Formation of amino acid precursors in cometary ice environments by cosmic radiation.

Cometary ices are believed to contain water, carbon monoxide, methane and ammonia, and are possible sites for the formation and preservation of organic compounds relating to the origin of life. Cosmic rays, together with ultraviolet light, are among the most effective energy sources for the formation of organic compounds in space. In order to study the possibility of the formation of amino acids in comets or their precursory bodies (interstellar dust grains), several types of ice mixtures made in a cryostat at 10 K ("simulated cometary ices") were irradiated with high energy protons. After irradiation, the volatile products were analyzed with a quadrupole mass spectrometer, while temperature of the cryostat was raised to room temperature. The non-volatile products remaining in the cryostat at room temperature were collected with water. They were acid-hydrolyzed, and analyzed by ion-exchange chromatography. When an ice mixture of carbon monoxide (or methane), ammonia and water was irradiated, some hydrocarbons were formed, and amino acids such as glycine and alanine were detected in the hydrolyzate. These results suggest the possible formation of "amino acid precursors" (compounds yielding amino acids after hydrolysis) in interstellar dust grains by cosmic radiation. We previously reported that amino acid precursors were formed when simulated primitive planetary atmospheres were irradiated with cosmic ray particles. It will be of great interest to compare the amount of bioorganic compounds that were formed in the primitive earth and that brought by comets to the earth.     

Characterization of complex organic compounds formed in simulated planetary atmospheres by the action of high energy particles.

A wide variety of organic compounds, which are not simple organics but also complex organics, have been found in planets and comets. We reported that complex organics was formed in simulated planetary atmospheres by the action of high energy particles. Here we characterized the experimental products by using chromatographic and mass spectrometric techniques. A gaseous mixture of CO, N2 and H2O was irradiated with high energy protons (major components of cosmic rays). Water-soluble non-volatile substances, which gave amino acids after acid-hydrolysis, were characterized by HPLC and mass spectrometry. Major part of the products were complex compounds with molecular weight of several hundreds. Amino acid precursors were produced even when no water was incorporated with the starting materials. It was suggested that complex molecules including amino acid precursors were formed not in solution from simple molecules like HCN, but directly in gaseous phase.     

Formation of bioorganic compounds in simulated planetary atmospheres by high energy particles or photons.

Various types of organic compounds have been detected in Jupiter, Titan, and cometary coma. It is probable that organic compounds were formed in primitive Earth and Mars atmospheres. Cosmic rays and solar UV are believed to be two major energy sources for organic formation in space. We examined energetics of organic formation in simulated planetary atmospheres. Gas mixtures including a C-source (carbon monoxide or methane) and a N-source (nitrogen or ammonia) was irradiated with the followings: High energy protons or electrons from accelerators, gamma-rays from 60Co, UV light from a deuterium lamp, and soft X-rays or UV light from an electron synchrotron. Amino acids were detected in the products of particles, gamma-rays and soft X-rays irradiation from each gas mixture examined. UV light gave, however, no amino acid precursors in the gas mixture of carbon monoxide, nitrogen and nitrogen. It gave only a trace of them in the gas mixture of carbon monoxide, ammonia and water or that of methane, nitrogen and water. Yield of amino acid precursors by photons greatly depended on their wavelength. These results suggest that nitrogen-containing organic compounds like amino acid precursors were formed chiefly with high energy particles, not UV photons, in Titan or primitive Earth/Mars atmospheres where ammonia is not available as a predominant N-source.     

Formation of oligopeptides on the surface of small bodies in solar system by cosmic radiation.

The present experiment indicates that oligopeptides are easily produced in solid state from mixtures of simple amino acids by irradiating with high energy charged particles. We investigated such amino acids and their mixtures as tryptophan, tyrosine and glycine. The thin films was irradiated with protons (6.6 MeV). Such dipeptides as Trp-Trp, Gly-Tyr, Tyr-Gly, and Tyr-Tyr have been detected as products of irradiation. Cosmic rays might be an effective energy source for abiotic formation of bioorganic compounds on the surface of small bodies in the solar system on early stage of formation of planets as well as at present day.     

Possible complex organic compounds on Mars.

It is suggested that primitive Mars had somehow similar environments as primitive Earth. If life was born on the primitive earth using organic compounds which were produced from the early Earth environment, the same types of organic compounds were also formed on primitive Mars. Such organic compounds might have been preserved on Mars still now. We are studying possible organic formation on primitive and present Mars. A gaseous mixture of CO2, CO, N2 and H2O with various mixing ratios were irradiated with high energy protons (major components of cosmic rays). Hydrogen cyanide and formaldehyde were detected among volatile products, and yellow-brown-colored water-soluble non-volatile substances were produced, which gave amino acids after acid-hydrolysis. Major part of "amino acid precursors" were not simple molecules like aminonitriles, but complex compounds which eluted earlier than free amino acids in cation-exchange HPLC. These organic compounds should be major targets in the future Mars mission. Strategy for the detection of the complex organics on Mars will be discussed.     

