关于粘土/高性能环氧纳米复合材料的形态及力学性能的研究

对粘土片层在纳米粘土／高性能环氧树脂体系中的分散状态及力学性能进行了研究。通过加入较少的粘土（含量≤5wt％）得到插层型纳米复合材料。纳米粘土的存在使环氧树脂的玻璃化转变温度有所降低。粘土质量含量为2％时，复合材料的冲击强度约上升10％，但超过2％后。冲击强度随之下降。材料的弯曲强度则随着粘土含量的升高而逐步降低。     

纳米CaCO3／PPS复合材料微观结构及性能研究

纳米碳酸钙(CaCO3)与聚苯硫醚(PPS)通过熔融共混挤出制得复合材料,通过透射电镜对纳米碳酸钙的形态及粒径分布进行观察,并用原子力显微镜、力学测试等方法对复合材料微观结构和力学性能进行表征.结果表明,纳米碳酸钙的平均粒径约56nm,从复合材料表面形貌可见纳米碳酸钙分散在树脂基体里,少量粒子变形;复合材料的韧性得到明显提高,在添加量为5wt%时,冲击强度达到74.13kJ/m2,抗拉强度则在10wt%时达到最大,83.73MPa.     

聚醚酰亚胺对T700/环氧复合材料的增韧技术

采用聚醚酰亚胺(PEI)对T700/环氧复合材料进行增韧改性。实验结果表明,PEI改性后环氧树脂复合材料的韧性得到显著提高,力学性能和Tg都稍有下降;在强度满足要求的前提下,PEI含量在20wt%时,所得复合材料的韧性最好,GIC达到593.6 J/m2。     

高性能M40J/BADCy复合材料的研究

对E51环氧树脂改性双酚A型氰酸酯(BADCy)体系的力学性能及热性能进行了研究,发现当E51环氧树脂的质量含量为5%时,改性体系的弯曲强度和冲击强度分别由原来的95.6MPa和9.24kJ/m²提高到了117.8MPa和12.6kJ/m²,而热变形温度仅下降8℃。以该改性体系为基体制作的M40J复合材料,其弯曲强度、模量和剪切强度分别高达:1270MPa,172GPa,68 9MPa。消泡剂BYK141能提高M40J/BADCy复合材料的力学性能,层间剪切强度可提高到77.1MPa。M40J/BADCy复合材料还具有良好的耐环境能力,是一种理想的航空航天结构材料。     

中温固化松香基环氧树脂碳纤维增强复合材料性能

以生物质松香基马来海松酸酐(MPA)作为固化剂固化石油基E-54、AG-80和014U三种环氧树脂混合物,研究松香基环氧树脂基体及其复合材料的热性能和力学性能,评价其作为先进树脂基复合材料应用在航空飞行器主承力结构件的可能性,拓宽生物质环氧树脂应用领域。结果表明：固化后的环氧树脂具有较高的力学性能和热失重温度,配方F2树脂固化后玻璃化转变温度为156℃、拉伸强度为82.6 MPa、拉伸模量为3.05 GPa、断裂伸长率为4.2%、5%热分解温度约为370℃;以F2/U3160预浸料制备的复合材料层合板干态玻璃化转变温度为158℃,湿态玻璃化转变温度为123℃,干态力学性能与已经应用于直升机旋翼系统的3261/HT3复合材料性能相当,并具备较高的湿态力学性能保持率。     

柔性缓冲层对T300／BADCy复合材料力学性能影响研究

为增强T300/BADCy复合材料的界面性能,用E51环氧树脂/丙酮溶液对T300纤维进行表面处理,在T300/BADCy复合材料界面处能形成柔性的口恶唑啉酮五元环缓冲层。利用红外光谱法研究环氧树脂与氰酸酯树脂的反应机理,并比较不同浓度E51环氧树脂处理液对复合材料力学性能的影响,发现经5wt%浓度的E51环氧液处理的T300/BADCy复合材料层间剪切强度提高了16%,弯曲强度提高了4%,当处理液的浓度大于5wt%时,T300/BADCy复合材料的力学性能有所下降。采用扫描电镜研究处理前、后T300/BADCy复合材料层间剪切断口形貌,发现未处理的T300/BADCy树脂复合材料断口的界面处存在明显裂纹,处理后的复合材料界面没有裂纹,且断裂主要发生在树脂基体内部。     

