Radio observations of Venus and the interpretations

The radio observations of Venus are reviewed and compared with theoretical microwave spectra computed for a variety of models of the Venusian environment. The models considered are (a) a CO₂-N₂ atmosphere, (b) an atmosphere of dust (the aeolosphere model), and (c) a cloud model with various loss mechanisms in the cloud. The effect of polarization on the surface emissivity has been included in all the computations. It is shown how the radio observations place limits upon the acceptable models, for example, the density and size of dust particles required in the aeolosphere model. It is shown how some models place severe restrictions on radar observations at short centimeter wavelengths, thereby emphasizing the importance of such experiments. These same models show that the Mariner II observations can not be interpreted in terms of surface phenomena and provide a new interpretation for the microwave phase effect.This work was supported in part by the U.S. Army, Navy and Air Force under Contract DA36-039-AMC-03200(E); and in part by the National Aeronautics and Space Administration (Grants NsG-250-62 and NsG-419).     

Emergence of a Habitable Planet

We address the first several hundred million years of Earth’s history. The Moon-forming impact left Earth enveloped in a hot silicate atmosphere that cooled and condensed over ∼1,000 yrs. As it cooled the Earth degassed its volatiles into the atmosphere. It took another ∼2 Myrs for the magma ocean to freeze at the surface. The cooling rate was determined by atmospheric thermal blanketing. Tidal heating by the new Moon was a major energy source to the magma ocean. After the mantle solidified geothermal heat became climatologically insignificant, which allowed the steam atmosphere to condense, and left behind a ∼100 bar, ∼500 K CO₂ atmosphere. Thereafter cooling was governed by how quickly CO₂ was removed from the atmosphere. If subduction were efficient this could have taken as little as 10 million years. In this case the faint young Sun suggests that a lifeless Earth should have been cold and its oceans white with ice. But if carbonate subduction were inefficient the CO₂ would have mostly stayed in the atmosphere, which would have kept the surface near ∼500 K for many tens of millions of years. Hydrous minerals are harder to subduct than carbonates and there is a good chance that the Hadean mantle was dry. Hadean heat flow was locally high enough to ensure that any ice cover would have been thin (<5 m) in places. Moreover hundreds or thousands of asteroid impacts would have been big enough to melt the ice triggering brief impact summers. We suggest that plate tectonics as it works now was inadequate to handle typical Hadean heat flows of 0.2–0.5 W/m². In its place we hypothesize a convecting mantle capped by a ∼100 km deep basaltic mush that was relatively permeable to heat flow. Recycling and distillation of hydrous basalts produced granitic rocks very early, which is consistent with preserved >4 Ga detrital zircons. If carbonates in oceanic crust subducted as quickly as they formed, Earth could have been habitable as early as 10–20 Myrs after the Moon-forming impact.     

A maintenance-free lead acid battery for inertial navigationsystems aircraft

Historically, aircraft inertial navigation system (INS) batteries have utilized vented nickel-cadmium batteries for emergency DC power. The United States Navy and Air Force developed separate systems during their respective INS developments. The Navy contracted with Litton industries to produce the LTN-72 and Air Force contracted with Delco to produce the Carousel IV INS for the large cargo and specialty aircraft applications, over the years, a total of eight different battery national stock numbers (NSNs) have entered the stock system along with 75 battery spare part NSNs. The standard hardware acquisition and reliability program is working with the Aircraft Battery Group at Naval Surface Warfare Center Crane Division, Naval Air Systems Command (AIR 536), Wright Laboratory, Battelle Memorial Institute, and Concorde Battery Corporation to produce a standard INS battery. This paper discusses the approach taken to determine whether the battery should be replaced and to select the replacement chemistry. The paper also discusses the battery requirements, aircraft that the battery is compatible with, and status of Navy flight evaluation. Projected savings in avoided maintenance in Navy and Air Force INS systems is projected to be $14.7 million per year with a manpower reduction of 153 maintenance personnel. The new INS battery is compatible with commercially sold INS systems which represents 66% of the systems sold     

