Observational astrochemistry

Astronomers have identified some 70 molecular species in dense interstellar clouds and the envelopes expelled by evolved stars. Some 75% of these are organic, including molecules with up to 13 atoms and with weights up to 147 daltons. Elements found in interstellar compounds include H, C, N, O, S, Si, and probably Cℓ. A recent addition to the list of interstellar molecules is the first hydrocarbon ring, cyclopropenylidene (C₃H₂). Current research in astrochemistry is concentrating on the determination of accurate chemical abundances as a function of environment. Both basic similarities and intriguing differences among clouds are found, which may provide clues to processes associated with cloud evolution and star formation.     

Observational astrochemistry: recent results.

More than 80 molecular species have now been observed by astronomers in the dense interstellar clouds where stars and planets form or in the envelopes expelled by evolved stars. Elemental constituents of these compounds include all of the "biogenic" elements, hydrogen, carbon, nitrogen, oxygen, sulfur, and (most recently) phosphorus. In addition, silicon is found in several molecules, and a series of metal halides have recently been detected in the outflowing envelope of a nearby carbon star. Additions to the list of known interstellar molecules since the last COSPAR meeting are discussed individually. Recent measurements of the hydrogen isotopic fractionation for the cyclic molecule C3H2 are described; values up to 10,000 times the cosmic deuterium-to-hydrogen ratio are found. Knowledge of the chemical reservoirs for the major volatile elements and a comparison between observed molecular abundances and theoretical models are both discussed.     

Summary of the workshop on gamma-ray burst afterglows at the 34th COSPAR meeting

A summary is given of the presentations at the COSPAR workshop on γ-ray bursts with some personal commentary on the contributions, the SN/GRB connection, and on the role of magnetic fields in γ-ray bursts and their afterglows. Of special interest were the accumulated arguments for strong collimation and associated reduction in the total required energy for γ-ray bursts. Significant discussion was also devoted to the issues associated with iron and metal lines in X-ray spectra. It is important to note that some of the afterglows seem to require ambient densities 1 g cm⁻³, rather incompatible with a massive star environment. Of associated difficulty is the fact that few, if any, afterglows seem consistent with the r⁻² wind expected for a massive star model. There are reasons to think that if γ-ray bursts are associated with supernovae they are of Type Ic. This suggests that any wind present might be rich in carbon and oxygen, not hydrogen or helium. If γ-ray bursts are narrowly collimated, then the burst is only probing a small portion of any wind, perhaps just that time-dependent and isotropic structure directly along the rotation axis. The characteristics of “hypernovae” may be the result of orientation effects in a mildly inhomogeneous set of progenitors, rather than requiring an excessive total energy or luminosity. The recent event GRB 021004 provided a rich photometric and spectroscopic record and perhaps the most direct evidence yet for the association of a specific γ-ray burst with a massive star progenitor. If the magnetic field plays a significant role in launching a relativistic γ-ray burst jet from within a collapsing star, then the magnetic field may also play a role in the propagation, collimation, and stability of that jet within and beyond the star. The magneto-rotational instability (MRI) can operate under conditions of moderate rotation. This means that the MRI will be at work generating strong fields exponentially rapidly even as the disk of material begins to form and makes a transition from a non-Keplerian to quasi-Keplerian flow in the collapsar and related models.     

Spectroscopic properties of polycyclic aromatic hydrocarbons (PAHs) and astrophysical implications.

PAHs (polycyclic aromatic hydrocarbons) are probably present as a mixture of neutral and ionized species and are responsible for the set of infrared emission bands in the 2-15 microns regions, which are observed in many different objects like reflection and planetary nebulae and external galaxies. PAHs are suggested to be the most abundant free organic molecules and ubiquitous in space. PAHs might also exist in the solid phase, included in interstellar ices in dense clouds. A complex aromatic network is expected on interstellar grains in the diffuse interstellar medium. The existence of an aromatic kerogen-like structure in carbonaceous meteorites and its similarity with interstellar spectra suggests a link between interstellar matter and primitive Solar System bodies.     

Interstellar dust in the neighbourhood of the sun

The distribution of interstellar dust within 500 pc from the sun obtained from recent investigations is described. Statistical properties of dust clouds in the neighbourhood of the sun and individual data of two near clouds in high galactic latitudes are discussed. The present knowledge of the chemical composition of the interstellar dust grains is outlined. Possible relations between solar system solids and interstellar solids are indicated.     

Force-free magnetic field in a cylindrical flux rope without a constant alpha

It is generally assumed that magnetic fields inside interplanetary magnetic clouds and flux ropes in the solar photosphere are force-free. In order to model such fields, the solution of rot B = B is commonly used where  = const. But comparisons of this solutions with observations show significant difference. To treat this problem,we examine the solutions with .     

Comets and life.

