhomogeneities. Depending on the specific diffusivity and kinetic coefficient of a protein and the impurities in the solution, either transport enhancement through forced flow or transport suppression under reduced gravity can result in a reduction of the kinetic fluctuations and, thus, growth with higher structural perfection. Investigating this mechanism of microgravity effects, we first demonstrate a one-to-one correspondence between these fluctuations, that are due to the bunching of growth steps, and the formation of defects in the crystals. We have confirmed the forced flow aspects of this rationale in ground-based experiments with lysozyme utilizing flowing solutions with varying, well characterized impurity contents.     

High resolution measurements of nightside ion troughs at venus: Evidence of electrodynamic perturbations

The Bennett rf ion mass spectrometer (OIMS) on the Pioneer Venus Orbiter was particularly designed to provide variable temporal resolution for measurements of thermal ion composition and density. An Explore-Adapt mode is used to obtain priority for measurement of most prominent ion species, and in a 2/16 configuration, the two dominant ions within the available range of 16 species are selectively sampled at the highest rate of 0.2 sec/sample. The high resolution measurements are combined with independent observations from the magnetic field (OMAG), neutral mass spectrometer (ONMS), and electron temperature (OETP) experiments to investigate sharply structured troughs in the low altitude nightside ion concentrations. The results indicate a close correlation between the structure in the ion distributions and the structured configuration of the magnetic field which is draped about the planet. In the regions of the ion depletions, sharp fluctuations in electron temperature and anomalous increases in the density of neutral gases indicate that the ion depletion may be associated either with dynamic perturbation in the ion and neutral flows, and/or local joule heating. The configuration of the ion flow/magnetic field draping and consequent electric fields for these events must be analyzed in detail to understand the relationships.     

Computational fluid dynamics and material processing (buoyancy and thermocapillary convections in melts during directional crystallization)

Modelisation and solution of heat and mass transfer problems relevant for material processing are generally hard to be handled, as they often involve 3D unsteady flows, viscous mixtures, phase changes, moving liquid-solid fronts, deforming liquid-gas interfaces, etc.… For space applications, material processing benefits of reduced buoyancy convection but can be faced to a strongly increased complexity due to variable g, mainly in manned flight.

Computational techniques used to analyse fluid motions in material processing, accounting for free surface, crystallization front and bulk convection in melt, are reviewed with emphasis to directional crystallization. Hydrodynamics stability and bifurcation analysis are shown to be useful complementary tools for correlating data, and for a better understanding of the physical laws. This last point will be illustrated in the case of the onset of oscillations in metallic melts.     

INTERBALL statistical study of ion flow fluctuations in the plasma sheet

We use ion distribution measurements with CORALL instrument on-board the INTERBALL/Tail spacecraft to study plasma flows in the mid-tail (−9> X> −27 R_E) plasma sheet. Three velocity components computed every 2 minutes exhibit two types of velocity variations: Earthward bursty bulk flows (BBFs) and random flow fluctuations. Their properties are in a good agreement with the observations of the ISEE-2 spacecraft (Borovsky et al., 1997). The INTERBALL/Tail spacecraft configuration favors measurements of V_z component, in contrast to previous experiments in which only V_x and V_y were measured reliably. In the outer part of the plasma sheet V_y and V_z fluctuations were close to each other (variances σ(V_y) and σ(V_z) were about 160 and 110 km/s, respectively), but in the inner part at the dusk flank amplitude of V_y fluctuations increased and was 2 times higher than that of V_z component. This asymmetry of fluctuations should be taken into account during modern theoretical analysis and simulations.     

PC-index fluctuations and intermittency of the magnetospheric dynamics

One minute resolution Polar Cap (PC) index was used for the analysis of magnetospheric dynamics. The 1995–2000 time series analysis revealed that the power spectrum of the PC-index fluctuations is a power law in a wide range of frequencies. However, the obtained exponents differ for low and high frequency regions. The probability distribution functions of the PC-index fluctuations show a strong non-gaussian shape, depending on the time of increment. This indicates that the PC-index exhibits intermittency, previously detected in solar wind and auroral electrojet index fluctuations. The PC-index probability distribution functions were fitted by the functional form proposed by Castaing et al. [Velocity probability density functions of high Reynolds number turbulence. Physica D. 46, 177–200, 1990] to describe intermittency phenomena in ordinary turbulent fluid flows. The agreement between the fitting parameters obtained for the PC index and those reported before for solar wind magnetic field fluctuations is within 30%; which is noticeably less than the difference between the same parameters of solar wind and the AE-index fluctuations. This fact indicates that the PC index reflects the solar wind influence on the high-latitude magnetosphere, especially during the summer.     

Convection and impurity distribution in crystal growth in low-gravity environments

Investigations conducted earlier by the authors have established that due to the steady-state field of body forces, convection is capable of giving rise to macroinhomogeneity in transverse impurity distribution in crystals. In the case of semiconductor materials the maximal value of this inhomogeneity is due to a weak convection in the melt, typical of low-gravity conditions. However, in addition to steady gravitational convection, other factors ignored previously, may also be employed in conducting experiments in low-g environments. The present paper discusses the results of theoretical studies of some factors influencing impurity distribution in the melt and the crystal.     

使用Gao-Yong湍流方程计算翼体角偶流动

Gao-Yong湍流方程基于侧偏统计平均方法保留了湍流脉动量的一阶统计信息,并引入加权漂移速度对称性及正交各向异性,导出漂移流连续方程、动量方程和机械能方程,最后依据湍流物理的唯象论,使用动量传输链概念模化封闭了整个方程组.大量算例验证了此方程对广泛范围的复杂湍流问题的适定性.为了进一步的工程应用,将其加入开源计算流体力学软件OpenFOAM(Open Field Operation and Manipulation)中,并就翼体角偶流动进行了数值模拟.翼体角偶流动具有三维分离、马蹄涡等十分复杂的流动特征,通过与实验测量结果的对比研究表明,Gao-Yong湍流方程不论在定性还是定量上,都成功捕捉到这类复杂流动现象的主要特征,得到了令人满意的结果.     

低热层臭氧含量振荡和温度起伏间的耦合关系

本文求出了声重波传播过程中,低热层臭氧含量振荡和温度场起伏间的耦合关系。首次揭示出其正负相关性的内在原因和判据——动力扰动尺度。在中小尺度声重波扰动范围内,臭氧含量振荡与温度场起伏是正相关的,且相关幅度可达或超过7;而在大尺度或行星尺度波范围内,则一般为负相关。此发现可解释低热层中臭氧含量快速变化及臭氧含量长时间纬圈平均值变化与温度场成负相关的观测事实。本文还在声重波尺度范围内比较了线性和非线性理论的结果,结果表明两者没有太大的差异。     

Two-component Bénard convection: Interfacial deformation,oscillatory instabilities and the onset of turbulence

Instabilities and convection in binary fluid mixtures (liquids with impurities, binary gas mixtures, etc.) have been the subject of intense research over the past decade. The major finding has been that mere ppm impurity concentration can play a drastic role in the stability of fluid layers subjected to thermal gradients. For layers open to ambient air the impurity cooperates or competes according to the sign of its migration in the thermal fields with the interfacial deformation thus leading to convective flows. For a layer enclosed between copper plates, say, the impurity can interplay with the slightest buoyancy or buoyancy variations in the environment thus amplifying this force and bringing instability under circumstances where with pure fluids no instability is expected. Recent predictions reported here refer to oscillatory instabilities with or without interfacial deformation and the onset of turbulence in the form of chaotic flows which correspond to irregular patterns with decaying correlations and broadband noise in their power spectra.