石墨烯对环氧树脂性能的影响研究

本文研究了石墨烯对环氧树脂性能的影响。采用螺杆挤出机与开炼机将石墨烯分散在环氧树脂体系中,通过拉力试验机、绝缘测试仪、差示扫描量热仪(DSC)、热分析仪(TGA)等对改性树脂体系的力学性能、电性能及热力学性能进行表征。结果表明,材料的常温剪切强度随着石墨烯用量的增加而下降,150℃剪切强度随石墨烯用量的增加呈先增大后趋于稳定;材料的电阻值随着石墨烯用量的增加而显著下降然后趋于稳定;当温度区间为100℃～140℃时,片层结构石墨烯的加入可明显改变胶膜的黏度范围;材料的热稳定性随着石墨烯用量的增加基本未发生变化;扫描电镜发现石墨烯的引入可大幅度提高环氧树脂的韧性;石墨烯的引入在一定程度提高了胶膜的玻璃化转变温度。     

KH550修饰碳纳米管增韧环氧树脂的研究

利用偶联剂KH550对多壁碳纳米管(MWCNTs)进行化学修饰,并制备了MWCNTs/环氧树脂纳米复合材料.研究了不同含量的MWCNTs对纳米复合材料力学性能的影响.研究结果表明,MWCNTs表面成功接枝上了一定量的KH550,将其加入环氧树脂基体可大幅提高复合材料的力学性能.当添加量达到0.5%时,复合材料的力学性能最好,冲击韧度和弯曲强度较纯环氧树脂分别提高了85.3%和21.6%.扫描电镜结果显示,复合材料由脆性断裂转变为韧性断裂.     

氰酸酯/线性酚醛/环氧树脂三元体系的研究

 在氰酸酯树脂/ 环氧树脂体系中引入了线性酚醛树脂,得到氰酸酯树脂/ 环氧树脂/ 线性酚醛树脂三元共聚体系。采用差示扫描量热法(DSC) 研究了三元共聚体系的反应动力学,根据Kissinger 方程和Ozawa 方程得到体系的表观活化能( Ea) :62. 94kJ / mol,确定了体系的反应速率常数K。比较了纯氰酸酯树脂、氰酸酯/ 环氧树脂体系和三元树脂体系玻璃布层压板的力学性能、介电性能以及吸湿率。结果表明,线性酚醛树脂用量为15wt %的三元体系复合材料的弯曲强度和层间剪切强度分别比氰酸酯/ 环氧树脂体系复合材料提高了6 %和15 %,介电损耗和吸水率分别降低了33 %和8 %。     

端羧基丁腈橡胶改性环氧形状记忆聚合物

以甲基四氢邻苯二甲酸酐(METHPA)为固化剂,利用端羧基丁腈橡胶(CTBN)改性环氧树脂(EP)制备形状记忆聚合物。研究了形状记忆环氧树脂的力学性能、玻璃化转变温度和形状记忆性能。研究表明,形状记忆环氧树脂的韧性得到明显的提高,Tg得到了相应的下降,形状记忆性能良好,形状固定率皆在97%以上,形状回复率约达100%。     

The effect of inlet conditions on the flow and heat transfer in multiple rotating cavity with axial throughflow

