The infrared synthetic spectrum of comet Halley

In order to prepare infrared sounding of comet Halley from the flyby VEGA probes, we have computed the synthetic spectrum between 2.5 and 15 μ of a typical comet at a heliocentric distance of ～ 0.8 AU. The present paper is particularly devoted to the contribution from the cometary gases. For a selection of 20 possible parent molecules, the most efficient excitation process is resonant fluorescence by the solar radiation field. The H₂O, CO, CO₂, CH₄, NH₃ and H₂CO molecules are the best candidates for detection by the IKS infrared spectrometers aboard the VEGA probes. For the water molecule, collisions are too rare to ensure thermal equilibrium in the whole coma ; therefore a limited number of fluorescence lines are expected to be present in the H₂O vibrational bands.     

Mass spectrometric measurements of stratospheric ions

Recent in situ measurements with balloon borne quadrupole mass spectrometers, between 20 and 45 km altitude, are reviewed and discussed.The major stratospheric positive ions observed are proton hydrates [H⁺(H₂O)_n] and non proton hydrates of the form H⁺X_m(H₂O)₂. The data analysis allows a derivation of the vertical mixing ratio profile of X (most probably CH₃CN), which is compared with recent model calculations. From negative ion composition data, showing the presence of NO₃^? and HSO₄^? cluster ions, the density of sulfuric acid in the stratosphere is deduced. The implications of these findings on our understanding of the sulfur chemistry is briefly treated.Finally some other aspects such as contamination, cluster break up and the use of stratospheric ion mass spectra for determination of thermochemical data and other minor constituents are discussed.     

Atmospheric sampling

Four important sampling techniques are briefly reviewed: Selective sampling on impregnated filters for measuring acidic gases, the matrix isolation technique for measuring radicals, whole air grabsampling and whole air cryogenic sampling for measuring stable source gases.Vertical profiles of H₂, CH₄, CO, N₂O, CFCl₃ and CF₂Cl₂ resulting from gas chromatographic analysis of whole air samples collected with a cryogenic sampler are presented. Year-to-year variations are observed for H₂, CH₄ and N₂O above 25 km, while CFCl₃ and CF₂Cl₂ mixing ratios show a noticeable increase between 1977 and 1979 at almost every height level.The CO₂ mixing ratio is not constant with height but rather decreases from 332 ppmV at 10 km to 325 ppmV at 30 km.The vertical distribution of methyl chloride is characterized by a rapid decrease from 600 pptV in the troposphere to less than 10 pptV at 32 km in agreement with model results.     

The escape of molecular hydrogen and the synthesis of organic nitriles in planetary atmospheres.

What is the influence of hydrogen escape from the atmosphere of small planetary bodies on the synthesis of organic molecules in that atmosphere? To answer this question, laboratory experiments have been performed to study the evolution of different reducing model atmospheres submitted to electrical discharges, with and without the simulation of H₂ escape. A study of mixtures of nitrogen and methane shows a very strong effect of H₂ escape on the formation of organic nitriles, the only nitrogen containing organics detected in the gas phase. These are HCN, CH  CCN, (CN)₂, CH₂CHCN, CH₃ CN and CH₃CH₂CN. The yield of synthesis of most of these compounds is noticeably increased, up to several orders of magnitude, when hydrogen escape is simulated. The escape of H₂ from the atmosphere of the primitive Earth may have played a crucial role in the formation of reactive organic molecules such as CHCCN or (CN)₂, which can be considered as important prebiotic precursors. These experimental results may also explain extant data concerning the nature and relative abundance of organics present in the atmosphere of Titan, a planetary satellite which may be an ideal model within our solar system for the study of organic cosmochemistry and exobiology.     

Vertical profiles of halocarbons in the stratosphere

Stratospheric air samples collected between 10 and 35 km altitude my means of a cryogenic sampler were analyzed by gaschromatography. Thus vertical profiles of source gases for halogen radicals were derived, such as CCl₄, CCl₃F, CCl₂F₂, CClF₃, CF₄, C₂F₃Cl₃, C₂F₄Cl₂, C₂F₅Cl, C₂F₆, CH₃Cl, CH₃CCl₃, CHF₂Cl, CH₃Br, CBrF₃, and CBrCl₂F. Systematic discrepancies between measured and modelled halocarbon profiles point to deficiencies of present one- and two-dimensional models. Measurements of fully halogenated hydrocarbons provide a tool for systematically studying these deficiencies and thus improving the models.     

Statistical global and regional atmospheric models of temperature and gas components over the northern hemisphere

Statistical mid-latitude models of altitude distribution of temperature, water vapor, ozone, carbon dioxide and trace gases (CO, CH₄, N₂O, NO, NO₂) are considered. The mean characteristics of altitude profiles of these parameters, as well as their time and space variability, have been taken into account. The statistical regional models were constructed using a temperature-humidy complex. The considered statistical mid-latitude models have been constructed as applied to solutions of the problems on remote sounding of the atmosphere and underlying surface from outer space.     