Effect of random nature of cosmic ray sources – Supernova remnants – on cosmic ray intensity fluctuations,anisotropy, and electron energy spectrum

The random nature of sources (the supernova remnants) leads to the fluctuations of cosmic ray intensity in space and time. We calculate the expected fluctuations in a flat-halo diffusion model for particles with energies from 0.1 to 10³ TeV. The data on energy spectra and anisotropy of very high energy protons, nuclei and electrons, and the astronomical data on supernova remnants, the potential sources of cosmic rays, are used to constrain the value of the cosmic-ray diffusion coefficient and its dependence on energy.     

Ion production and ionization effect in the atmosphere during the Bastille day GLE 59 due to high energy SEPs

The influence of high energy particles, specifically cosmic rays, on atmospheric physics and chemistry is highly discussed. In most of the proposed models the role of ionization in the atmosphere due to cosmic rays is not negligible. Moreover, effect(s) on minor constituents and aerosols are recently observed, specifically over the polar regions during strong solar particle events. According to the recent findings for such effects it is necessary an essential increase of ion production, specifically during the winter period. The galactic cosmic rays are the main source of ionization in the Earth’s stratosphere and troposphere. Occasionally, the atmospheric ionization is significantly enhanced during strong solar energetic particles events, specifically over the polar caps. During the solar cycle 23 several strong ground level enhancements were observed. One of the strongest was the Bastille day event occurred on 14 July 2000. Using a full Monte Carlo 3-D model, we compute the atmospheric ionization, considering explicitly the contribution of cosmic rays with galactic and solar origin, focusing on high energy particles. The model is based on atmospheric cascade simulation with the PLANETOCOSMICS code. The ion production rate is computed as a function of the altitude above the sea level. The ion production rate is computed on a step ranging from 10 to 30?min throughout the event, considering explicitly the spectral and angular characteristics of the high energy part of solar protons as well as their time evolution. The corresponding event averaged ionization effect relative to the average due to galactic cosmic rays is computed in lower stratosphere and upper troposphere at various altitudes, namely 20?km, 15?km, 12?km and 8?km above the sea level in a sub-polar and polar regions. The 24^h and the weekly ionization effects are also computed in the troposphere and low stratosphere. Several applications are discussed.     

Radiation-induced syntheses in cometary simulated models.

The behavior of an aqueous-dominant multicomponent cometary model is examined at high doses of ionizing radiation. The system is composed of a water mixture of HCN (0.2 mol dm-3), CH3CN (0.04 mol dm-3), C2H5CN (0.02 mol dm-3), CH3OH (0.12 mol dm-3) and HCO2H (0.01 mol dm-3. It was exposed to gamma rays at doses up to 18.5 MGy. The chemical kinetic database used in the computer treatment of experimental data consists of 79 reactions. A complex mixture of products has been synthesized: gases, amino acids, carboxylic acids and polymeric material. The results suggest that the pristine material in cometary nuclei may have been chemically altered by the action of cosmic rays and embedded radionuclides.     

Microelectronics effects as seen on CRRES.

A MicroElectronics Test Package (MEP) measured total dose degradation and single event upsets (SEUs) on 60 device types on the Combined Release and Radiation Effects Satellite (CRRES) in an 18 degrees inclination orbit between 350 km and 36000 km from July 1990 to October 1991. Simultaneous measurements of the high energy particle environment were used to make a direct cause and effect comparison of the energetic particle backgrounds and microelectronic performance characteristics. The galactic cosmic ray background for the period of the CRRES mission was at a minimum. The SEUs experienced from the cosmic ray background were correspondingly few in number, but surprisingly produced an equal probability of upset over an L-shell range of 8.5 Earth radii (RE) down to less than 3.0 RE. Cosmic ray induced upset frequencies in proton sensitive chips were over 2 orders of magnitude lower than those produced by protons in the heart of the inner proton radiation belts. Multiple upsets, those produced when a single particle upsets more than one memory location, were just as common from protons as from cosmic rays.     

Peculiarities of the solar proton events of 19 October 1989 and 23 March 1991 according to the measurements onboard the Mir space station.

