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1.
Diiminosuccinonitrile (DISN) has been investigated as a potential prebiotic phosphorylating agent. It is formed readily by the oxidation of diaminomaleonitrile (DAMN), a tetramer of HCN. DISN effects the cyclization of 3'-adenosine monophosphate to adenosine 2',3'-cyclic phosphace in up to 40% yield. The DISN-mediated phosphorylation of uridine to uridine mono-phosphate does not proceed efficiently in aqueous solution. The reaction of DISN and BrCN with uridine-5'-phosphate and uridine results in the formation of 2,2'-anhydronucleotides and 2,2'-anhydronucleosides respectively, and other reaction products resulting from an initial reaction at the 2'- and 3'-hydroxyl groups. The clay mineral catalysis of the cyclization of adenosine-3'-phosphate was investigated using homoionic montmorillonites. 相似文献
2.
Deoxynucleoside 5'-monophosphates were condensed by cyanamide or by l-ethyl-3-(3-dimethylaminopropyl) carbodiimide in the presence of ammonium chloride at 0 degree, 37 degrees or 60 degrees C through several cycles of evaporation to dryness with replenishment of all reactants at each cycle. We found that at 37 degrees or 60 degrees cyanamide gives distinctly more high molecular weight material than does carbodiimide. Indeed, the yield of condensed products for the cyanamide reaction (dimers and higher oligomers) was found to be between 60 percent and 80 percent. The molecular weight distribution of the product shifts to higher molecular weights as cycling continues at 37 degrees or 60 degrees for both condensing agents. The water soluble carbodiimide gives higher yields of low molecular weight product but much lower yields of the higher molecular weight products. At 0 degree yields of high molecular weight product were low for both condensing agents. Results of characterization of the products demonstrate the synthesis of oligodeoxynucleotides including tetramers, with 3'-5' phosphodiester linkages. 相似文献
3.
Modern studies now favor the fact that extraterrestrial organic molecules served as an important source of biological important substances on the primitive Earth. It is presumed that these space-made organic molecules could be transported safely to the Earth surface being associated with mineral grains. It is important to test whether nucleotides synthesized in Earth orbit could be protected by lunar surface regolite. The phosphorylation of adenosine, uridine and thymidine has been studied with respect of their further transformations and degradation in presence of mineral bed. After retrieval, HPLC analysis is used to identify all the mononucleotides of certain nucleosides. It has been shown, that exposure of the investigated nucleosides as dry films in space conditions in the presence of Lunar soil increases the yield of synthesized nucleotides in 1.1-3.0 times as compared with the exposure of the same samples in absence of Lunar soil. To identify and evaluate the principal source of energy in open space responsible for nucleotide synthesis reaction laboratory experiments were performed. It has been shown, that vacuum ultra violet (VUV 145 nm) radiation promotes nucleotide synthesis more effectively than ultra violet (UV 254 nm) while the presence of Lunar soil increases reaction yield in 1.5-2.0 times. Formation of 5'-mononucleotides seemed to be the most effective reaction both in flight and in laboratory experiments. Protective action of lunar soil on synthesized nucleotides against UV radiation has been shown in open Space conditions. 相似文献
4.
The behavior of an aqueous-dominant multicomponent cometary model is examined at high doses of ionizing radiation. The system is composed of a water mixture of HCN (0.2 mol dm-3), CH3CN (0.04 mol dm-3), C2H5CN (0.02 mol dm-3), CH3OH (0.12 mol dm-3) and HCO2H (0.01 mol dm-3. It was exposed to gamma rays at doses up to 18.5 MGy. The chemical kinetic database used in the computer treatment of experimental data consists of 79 reactions. A complex mixture of products has been synthesized: gases, amino acids, carboxylic acids and polymeric material. The results suggest that the pristine material in cometary nuclei may have been chemically altered by the action of cosmic rays and embedded radionuclides. 相似文献
5.
Atmospheric chemistry may be one of the important pathways to the synthesis of organic compounds in a planetary periphery. Depending on the nature of the carbon source (CH 4, CO or CO 2), the main composition of the atmosphere, and the respective roles of the various energy sources, is it possible, and to what extent, to produce organics? What kind of gaseous mixture is the most favourable to prebiotic organic syntheses? How far can the results of laboratory works be extrapolated to the case of planetary atmospheres? These questions are discussed, on the basis of several available laboratory data, and by considering the main atmospheric composition of the planets of the solar system, and the list of organic compounds which have already been dettected in their atmospheres. 相似文献
6.
ISAS's (Institute of Space and Astronautical Science) project for the exploration of comet Halley consists of two spacecraft, Sakigake and Suisei, launched on 7 January 1985 and 18 August, respectively. Sakigake passed the sunward side of the comet on 11 March 1986 with a miss distance of 6.99 million km. Three experiments, a plasma wave probe with dipole and search-coil antennae, a magnetometer with three axis ring core sensor on an extended boom and a four-grid Faraday cup attached to the inner side of the wall of the spacecraft, detected various phenomena caused by the comet at a distance as far as 7 million km. The other spacecraft, Suisei, flew by the comet on its sunward side with a miss distance of 151 thousand km on 8 March 1986. It carried two experiments, an ultraviolet imager and an energy analyzer for ions. The UV imager was able to take the first image of the hydrogen cloud of comet Halley on 26 November 1985. With this experiment, the spin period of the cometary nucleus, location of jets, amount of water evaporation, distribution of hydrogen density inside cloud, etc. were clarified. The energy analyser experiment provided information on the intensive interaction between cometary and solar wind ions. 相似文献
7.