Proposed reference models for CO2 and halogenated hydrocarbons

The vertical distribution of carbon dioxide, halocarbons and their sink products, HCl and HF, have become available, mainly by means of balloon measurements. Most measurements were made at northern mid-latitudes, but some constituents were measured at tropical latitudes and in the southern hemisphere as well. This report attempts to combine the available data for presentation of reference models for CO₂, CCl₄, CCl₃F, CCl₂F₂, CClF₃, CF₄, CCl₂F-CClF₂, CClF₂-CClF₂, CClF₂-CF₃, CF₃-CF₃, CH₃Cl, CHClF₂, CH₃-CCl₃, CBrClF₂, CBrF₃, HCl and HF.     

陨石、流星体与小行星及彗星的演化关系

小行星、彗星和流星体(meteoroid)都是绕太阳公转的小天体,它们只是在轨道特性和物理-化学性质方面有所不同,流星体泛指在行星际空间运行的、质量从10~(-16)克微流星体或微尘到10~8克的所有小天体,当它们闯入地球大气时与大气剧烈碰撞而产生发光的流星(meteor)现象,落到地面的流星体残余则称为陨石或陨星(meteorite)。     

An icy mineralogy package (IMP) for in-situ studies of Titan’s surface

We describe the scientific case for and preliminary design of an instrument whose primary goal is to determine the chemistry (element abundance) and mineralogy (compound identity and abundance) of Titan’s surface using a combination of energy dispersive X-ray fluorescence spectroscopy (EDXRF) and X-ray diffraction (XRD). XRD is capable of identifying any crystalline substance present on Titan’s surface at relative abundances greater than ∼1 wt%, allowing unambiguous identification of, for example, structure I and II clathrates (even in the presence of ice), and various organic solids, which may include C₂H₂, C₂H₄, C₄H₂, HCN, CH₃CN, HC₃N, and C₄N₂). The XRF component of the instrument will obtain elemental abundances for 16 < Z < 60 with minimum detection limits better than 10 ppm (including detection of atmospheric noble gas isotopes), and may achieve detection limits of 0.01–1% for lighter elements down to Z = 6 (carbon). The instrument is well suited to integration with other analytical tools as part of a light-weight surface chemistry and mineralogy package. Although considerably less sensitive to elemental abundance than GC–MS (10⁻² vs. 10⁻⁸) it is likely to be significantly lighter (<0.5 kg vs. 10 kg).     

Positive ion composition and electron density in a combined auroral and NLC event

The positive ion composition and electron density were measured in the lower ionosphere above Kiruna in salvo A of CAMP (Cold Arctic Mesopause Project). The CAMP/P (S37/P) payload carrying a magnetic ion spectrometer, positive ion and electron probes, and propagation experiments was launched on 3 August 1982 2332 UT during extended Noctilucent Clouds (NLC) and auroral activities over Kiruna. The measured electron density was 5×10³cm^?3 at 80 km and 2.5×10⁵cm^?3 at 90 km. The increase of ion and electron densities in the D- and E-region during twilight was caused by precipitating auroral particles. The height distribution of the positive ions measured by the mass spectrometer in the mass range 19–280 amu is different from a winter flight with similar auroral conditions. Below 85.5 km proton hydrates H⁺(H₂O)₃ ? H⁺(H₂O)₈ were the dominant ions. The heaviest proton hydrates H⁺(H₂O)₇ and H⁺(H₂O)₈ were most abundant at 82–85.5 km, the altitude of visible NLC. Above 85.5 km O₂⁺ and NO⁺ became dominant. A small metal ion layer was observed between 90.5–93 km with a maximum ion density of 10% of the total positive ion density at 91 km altitude. The metal ion density disappeared within about a km below 90.5 km.     

Meteorites,asteroids and comets — A study of their interrelationship

The origins of the three kinds of extra-terrestrial bodies, meteorites, asteroids and comets can be traced to the origin of solar system. From a study of their properties, a generic relatinship of the form interstellar gas and dust condensing in the primitive solar nebula leading to the formation of comets, the comets getting degassed and ablated to become asteroids and the asteroids on fragmentation due to collisions becoming meteorites, is advocated here. The isotopic abundances of carbon are suggested as the key to unlock the mystery of this relationship.     

Composition of the Venus atmosphere below 100 km altitude

Our current knowledge on the composition of the Venus atmosphere in the altitude range from the surface to 100 km is compiled. Gases that have been measured, and whose mixing ratios are assumed to be constant with altitude, are CO₂, N₂, He, Ne, Ar, and Kr. Gases that have been identified in the lower and/or middle atmosphere, but whose mixing ratios may depend on altitude, latitude and/or local time, are CO, H₂O, HCl, HF, and SO₂. Conflicting data or only upper limits exist on some important trace gases, such as O₂, H₂, and Cl₂. The latter two are key constituents in the photochemistry of the middle atmosphere of Venus. The chapter concludes with a listing of the isotopic abundances of elements measured in the Venus atmosphere.     