Some of the chemical species which have been detected in comets include H2O, HCN, CH3CN, CO, CO2, NH3, CS, C2 and C3. All of these have also been detected in the interstellar medium, indicating a probable relationship between interstellar dust and gas clouds and comets. Laboratory experiments carried out with different mixtures of these molecules give rise to the formation of the biochemical compounds which are necessary for life, such as amino acids, purines, pyrimidines, monosaccharides, etc. However, in spite of suggestions to the contrary, the presence of life in comets is unlikely. On the other hand, the capture of cometary matter by the primitive Earth is considered essential for the development of life on this planet. The amount of cometary carbon-containing matter captured by the Earth, as calculated by different authors, is several times larger than the total amount of organic matter present in the biosphere (10(18)g). The major classes of reactions which were probably involved in the formation of key biochemical compounds are discussed. Our tentative conclusions are that: 1) comets played a predominant role in the emergence of life on our planet, and 2) they are the cosmic connection with extraterrestrial life.     

The formation of organic molecules in astronomical ices.

An absorption feature at 3.4 micrometers has been observed in various lines-of-sight through the diffuse interstellar medium. Its position and width lead to an identification with the C-H stretching mode of solid organic material. A possible mechanism for the production of organic solids in the interstellar medium is UV photoprocessing of icy mantles which accrete on dust grains in dense clouds. Furthermore, thermally induced reactions involving formaldehyde molecules in the mantles could be an important source of organics. Laboratory simulation of these processes shows that a large variety of oxygen- and nitrogen-rich species may be produced. It is shown that the occurrence of periodic transient heating events plays an important role in the production of organic material in the ice mantles. Finally, it is pointed out how future missions like the Infrared Space Observatory (ISO) as well as analysis of comet material by Rosetta may be able to clarify the nature and evolution of interstellar organics.     

Organic molecules in the gas phase of dense interstellar clouds.

Since a previous COSPAR review on this subject, the number of molecular species identified by astronomers in dense interstellar clouds or in the envelopes expelled by evolved stars has grown from about eighty to approximately one hundred. Recent detections in stellar envelopes include the radical CP, the second phosphorus-containing astronomical molecule; SiN, the first astronomical molecule with a Si-N bond; and the HCCN radical. In the dense interstellar clouds recent detections or verifications of previous possible identifications include the H3O+ ion, which is a critical intermediary in the production of H2O and O2; the CCO radical, which is isoelectronic with HCCN; the SO+ ion, which appears to be diagnostic of shock chemistry; two new isomers of cyanoacetylene, HCCNC and CCCNH; and the two cumulenes H2C3 and H2C4. Some recent work is also described on the mapping of interstellar clouds in multiple molecular transitions in order to separate variations in chemical abundance from gradients in physical parameters.     

Cycling of the local interstellar matter

The origin of the local interstellar matter, especially the hot component, is studied. The bulk of the local interstellar space is occupied with hot low-density matter, which is similar to the gas heated by the shock front of the supernova remnant. We investigate the model that our Sun is located in a superbubble. The superbubbles are observed in Orion-Eridanus region and Gum nebula. The similar objects are found in λ 21 cm H I maps as H I shells and holes. The superbubbles certainly correlate with OB associations and giant molecular clouds. The evolution of superbubbles formed by sequential supernova explosions in an OB association is studied by hydrodynamical simulations. We compare the results with observations. A model of cycling of interstellar matter is presented, in relation to the evolution of the superbubble.     

Large scale MHD properties of interplanetary magnetic clouds

Magnetic Clouds (MCs) are the interplanetary manifestation of Coronal Mass Ejections. These huge astrophysical objects travel from the Sun toward the external heliosphere and can reach the Earth environment. Depending on their magnetic field orientation, they can trigger intense geomagnetic storms. The details of the magnetic configuration of clouds and the typical values of their magnetohydrodynamic magnitudes are not yet well known. One of the most important magnetohydrodynamic quantities in MCs is the magnetic helicity. The helicity quantifies several aspects of a given magnetic structure, such as the twist, kink, number of knots between magnetic field lines, linking between magnetic flux tubes, etc. The helicity is approximately conserved in the solar atmosphere and the heliosphere, and it is very useful to link solar phenomena with their interplanetary counterpart. Since a magnetic cloud carries an important amount of helicity when it is ejected from the solar corona, estimations of the helicity content in clouds can help us to understand its evolution and its coronal origin. In situ observations of magnetic clouds at one astronomical unit are in agreement with a local helical magnetic structure. However, since spacecrafts only register data along a unique direction, several aspects of the global configuration of clouds cannot be observed. In this paper, we review the general properties of magnetic clouds and different models for their magnetic structure at one astronomical unit. We describe the corresponding techniques to analyze in situ measurements. We also quantify their magnetic helicity and compare it with the release of helicity in their solar source for some of the analyzed cases.     

Chemical and biological evolution in space

Astronomical infrared spectra are used to confirm the existence of complex organic molecules produced by ultraviolet photoprocessing of interstellar grain mantles. This material is shown to be the major component of the interstellar grains between the sun and the galactic center and, by inference, constitutes more than 10 million solar masses — or close to one part in a thousand of the entire mass of the milky way galaxy. It may be demonstrated that the primitive chemistry of the earth's surface was dominated by these extraterrestrial molecules after aggregated into comets if the rate of comet impacts with the earth was comparable with that required to account for the extinction of species over the past 300 million years.