Vibrational relaxation of CO2 (m,nl, p) in a CO2-N2 mixture. Part 1: Survey of available data

The knowledge of the vibrational relaxation reaction rates of diatomic and triatomic molecules is required for the modelling of numerous gaseous mixtures such as the Earth atmosphere (involving radiation transfer phenomena), exhaust plumes, afterbody wakes, Mars atmosphere, shock waves and chemical lasers. It enables a better understanding of the chemical reaction product rates and provides the populations of the radiating levels. In this study, we consider the few lowest vibrational levels of a CO₂-N₂ mixture and the V-T and V-V energy transfer processes between these levels. The reaction rates given by experimental and theoretical studies and by different surveys of data supplied by a bibliographic search are presented. Then, comparisons of the data available for the most important processes are shown. The usual assumptions concerning the vibrational relaxation of CO₂ (m, n^l, p) are recalled and briefly discussed.     

A Comparative Study of the Influence of the Active Young Sun on the Early Atmospheres of Earth, Venus, and Mars

Because the solar radiation and particle environment plays a major role in all atmospheric processes such as ionization, dissociation, heating of the upper atmospheres, and thermal and non-thermal atmospheric loss processes, the long-time evolution of planetary atmospheres and their water inventories can only be understood within the context of the evolving Sun. We compare the effect of solar induced X-ray and EUV (XUV) heating on the upper atmospheres of Earth, Venus and Mars since the time when the Sun arrived at the Zero-Age-Main-Sequence (ZAMS) about 4.6 Gyr ago. We apply a diffusive-gravitational equilibrium and thermal balance model for studying heating of the early thermospheres by photodissociation and ionization processes, due to exothermic chemical reactions and cooling by IR-radiating molecules like CO₂, NO, OH, etc. Our model simulations result in extended thermospheres for early Earth, Venus and Mars. The exospheric temperatures obtained for all the three planets during this time period lead to diffusion-limited hydrodynamic escape of atomic hydrogen and high Jeans’ escape rates for heavier species like H₂, He, C, N, O, etc. The duration of this blow-off phase for atomic hydrogen depends essentially on the mixing ratios of CO₂, N₂ and H₂O in the atmospheres and could last from ∼100 to several hundred million years. Furthermore, we study the efficiency of various non-thermal atmospheric loss processes on Venus and Mars and investigate the possible protecting effect of the early martian magnetosphere against solar wind induced ion pick up erosion. We find that the early martian magnetic field could decrease the ion-related non-thermal escape rates by a great amount. It is possible that non-magnetized early Mars could have lost its whole atmosphere due to the combined effect of its extended upper atmosphere and a dense solar wind plasma flow of the young Sun during about 200 Myr after the Sun arrived at the ZAMS. Depending on the solar wind parameters, our model simulations for early Venus show that ion pick up by strong solar wind from a non-magnetized planet could erode up to an equivalent amount of ∼250 bar of O⁺ ions during the first several hundred million years. This accumulated loss corresponds to an equivalent mass of ∼1 terrestrial ocean (TO (1 TO ∼1.39×10²⁴ g or expressed as partial pressure, about 265 bar, which corresponds to ∼2900 m average depth)). Finally, we discuss and compare our findings with the results of preceding studies.     

Galileo Probe Mass Spectrometer experiment

The Galileo Probe Mass Spectrometer (GPMS) is a Probe instrument designed to measure the chemical and isotopic composition including vertical variations of the constituents in the atmosphere of Jupiter. The measurement will be performed by in situ sampling of the ambient atmosphere in the pressure range from approximately 150 mbar to 20 bar. In addition batch sampling will be performed for noble gas composition measurement and isotopic ratio determination and for sensitivity enhancement of non-reactive trace gases.The instrument consists of a gas sampling system which is connected to a quadrupole mass analyzer for molecular weight analysis. In addition two sample enrichment cells and one noble gas analysis cell are part of the sampling system. The mass range of the quadrupole analyzer is from 2 amu to 150 amu. The maximum dynamic range is 10⁸. The detector threshold ranges from 10 ppmv for H₂O to 1 ppbv for Kr and Xe. It is dependent on instrument background and ambient gas composition because of spectral interference. The threshold values are lowered through sample enrichment by a factor of 100 to 500 for stable hydrocarbons and by a factor of 10 for noble gases. The gas sampling system and the mass analyzer are sealed and evacuated until the measurement sequence is initiated after the Probe enters into the atmosphere of Jupiter. The instrument weighs 13.2 kg and the average power consumption is 13 W.The instrument follows a sampling sequence of 8192 steps and a sampling rate of two steps per second. The measurement period lasts appropriately 60 min through the nominal pressure and altitude range.     