Trace constituents measurements deduced from spectrometric observations on-board spacelab

The observation of infrared absorption lines by means of a grille spectrometer on board Spacelab 1 allows the determination of Co₂ and CO in the low thermosphere and in the middle atmosphere. Equal abundances of CO and CO₂ are found at 115 ± 5 km altitude. CO₂ is observed to depart from its homospheric volume mixing ratio near 100 km, dropping by a factor of 10,15 km higher. The CO largest number density is observed near 70 km altitude, close to the H Lyman alpha photoproduction peak.The analysis of one run dedicated to the observation of water vapor shows a middle atmospheric mixing ratio of this species within the limits : 3 to 8 ppmv up to 70 km altitude, with the indication of an increase from 30 to 50 km altitude. The H₂O mixing ratio drops very rapidly above 70 km.The comparison of the results from strong and weak H₂O and CO₂ lines shows the need to refine the line profile model.     

On the mechanisms of cooling of the nightside thermosphere of venus

The plausible mechanisms of cooling of the nightside Venus' thermosphere are analysed with the aid of the model of the atmospheric heat budget that incorporates, in addition to thermal conduction and IR radiation in the 15 μ band of CO₂, heating and cooling due to global scale winds, eddy turbulence, and IR radiation in the rotational bands of H₂O and CO, as well as the 63 μ line of atomic oxygen. The H₂O mixing ratio and parameters of turbulence required for cooling of the thermosphere down to the observed low temperatures are evaluated.     

Plasma chemical reactions in C2H2/N2, C2H4/N2, and C2H6/N2 gas mixtures of a laboratory dielectric barrier discharge

Plasma chemical reactions in C₂H₂/N₂, C₂H₄/N₂, and C₂H₆/N₂ gas mixtures have been studied by means of mass spectrometry at a medium pressure of 300 mbar in a laboratory dielectric barrier discharge. A major reaction scheme is production of larger hydrocarbons like C_nH_m with n up to 12 including formation of functional CN groups.     

Organic syntheses in gas phase and chemical evolution in planetary atmospheres

Atmospheric chemistry may be one of the important pathways to the synthesis of organic compounds in a planetary periphery. Depending on the nature of the carbon source (CH₄, CO or CO₂), the main composition of the atmosphere, and the respective roles of the various energy sources, is it possible, and to what extent, to produce organics? What kind of gaseous mixture is the most favourable to prebiotic organic syntheses? How far can the results of laboratory works be extrapolated to the case of planetary atmospheres? These questions are discussed, on the basis of several available laboratory data, and by considering the main atmospheric composition of the planets of the solar system, and the list of organic compounds which have already been dettected in their atmospheres.     

High-density and high-temperature molecular gas around the AGN in M51

We investigated the physical properties of molecular gas in the nuclear region of M51 (Seyfert 2). We obtained an aperture synthesis ¹³CO(J = 1 − 0) image using the Nobeyama Millimeter Array (NMA), and compared it with NMA ¹²CO(J = 1 − 0) and HCN(J = 1 − 0) maps at similar spatial resolutions. Within a radius of 180 pc from the center, the ¹³CO(1 − 0) integrated intensity was found to be 3 times weaker than that of HCN(1 − 0). Large-Velocity-Gradient (LVG) calculations suggest that the observed high HCN(1 − 0)/¹³CO(1 − 0) intensity ratio would arise from dense (n_H2 ∼ 10⁵ cm⁻³) and hot (T_kin ≳ 300 K) molecular clouds in the nuclear molecular disk. We also observed in the ¹²CO(1 − 0), (3 − 2), ¹³CO(1 − 0), and (3 − 2) lines using the Nobeyama 45m and JCMT 15m telescopes. We detected weak ¹³CO lines as well as strong ¹²CO lines. The LVG calculations assuming a two-component model suggest that there is a large amount of low-density (n_H2 ∼ 3 − 6 × 10² cm⁻³), low-temperature (T_kin ∼ 20 – 50 K) gas, and a small amount of high-density (n_H2 ≳ 10⁴ cm⁻³), high-temperature (T_kin ≳ 500 K) gas. The existence of the high-density and high-temperature component, although having a quite small beam filling factor, supports the aperture synthesis observation results mentioned above. Since this dense, hot gas is located in the nuclear molecular disk around the Active Galactic Nucleus (AGN), it may be heated by the strong X-ray radiation and/or by the shock induced by the radio jet.     

Vertical profiles of source gases at tropical latitudes

A first ISRO-DFVLR collaborative balloon flight of the MPAE cryogenic sampler was conducted at Hyderabad, India (17.5°N), on March 27 1985, and 15 air samples were collected between 10 and 35 km altitude. Vertical profiles of source gases analysed from these samples, such as CCl₃F, CCl₂F₂, CBrClF₂, and CH₄ are presented. Due to tropical upwelling, mixing ratios of source gases decrease less rapidly with altitude than at mid-latitudes.