Parameters of the best-fitting tri-axial ellipsoids representing external equipotential surfaces of Venus and Mars have been determined from satellite data. The dynamic consequence of the equatorial flattening of Venus has been discussed from the point of view of the s.c. synodic resonance rotation. The major gravitational anomalies of Venus have been interpreted, space locations and magnitudes of anomalous masses determined and their contribution to the second zonal Stokes' constant in the gravitational potential computed. The conclusions were done: The figure of the aphroditoid is strange even if there is a relatively small polar flattening; an equatorial “disc” of Venus is enormous. Recent space data do not support hypothesis that the Earth controls the spin of Venus. 相似文献
8.
Observations using the Rossi X-ray Timing Explorer ( RXTE) have discovered dozens of accreting neutron stars with millisecond spin periods in low-mass binary star systems. Eighteen are millisecond X-ray pulsars powered by accretion or nuclear burning or both. These stars have magnetic fields strong enough for them to become millisecond rotation-powered (radio) pulsars when accretion ceases. Few, if any, accretion- or rotation-powered pulsars have spin rates higher than 750 Hz. There is strong evidence that the spin-up of some accreting neutron stars is limited by magnetic spin-equilibrium whereas the spin-up of others is halted when accretion ends. Further study will show whether the spin rates of some accretion- or rotation-powered pulsars are or were limited by emission of gravitational radiation. 相似文献
9.
The possibility that the organic molecules that have been found near comets could have formed by UV photolysis of interstellar ices was investigated by simulating this process in the laboratory. It is found that oxygen rich organics containing C-OH, C-H and C=O groups are readily produced in this way. These results indicate that part of the organic material in comets may have formed by UV irradiation of ices, either in the pre-solar nebula or in the interstellar phase. 相似文献
10.
以实现对海上多平台传感器资源进行自动或半自动的协调管理控制为目标,设计了传感器管理与控制系统的功能结构,对组成系统的传感器信息管理、传感器组织管理、收发通信管理、传感器控制管理和传感器综合效能分析等功能模块进行了描述,采用基于效能函数的多传感器管理算法实现了传感器的任务规划与资源分配,并采用"集中管理,分散控制"的方式进行海上多平台传感器的管理与控制。 相似文献
11.
In this review article the current status of particle dark matter is addressed. We discuss the main theoretical extensions of the standard model which allow to explain dark matter in terms of a (yet undiscovered) elementary particle. We then discuss the theoretical predictions for the searches of particle dark matter: direct detection in low-background underground experiments and indirect detection of neutrinos, gamma-rays and antimatter with terrestrial and space-borne detectors. Attention will be placed also on the discussion of the uncertainties, mainly of astrophysical origin, which affect the theoretical predictions. The constraints placed by these searches on the extensions of the standard models will be briefly addressed. 相似文献
12.
介绍了热电偶、热电阻系统的工作原理及其硬件组成、软件实现,并简要叙述了其自动检定的过程及方法。 相似文献
14.
针对一类具有双拼椭球体外形的平流层飞艇,根据适当假设,给出该类飞艇质量和惯量特性的解析计算方法.以飞艇上升过程为例,通过仿真计算给出该过程飞艇质量、质心位置和转动惯量的变化曲线,结合理论分析,验证该计算方法的合理性.最后,简要分析了质量和惯量特性变化对飞艇运动稳定性和能控性的影响. 相似文献
15.
We explore how nuclear rotation and activity can be used as effective probes of the gross nuclear structure and therefore of the interior of comets. We present a model of nuclear activity and discuss that in the context of how activity and rotation can control the present day size distribution of active short period comets. We argue that there is a real paucity of sub-km comets when compared with what one expects based on the size distribution of the known Kuiper Belt Objects. 相似文献
17.
作者参加了 2 0 0 3年 7月在澳大利亚悉尼市举行的第 2 5届国际天文学会大会 (3年一届 ) ,会议期间在第 31专业委员会 (时间专业 )的会议上国际权度局 (BIPM)时间部的首席科学家E F Arias介绍了有关 2 0 0 0年~2 0 0 3年TAI的研究进展、美国海军天文台 (USNO)的D .McCarthy介绍了 2 0 0 3年 5月 2 8日~ 30日在意大利都灵市举行的“UTC的未来”研讨会的情况 ,与会成员就此两项也展开了热烈的讨论。本文介绍了TAI和UTC进展的最新情况。 相似文献
19.
该系统是基于计算机应用技术、星体标校方法、标准硬件接口及通用软件开发平台的便携式智能型检测系统 ,解决对野外分散站点上的光测设备进行检测、标校、监控和测控网通信联试等技术问题。着重阐述对外场经纬仪进行准确度检测和单项误差调整的自动化星体标校的原理和具体实现方法 相似文献
20.
介绍了近期研制完成的交直流耐压测试仪的总体结构,重点叙述了交流大功率电源以及较高等级(10 kV~100 kV)交流耐压测试仪的失真度测量技术。 相似文献
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