Vertical distribution of disequilibrium species in Jupiter's troposphere

Sources of organic matter and inorganic tracers on Jupiter, including solar UV photolysis, lightning discharges, and convective quenching of hot gases from the lower atmosphere, are reviewed in light of Earth-based and Voyager data with the purpose of predicting the tropospheric steady-state abundances and vertical distributions of HCN, CH₂O, and other species.It is concluded that a steady-state mole fraction of HCN in the Jovian troposphere of only 10^-12 could be maintained by vertical transport of hot gases from the deep atmosphere. The observed HCN abundance (roughly X_HCN = 10^-9) appears to be due to photochemical reactions.After HCN, the most abundant organic disequilibrium species in the troposphere is probably C₂H₆, derived from direct photolysis of CH₄ at high altitudes, with a mole fracton of 10^-10 at the H₂O cloud level. Inorganic tracers of disequilibrium processes are also briefly summarized.     

Solar pulsations

Recent observational evidence on solar oscillations is reviewed; this evidence strongly favors the global interpretation for much of the observed spectrum. Implications of these observations for the study of the solar interior and atmosphere are discussed.This work was supported in part by the National Science Foundation and the Air Force Office of Scientific Research.     

低密度气凝胶复合材料的火星环境适应性研究

针对航天器的使用要求,研制了密度≤30 kg/m~3轻质高效的二氧化硅气凝胶复合材料。针对深空探测的应用环境,对低密度气凝胶复合材料在不同条件下的热导率、热循环、热真空和电离总剂量等环境试验进行测试。结果表明,低密度气凝胶复合材料服役温度可达到-145～85℃,在1 kPa CO_2气氛下热导率可达到6.6 mW/(m·K)。获得了不同气氛和不同温度条件下以及同种气氛、不同压力条件下低密度气凝胶复合材料的热导率变化规律,并测试批次性材料热导率,结果表明批次热导率稳定性良好。热循环、热真空和电离辐照试验前后热导率和尺寸收缩率均未变化,表明低密度气凝胶复合材料在深空环境下保持良好的结构和稳定的隔热性能。     

Causes of aircraft electrical failures

The results of a survey of data on failures of aircraft electronic and electrical components that was conducted to identify problematic components are reported. The motivation for the work was to determine priorities for future work on the development of accident investigation techniques for aircraft electrical components. The primary source of data was the Airforce Mishap Database, which is maintained by the Directorate of Aerospace Safety at Norton Air Force Base. Published data from the Air Force Avionics Integrity Program (AVIP) and Hughes Aircraft were also reviewed. Statistical data from these three sources are presented. Two major conclusions are that problems with interconnections are major contributors to aircraft electrical equipment failures, and that environmental factors, especially corrosion, are significant contributors to connector problems     