Flux and dose rate dynamics of solar cosmic rays were measured by the Lyulin dosimeter during the events 19 October 1989 and 23 March 1991. The maximum dose rate registered was 0.4, 0.12 and 0.01 cGy/hour, respectively. Based on the latitude distribution of particle flux a power law form for the energy spectra of solar protons in the anisotropic phase of the events on 19 October 1989 and 23 March 1991 was determined. It was obtained that after the development of geomagnetic storm protons with energies more than 1 GeV were registered.     

Relative biological effectiveness and microdosimetry of a mixed energy field of protons up to 200 MeV.

We have studied radiation effects utilizing the new 250 MeV Synchrotron at Loma Linda University Medical Center. In this paper we present the data collected for the survival of Chinese hamster lung (V79) cells, that were irradiated with a beam of mixed energy protons up to 200 MeV. The RBE for protons, when compared to 60Co gamma rays, ranged from a low of 1.2 at the high energy portion of the field to 1.3+ at the low energy portion of the field. These results are consistent with the measured lineal energy (microdosimetric) spectra.     

The influence of interplanetary shocks on solar protons measured in the stratosphere.

Since the beginning of the 22nd solar cycle twenty solar proton events were observed by the regular balloon measurements of cosmic rays. Temporal changes of intensities and energy spectra of solar protons with energy 100-500 MeV were obtained. The strong influence of interplanetary shock waves on the proton flux characteristics near the Earth was observed. Possible effects of solar proton transport in the vicinity of shock fronts are discussed to explain the observational data.     

The effects of proton exposure on neurochemistry and behavior.

Future space missions will involve long-term travel beyond the magnetic field of the Earth, where astronauts will be exposed to radiation hazards such as those that arise from galactic cosmic rays. Galactic cosmic rays are composed of protons, alpha particles, and particles of high energy and charge (HZE particles). Research by our group has shown that exposure to HZE particles, primarily 600 MeV/n and 1 GeV/n 56Fe, can produce significant alterations in brain neurochemistry and behavior. However, given that protons can make up a significant portion of the radiation spectrum, it is important to study their effects on neural functioning and on related performance. Therefore, these studies examined the effects of exposure to proton irradiation on neurochemical and behavioral endpoints, including dopaminergic functioning, amphetamine-induced conditioned taste aversion learning, and spatial learning and memory as measured by the Morris water maze. Male Sprague-Dawley rats received a dose of 0, 1.5, 3.0 or 4.0 Gy of 250 MeV protons at Loma Linda University and were tested in the different behavioral tests at various times following exposure. Results showed that there was no effect of proton irradiation at any dose on any of the endpoints measured. Therefore, there is a contrast between the insignificant effects of high dose proton exposure and the dramatic effectiveness of low dose (<0.1 Gy) exposures to 56Fe particles on both neurochemical and behavioral endpoints.     

Antiparticle content in the magnetosphere

In the present work we assess the stable and transient antiparticle content of planetary magnetospheres, and subsequently we consider their capture and application to high delta-v space propulsion. We estimate the total antiparticle mass contained within the Earth’s magnetosphere to assess the expediency of such usage. Using Earth’s magnetic field region as an example, we have considered the various source mechanisms that are applicable to a planetary magnetosphere, the confinement duration versus transport processes, and the antiparticle loss mechanisms. We have estimated the content of the trapped population of antiparticles magnetically confined following production in the exosphere due to nuclear interactions between high energy cosmic rays (CR) and constituents of the residual planetary upper atmosphere.The galactic antiprotons that directly penetrate into the Earth’s magnetosphere are themselves secondary by its nature, i.e. produced in nuclear reactions of the cosmic rays passing through the interstellar matter. These antiproton fluxes are modified, dependent on energy, when penetrating into the heliosphere and subsequently into planetary magnetospheres. During its lifetime in the Galaxy, CR pass through the small grammage of the interstellar matter where they produce secondary antiprotons. In contrast to this, antiprotons generated by the same CR in magnetosphere are locally produced at a path length of several tens g/cm² of matter in the ambient planetary upper atmosphere. Due to the latter process, the resulting magnetically confined fluxes significantly exceed the fluxes of the galactic antiprotons in the Earth’s vicinity by up to two orders of magnitude at some energies.The radiation belt antiparticles can possibly be extracted with an electromagnetic-based “scoop” device. The antiparticles could be concentrated by and then stored within the superimposed magnetic field structure of such a device. In future developments, it is anticipated that the energy of the captured antiparticles (both rest energy and kinetic energy) can be adapted for use as a fuel for propelling spacecraft to high velocities for remote solar system missions.     