This paper discusses experimental results from two different build configurations of a heated multiple rotating cavity test rig.Measurements of heat transfer from the discs and tangential velocities are presented.The test rig is a 70% full scale version of a high pressure compressor stack of an axial gas turbine engine.Of particular interest are the internal cylindrical cavities formed by adjacent discs and the interaction of these with a central axial throughflow of cooling air.Tests were carried out for a range of non-dimensional parameters representative of high pressure compressor internal air system flows(Re up to 5×106 and Rez up to 2×105).Two different builds have been tested.The most significant difference between these two build configurations is the size of the annular gap between the(non-rotating) drive shaft and the bores of the discs.The heat transfer data were obtained from thermocouple measurements of surface temperature and a conduction solution method.The velocity measurements were made using a two component,LDA system.The heat transfer results from the discs show differences between the two builds.This is attributed to the wider annular gap allowing more of the throughflow to penetrate into the cavity.There are also significant differences between the radial distributions of tangential velocity in the two builds of the test rig.For the narrow annular gap,there is an increase of non-dimensional tangential velocity V/Ωr with radial location to solid body rotation V/Ωr=1.For the wider annular gap,the non-dimensional velocities show a decrease with radial location to solid body rotation.      

Research on Auto-detection for Remainder Particles of Aerospace Relay Based on Wavelet Analysis

Aerospace relay is one kind of electronic components which is used widely in national defense system and aerospace system. The existence of remainder particles induces the reliability declining, which has become a severe problem in the development of aerospace relay. Traditional particle impact noise detection (PIND) method for remainder detection is ineffective for small particles, due to its low precision and involvement of subjective factors. An auto-detection method for PIND output signals is proposed in this paper, which is based on direct wavelet de-noising (DWD), cross-correlation analysis (CCA) and homo-filtering (HF), the method enhances the affectiv-ity of PIND test about the small particles. In the end, some practical PIND output signals are analysed, and the validity of this new method is proved.     

Preparation of Highly Dispersed Antimony-doped Tin Oxide Nano-powder via Ion-exchange Hydrolysis of SnCl4 and SbCl3 and Azeotropic Drying

Antimony-doped tin hydroxide colloid precipitates have been synthesized by hydrolysis of SnCl4 and SbCl3 using: (1) an ion-exchange hydrolysis to remove chlorine ions, and (2) isoamyl acetate as an azeotropic solvent to obviate water. The obtained dried powder is of high dispersivity without any need for further grinding. The size and dispersivity of the final particles are investigated with the aid of TG-DTA, BET, XRD and TEM. After having calcined, the antimony-doped tin oxide nanopowder possesses a tetragonal rutile structure with high dispersivity, uniform particles and low hard agglomeration.     

Effects of Mo on the Microstructure and Hydrogen Sorption Properties of Ti-Mo Getters

The effects of Mo on the microstructure evolution, porosity and hydrogen sorption properties of Ti-Mo getters are investigated in this work. The results show that the addition of Mo prolongs the densification process of Ti-Mo getters and results in a significant amount of sintered pores. With the Mo content increasing, the porosity of getters firstly increases reaching the maximum value as it at- tains about 7.5wt.%, and then drops. At the room temperature, the hydrogen sorption property of getters increases progressively with the Mo content increasing, but the tendency is not very clear before its content lies below 2.5wt.%. When the Mo content achieves about 7.5wt.%, the hydrogen sorption property proves to be the best. The discussion is made about the above mentioned phenomena inclusive of hydrogen sorption properties of getters under different activation conditions (from 500-750 ℃).     

超声速燃烧数值模拟中的湍流与化学反应相互作用模型

高精度数值模拟有助于理解超声速湍流燃烧中湍流与化学反应的相互作用,可为发动机燃烧室等工程应用设计提供可靠的预测模型。除直接数值模拟外,目前在湍流燃烧应用中使用的大涡模拟和雷诺平均Navier-Stokes模拟均需要借助模型模化发生在湍流小尺度上的流动与化学反应过程对湍流大尺度运动的影响。现有的湍流与化学反应相互作用模型大致可分为:火焰面类模型和概率密度函数类模型,2类模型在不同的应用中各自具有优势和局限性。此外,现有模型大都基于低马赫数燃烧,而超声速燃烧中通常会伴随快速混合、局部熄火和再着火以及激波等复杂过程,这为发展其中的湍流与化学反应相互作用模型提出了更多的挑战。     