Dynamical theory of the solar wind

This paper is a review of the basic theoretical dynamical properties of an atmosphere with an extended temperature strongly bound by gravity. The review begins with the historical developments leading up to the realization that the only dynamical equilibrium of an atmosphere with extended temperature is supersonic expansion. It is shown that sufficient conditions for supersonic expansion are T(r) declining asymptotically less rapidly than 1/r, or the density at the base of the corona being less than N _b given by (40) if no energy is available except through thermal conductivity, or the temperature falling within the limits given by (18) if T N ^-1 throughout the corona. Less extended temperatures lead to equilibria which are subsonic or static. The hypothetical case of a corona with no energy supply other than thermal conduction from its base is considered at some length because the equations may be solved by analytical methods and illustrate the transition from subsonic to supersonic equilibrium as the temperature becomes more extended. Comparison with the actual corona shows that the solar corona is actively heated for some distance into space by wave dissipation.The dynamical stability of the expanding atmosphere is demonstrated, and in a later section the radial propagation of acoustic and Alfvén waves through the atmosphere and wind is worked out. The calculations show that the magnetometer will probably detect waves more easily than the plasma instrument, but that both are needed to determine the mode and direction of the wave. An observer in the wind at the orbit of Earth can listen to disturbances generated in the corona near the sun and in turbulent regions in interplanetary space.The possibility that the solar corona is composed of small-scale filaments near the sun is considered. It is shown that such filamentary structure would not be seen at the orbit of Earth. It is pointed out that the expansion of a non-filamentary corona seems to lead to too high a calculated wind density at the orbit of Earth to agree with the present observations, unless T(r) is constant or increases with r. A filamentary corona, on the other hand, would give the observed wind density for declining T(r).It is shown that viscosity plays no important role in the expansion of an atmosphere either with or without a weak magnetic field. The termination of the solar wind, presumably between 10–10³ AU, is discussed briefly. The interesting development here is the interplanetary L recently observed, which may come from the interstellar neutral hydrogen drifting into the outer regions of the solar wind.Theory is at the present time concerned with the general dynamical principles which pertain to the expansion equilibrium of an atmosphere. It is to be expected that the rapid progress of direct observations of the corona and wind will soon permit more detailed studies to be carried out. It is important that the distinction between detailed empirical models and models intended to illustrate general principles be kept clearly in mind at all times.This work was supported by the National Aeronautics and Space Administration under Grant NASA-NsG-96-60.     

Rare Atoms,Molecules and Radicals in the Coma of P/Halley

We have searched for rare molecules and radicals in the coma of P/Halley using the ion data obtained by IMS-Giotto. Whereas our established methods were used in the ionosphere, a new model was developed for the interpretation of the ion data in the outer coma. Ne/H₂O < 1.5 × 10^-3 was determined in the coma of the comet. Upper limits for the production of Na were derived from the very low abundance of Na⁺. Methyl cyanide and (probably) ethyl cyanide were identified with abundances of CH₃CN/H₂O = (1.4 ± .6) × 10^-3 and C₂H₅CN/H₂O = (2.8 ± 1.6) × 10^-4. These results and upper limits for other N-bearing species confirm that nitrogen is depleted in the Halley material. C₄H was identified and a point source strength of C₄H/H₂O = (2.3 ± .8) × 10^-3 was derived. Our upper limit for C₃H is lower than the abundance of C₄H. This is in agreement with the enhanced abundances of C_nH species with even numbers of C-atoms found in interstellar molecular clouds, suggesting that the C₄H in Halley was synthesized under molecular cloud conditions. Thus, C₄H and other organics with unpaired electrons may turn out to be indicators for a molecular cloud origin of cometary constituents. This revised version was published online in June 2006 with corrections to the Cover Date.     

Solar Variability and Climate Impact on Terrestrial Planets

Some possible factors of climate changes and of long term climate evolution are discussed with regard of the three terrestrial planets, Earth, Venus and Mars. Two positive feedback mechanisms involving liquid water, i.e., the albedo mechanism and the greenhouse effect of water vapour, are described. These feedback mechanisms respond to small external forcings, such as resulting from solar or astronomical constants variability, which might thus result in large influences on climatic changes on Earth. On Venus, reactions of the atmosphere with surface minerals play an important role in the climate system, but the involved time scales are much larger. On Mars, climate is changing through variations of the polar axis inclination over time scales of ～10⁵–10⁶ years. Growing evidence also exists that a major climatic change happened on Mars some 3.5 to 3.8 Gigayears ago, leading to the disappearance of liquid water on the planet surface by eliminating most of the CO₂ atmosphere greenhouse power. This change might be due to a large surge of the solar wind, or to atmospheric erosion by large bodies impacts. Indeed, except for their thermospheric temperature response, there is currently little evidence for an effect of long-term solar variability on the climate of Venus and Mars. This fact is possibly due to the absence of liquid water on these terrestrial planets.     