Ultraviolet irradiation of bacterial spores has been studied for the first time under simulated interstellar conditions. The inactivation time predicted for the less dense regions of space is at most several hundred years. Within molecukar clouds it is shown on theoretical and experimental grounds that this t the estimated cloud. However survival of spores during their initial exposure to the solar ultraviolet presents a problem for panspermia because it requires that in the process of ejection from the earth's surface they must be enclosed within a cocoon (or mantle) of ultraviolet absorbing material of 0.6 μm thickness. Thus, although panspermia can not be rejected on the basis of lack of interstellar survival there may remain insurmountable obstacles to its occuring because of the very special protective shield requirements during ejection from its planetary source.     

EUV emission from normal galaxies

Using data from the Wide Field Camera EUV all-sky survey, we have established upper limits to the EUV flux from a sample of 30 bright, nearby, non-active spiral galaxies. These galaxies were chosen to be those most likely to be detected in the EUV on the basis of (i) low interstellar absorption within our own galaxy, (ii) brightness in other wavebands, (iii) high star formation activity, and (iv) proximity. The derived EUV upper limits are restrictive, and establish for the first time that the EUV flux escaping from galaxies does not constitute a major component of their bolometric luminosity, and in particular that it cannot be the sink for the energy injected into the interstellar medium by supernova explosions, as had been suggested following the failure to detect this power in the X-ray band.     

On the possible detection of solid O2 and O3 interstellar grains with ISO

In various models of interstellar grain chemistry, solid O₂ is formed by accretion as well as by surface reactions on grains. In dense molecular cloud models, at a later stage of the evolution, the O₂ molecule may become a substantial grain mantle constituent. Since IR dipole vibrational transitions for the homonuclear diatomic molecule O₂ are forbidden, the abundance of this potentially important grain mantle component can not be determined. However, embedded in a dirty ice matrix, the fundamental vibration of O₂ at 1550 cm⁻¹ becomes observable at 10 K, due to interactions with surrounding molecules, which break the symmetry of molecular oxygen. This process might be applicable for the dust mantle environment of interstellar grains. We have studied the role of solid O₂ and O₃ in astrophysically relevant ice mixtures and discuss the possible detection of solid O₂ and its major photolysis product O₃ in interstellar grains, in dense molecular clouds. Both molecules represent a specific target to be observed by the ISO satellite in the near future.     

Heliospheric implications of structure in the interstellar medium

Equilibrium models of diffuse interstellar material (ISM) near the Sun show a range of cloud densities, ionization, and temperatures which are consistent with data, although the local ISM must be inhomogeneous over ∼2 pc scales. The ISM close to the Sun has properties that are consistent with the sheetlike warm neutral (and partially ionized) gas detected in the Arecibo Millennium Survey. Local interstellar magnetic fields are poorly understood, but data showing weak polarization for nearby stars indicate dust may be trapped in fields or currents in the heliosheath nose region. Implications of this dust capture are widespread, and may impact the interpretation of the cosmic microwave background data. Observations of interstellar H⁰ inside of the solar system between 1975 and 2000 do not suggest any variation in the properties or structure of local interstellar H⁰ over distance scales of ∼750 AU to within the uncertainties.     

中子星吸积柱中荷电粒子密度的分布及电场的形成

本文从刘维定理出发,通过相空间求平均,建立了中子星吸积柱中粒子流连续方程和动量迁移方程。并在静力学平衡下求出其解;建立了吸积柱中的荷电粒子分布;引出了某些有趣的新结果。      

Coagulation of grains and gas-grain interactions.

Three-dimensional off-lattice Monte Carlo simulations have been used to simulate the production of interstellar dust analogues on the computer. At first, the two rather well known extreme cases of ballistic growth, i.e. particle-cluster (BPCA) and cluster-cluster aggregation (BCCA) were investigated. In a second step, we included rotation of the clusters during the growth process. Following this, gas particles were deposited on these aggregates taking variable sticking probabilities due to the growth of monolayers into account. This is of interest to the problem of molecular abundances in dark clouds.     

Production and evolution of carbonaceous material by ion irradiation in space.

We review recent experimental studies concerning the evolution, driven by ion irradiation, of carbonaceous material from frozen gas to a refractory molecular solid. Under further irradiation the latter changes to a polymer-like material and ultimately to amorphous carbon. Most of the results have been obtained by "in situ" and remote IR and Raman spectroscopy. The results have been applied to demonstrate that molecular solids may be easily formed by irradiation of frozen mantles in dense interstellar clouds. Polymer-like material and amorphous carbons may result by further irradiation of organic mantles on grains in the diffuse interstellar medium. Those grains, during the aggregation to form extended bodies like comets (T-Tau phase of the Sun), are further modified. These latter are also irradiated, after the comet formation, during their long stay in the Oort cloud. In particular it has been suggested that comet may develop an ion-produced cometary organic crust that laboratory evidences show to be stable against temperature increases experienced during passages near the Sun. The comparison between the Raman spectra of some IDP (Interplanetary Dust Particles) and the Raman spectra of some ion-produced amorphous carbons, is also discussed.