适于低轨卫星IP网络的单核共享树组播算法(英文)

为了解决低轨卫星IP网络中现有典型源组播算法的信道资源浪费问题,本文提出了一套单核共享树组播算法,即核心群合并共享树(CCST)和加权核心群合并共享树(w-CCST)算法。CCST 算法包括动态近似中心(DAC)选核方法和核心群合并组播路径构建方法。DAC方法专为周期、规律运动的低轨卫星网络提出,不需要复杂的星上计算。在核心群合并方法中,以核节点作为初始核心群,通过核心群和剩余组成员的最短路径方法逐步扩展直至整棵组播树构建完成,从而使得组播树的树代价最小,大大提高了网络的带宽利用率和组播传输效率。w-CCST 算法中所提出的加权因子可以调整树代价和端到端传播时延之间的折衷程度,因此,可以通过调整加权因子来适度增大树代价、降低端到端传播时延以支持某些端到端时延要求苛刻的实时组播业务。最后,与低轨卫星 IP 网络中典型算法进行了性能比较,仿真结果说明,CCST 算法的平均树代价比其它算法显著降低,w-CCST 算法的平均端到端传播时延小于 CCST 算法。     

Jet Vectoring Control Using a Novel Synthetic Jet Actuator

A primary air jet vectoring control system with a novel synthetic jet actuator (SJA) is presented and simulated numerically. The results show that, in comparison with an existing traditional synthetic jet actuator, which is able to perform the duty of either “push” or “pull”, one novel synthetic jet actuator can fulfill both “push” and “pull” functions to vector the primary jet by shifting a slide block inside it. Therefore, because the new actuator possesses greater efficiency, it has potentiality to replace the existing one in various appli- cations, such as thrust vectoring and the reduction of thermal signature. Moreover, as the novel actuator can fulfill those functions that the existing one can not, it may well be expected to popularize it into more flow control systems.     

Nonlinear Adaptive Slewing Motion Control of Spacecraft Truss Driven by Synchronous V-gimbaled CMG Precession

The slewing motion control of a truss arm driven by a V-gimbaled control-moment-gyro (CMG) is a nonlinear control problem. The V-gimbaled CMG consists of a pair of gyros that must precess synchronously. The moment of inertia of the system, the angular momentum of the gyros and the external disturbances are not exactly known. With the help of feedback linearization and recursive Lyapunov design method, an adaptive nonlinear controller is designed to deal with the unknown items. Performance of the proposed controller is verified by simulation.     

An SOR Implicit Time-accurate Scheme in Calculating Unsteady Flows

A new time-accurate marching scheme for unsteady flow calculations is proposed in the present work. This method is the combination of classical Successive Over-Relaxation (SOR) iteration method and Jacobian matrix diagonally dominant splitting method of LUSGS. One advantage of this algorithm is the second-order accuracy because of no factorization error. Another advantage is the low computational cost because the Jacobian matrices and fluxes are only calculated once in each physical time step. And, the SOR algorithm has better convergence property than Gauss-Seidel. To investigate its accuracy and convergency, several unsteady flow computa- tional tests are carried out by using the proposed SOR algorithm. Roe’s FDS scheme is used to discritize the inviscid flux terms. Un- steady computational results of SOR are compared with the experiment results and those of Gauss-Seidel. Results reveal that the numerical results agree well with the experimental data and the second-order accuracy can be obtained as the Gauss-Seidel for unsteady flow computations. The impact of SOR factor is investigated for unsteady computations by using different SOR factors in this algorithm to simulate each computational test. Different numbers of inner iterations are needed to converge to the same criterion for different SOR factors and optimal choice of SOR factor can improve the computational efficiency greatly.