Choosing software and replacing ATE: lessons learned

When tasked to ensure the Minuteman Intercontinental Ballistic Missile system remains fully operational and supportable through 2020, the Air Force realized that the support capability of its legacy automated test system for the operational ground support electronics subsystem would need to be completely replaced. The legacy test system, while fully operational, was rapidly becoming non-supportable. Unless replaced with new hardware and upgraded test program sets, the needed long-term support could not be provided to the weapon system. To address this issue within the scope of available program funding constraints, the Air Force selected an approach of combining the technical and programmatic expertise of the weapon system prime contractor, the program control responsibilities of the weapon system Program Office, and the technical capability of an Air Force technical organization. The program was divided into two phases: a prototype phase and a production/rehost phase. This paper gives an overview of the program and presents valuable lessons learned during the prototype phase.     

Thermospheric X-Ray and Euv Heating by the Young Sun on Early Venus and Mars

In view of the low H₂O abundance in the present Venusian and Martian atmospheres several observations by spacecraft and studies suggest that both planets should have lost most of their water over the early active period of the young Sun. During the first Gyr after the Sun arrived at the Zero- Age-Main-Sequence high X-ray and EUV fluxes between 10 and 100 times that of the present Sun were responsible for much higher temperatures in the thermosphere-exosphere environments on both planets. By applying a diffusive-gravitational equilibrium and thermal balance model for investigating radiation impact on the early thermospheres by photodissociation and ionization processes, due to exothermic chemical reactions and cooling by CO₂ IR emission in the 15μm band we found expanded thermospheres with exobase levels between about 200 km (present) and 2000 km (4.5 Gyr ago). The higher temperatures in the upper atmospheres of both planets could reach “blow-off” conditions for H atoms even at high CO₂ mixing ratios of 96%. Lower CO₂/N₂ mixing ratio or higher contents of H2O vapor in the early atmospheres could have had a dramatic impact from the loss of atmosphere and water on both planets. The duration of this phase of high thermal loss rates essentially depended on the mixing ratios of CO₂, N₂, and H₂O in the early atmospheres and could have lasted between about 150 and several hundred Myr.     

Vibrational relaxation of CO2(m,nl, p) in a CO2N2 mixture. Part 2: Application to a one-dimensional problem

In order to quantify the relaxation mechanism of CO₂(m, n^l, p), the vibrational level populations are calculated for a particular test-case: the vibrational relaxation of a CO₂N₂ mixture along the stagnation streamline in a reentry problem. The N₂ species is chosen as a collision partner because it is a component existing in numerous gaseous mixtures (cf. Part. 1). Excitation and deexcitation processes are taken following Nickerson and Herzfeld. The Navier-Stokes code CELHYO for the simulation of hypersonic laminar viscous flows in chemical and thermal nonequilibrium is used with a new one-dimensional approach, reduction of the Navier-Stokes equations along the stagnation streamline. Mass fraction and ‘vibrational temperature’ distributions of every vibrational level, considered as an independent chemical species, are presented for the two different CO₂N₂ mixture compositions. The validity of the usual assumptions for the vibrational mechanism is examined on the basis of the obtained results.     

3He-rich solar flares

The formation of the observed solar cosmic ray (SCR) composition remains an open question. It has become particularly acute after the discovery of ³He-rich events. The ³He/⁴He abundance ratio revealed in such events exceeds substantially (up to four orders of magnitude) that in the solar atmosphere.The data available on the ³He-rich events are discussed and a list of all such events known up to date is presented. Most of the ³He-rich SCR events can be associated with the corresponding optical flares on the Sun, with X-ray and radiobursts.An analysis of the models of ³He enrichement proposed up to now shows that only preferential ³He heating by plasma mechanisms can provide the observed high enrichment levels (³He/⁴He 1).A model involving preferential heating of ³He by induced scattering on ions of the ion acoustic waves generated by flare associated electrons in the solar atmosphere is considered in detail. This model can account for the major properties of the ³He-rich flares.Observational implications of the ³He-rich solar flare model are analyzed; the predictions of the theory are compared with the experimental data available, and promising avenues of further relevant experimental and theoretical research are considered.However it is shown that all main conclusions made based on the expressions ((3.2), (3.11), (3.12)) remain the same.     