1998年9月24日地磁暴前宇宙线各向异性特性分析

分析了日本Nagoya 宇宙线闪烁体望远镜30°, 49°, 64° 倾角的东、西、南、北方向探测数据的变化特点, 运用小波分析方法定性地探讨了磁暴前后宇宙线南北、东西各向异性的变化特征. 研究发现, 当发 生大地磁暴时, 地面宇宙线强度的各向异性特征将发生非常大的变化, 这种变化一般在磁暴发生前10~20 h就开始出现. 当描述这种各向异性特征的各向异性指数的小波系数变化达到一定阈值时, 就可能有大地磁暴发生.      

Empirical model of cosmic ray spectrum in energy interval 1 MeV–100 GeV during 11-year solar cycle

The galactic cosmic rays (GCR) are the main ionization source at altitude of ∼3–35 km in the atmosphere. For high latitude anomalous cosmic ray (ACR) component has also a significant influence on the atmospheric ionization. We propose an empirical model for differential spectra D(E) of galactic and anomalous cosmic rays in energy interval 1 MeV–100 GeV during solar cycle. In the model data are used which cover three solar cycles: 20, 22 and 23. The LEAP87, IMAX92, CAPRICE94, AMS98 and BESS experimental spectra for protons and alpha particles are fitted to the proposed empirical model. The modulated GCR differential spectra are compared with force-field approximation to the one-dimensional transport equation and with solutions of two-dimensional cosmic ray transport equation. For experimental spectra, the calculation of the model parameters is performed by Levenberg–Marquardt algorithm, applied to the special case of least squares. Algorithm that combines the rapid local convergence of Newton–Raphson method with globally convergent method for non-linear systems of equations is applied for theoretically obtained differential spectra. The described programmes are realized in algorithmic language C++. The proposed model gives practical possibility for investigation of experimental data from measurements of galactic cosmic rays and their anomalous component.     

Measurements of LET spectra and comparison to models.

We present measurements of LET spectra for near earth orbits with various inclinations and altitudes. A comparison with calculated LET spectra shows that the contribution from direct ionizing galactic cosmic rays is well described by the models. An additional contribution to the spectra originates from stopping protons and from nuclear interactions of particles with material. In the case of an interaction a large amount of energy is deposited in a small volume by target recoils or target fragments. These events will be called short range (SR) events. For a low inclination orbit radiation belt protons are the main source of these events while galactic protons become more important when increasing the inclination to near polar orbits. We show that the contribution of SR events for orbits with low altitude (324 km) and 57 degrees inclination is comparable to that for an orbit with 28 degrees inclination at a high altitude (510 km).     

Comparison of measured cosmic ray LET spectra with models and predictions.

Radiation effects of cosmic ray nuclei are generally described as a function of the particle LET. For a large number of space missions LET spectra have been measured and models have been developed to calculate these spectra that include the effects of geomagnetic shielding and shielding provided by material. In this paper we compare measured and calculated LET spectra. For low earth orbits events with high local energy deposition, i.e., short range secondaries, contribute significantly to the measured spectra. These events are produced by nuclear interactions, mainly induced by protons from the south atlantic anomaly. The technique to include these contributions in the models depends on the size of radiation sensitive volumes. For sizes comparable to or larger than the range of target secondaries it is essential to separate contributions by target interactions from those of cosmic rays. This separation is possible in experiments which use stacks of plastic nuclear track detectors. The yield of short range events generated by protons and measured in the detector can be calibrated from accelerator experimental data. We present first results for CR-39 detectors.     

Radiation factors in space and a system for their monitoring.

The radiation environment is of special concern when the spaceship flies in deep space. The annual fluence of the galactic cosmic rays is approximately 10(8) cm-2 and the absorbed dose of the solar cosmic rays can reach 10 Gy per event behind the shielding thickness of 3-5 g cm-2 Al. For the radiation environment monitoring it is planned to place a measuring complex on the space probes "Mars" and "Spectr" flying outside the magnetosphere. This complex is to measure: cosmic rays composition, particle flux, dose equivalent, energy and LET spectra, solar X-rays spectrum. On line data transmission by the space probes permits to obtain the radiation environment data in space.     

Real-time GLE alert in the ANMODAP Center for December 13, 2006

Within the last years, a real-time system to monitor high energy cosmic rays for space weather use has been operated at Athens cosmic ray station. Neutron monitors and satellite high resolution data in real time are used, making it possible to observe cosmic rays in dual energy range observations. In large solar energetic particle (SEP) events, ground level enhancement (GLE) can provide the earliest alert for the onset of the SEP event. This system watches for count rate increases recorded in real time by 23 neutron monitors, which triggers an alarm if a ground level enhancement (GLE) of cosmic ray intensity is detected.