Experimental comparison between aircraft fuel tank inerting processes using NEA and MIG

Fuel tank inerting technologies are able to reduce the fire risk by injection of inert gas into the ullage or fuel, the former called ullage washing and the latter fuel scrubbing. The Green On-Board Inert Gas Generation System (GOBIGGS) is a novel technology based on flameless catalytic combustion, and owning to its simple structure and high inerting efficiency, it has received a lot of attentions. The inert gas in the GOBIGGS is mainly comprised of CO₂, N₂, and O₂ (hereinafter, Mixed Inert Gas (MIG)), while that in the On-Board Inert Gas Generation System (OBIGGS), which is one of the most widely used fuel tank inerting technologies, is Nitrogen-Enriched Air (NEA). The solubility of CO₂ is nearly 20 times higher than that of N₂ in jet fuels, so the inerting capability and performance are definitely disparate if the inert gas is selected as NEA or MIG. An inerting test bench was constructed to compare the inerting capabilities between NEA and MIG. Experimental results reveal that, if ullage washing is adopted, the variations of oxygen concentrations on the ullage and in the fuel are nearly identical no matter the inert gas is NEA or MIG. However, the ullage and dissolved oxygen concentrations of MIG scrubbing are always higher than those of NEA scrubbing.     

Oxygen Isotope Processes and Transfer Reactions

A unique kinetic isotope effect has been found in the formation process of ozone molecules. Isotope enrichments of about 10% above statistically expected values were first discovered in atmospheric isotopomers ⁴⁹O₃ and ⁵⁰O₃ and later in many other molecular combinations. Most recently the source of this effect was identified through measurement of isotope-specific ozone formation rate coefficients which show a large variability of over 50%. Ozone molecule formation is a complex process since different reaction channels contribute to a specific isotopomer. In addition, fast oxygen isotope exchange reactions determine the abundance of atomic oxygen participating in ozone formation. The isotope enrichments observed are both pressure and temperature-dependent and they decrease at pressures above 100 mbar and toward lower temperatures. Ozone possesses not only one of the most unusual isotope anomalies, it also serves as a mediator by transferring heavy oxygen from the O₂ reservoir to other species. Stratospheric isotope composition of CO₂ has been recently measured with high accuracy and a pronounced isotopic signature was found which shows that ¹⁷O is preferentially transferred from O₃ into CO₂. This revised version was published online in August 2006 with corrections to the Cover Date.     

Development of the Primary Sorption Pump for the SEIS Seismometer of the InSight Mission to Mars

We report on the development of a passive sorption pump, capable of maintaining high-vacuum conditions in the InSight seismometer throughout the duration of any extended mission. The adsorber material is a novel zeolite-loaded aerogel (ZLA) composite, which consists of fine zeolite particles homogeneously dispersed throughout a porous silica network. The outgassing species within the SEIS evacuated container were analyzed and the outgassing rate was estimated by different methods. The results were used to optimize the ZLA composition to adsorb the outgassing constituents, dominated by water, while minimizing the SEIS bakeout constraints. The InSight ZLA composite additionally facilitated substantial CO₂ adsorption capabilities for risk mitigation against external leaks in Mars atmosphere. To comply with the stringent particle requirements, the ZLA getters were packaged in sealed containers, open to the SEIS interior through \(1~\upmu\mbox{m}\)-size pore filters. Results from experimental validation and verification tests of the packaged getters are presented. The pressure forecast based on these data, corroborated by rudimentary in situ pressure measurements, infer SEIS operational pressures not exceeding \(10^{-5}~\mbox{mbar}\) throughout the mission.