HF-W Chronometry and Inner Solar System Accretion Rates

Models for the mechanisms of accretion of the terrestrial planets are re-examined using the experimental technique of high-precision isotope ratio mass spectrometry of tungsten (W). The decay of ¹⁸²Hf to ¹⁸²W (via ¹⁸²Ta) provides a new kind of radiometric chronometer of planet formation processes. Hafnium and W, the parent and daughter trace elements, are highly refractory; however, Hf is lithophile and strongly partitioned into the silicate portion of a planet, whereas W is moderately siderophile and preferentially partitioned into a coexisting metallic phase. More than 90% of terrestrial W has gone into the Earth's core during its formation. The residual silicate portion, the Earth's primitive mantle, has a Hf/W ratio in the range 10−40, an order of magnitude higher than chondritic (∼1.3). Tungsten isotopic data for the Earth and the Moon suggest that we can date a major event of planet formation: The Moon formed about 50 Myrs after the start of the solar system, providing strong support for the Giant Impact Theory of lunar origin. Recent simulations of this event imply that the Earth was probably only half formed at the time. From this we can deduce the planetary accretion rate. Tungsten isotope data for Mars provide evidence of a much shorter accretion interval, perhaps as little as 10 Myrs, but the rates for the Earth over the same time interval could have been comparable. The large W isotopic heterogeneities on Mars could only have been produced within the first 30 Myrs of the solar system. Large-scale mixing, e.g. from convective overturn, as is thought to drive the Earth's plates, must be absent from Mars. Limitations of the method such as 1) cosmogenic ¹⁸²Ta effects on lunar samples, 2) incomplete mixing of debris to cause W isotope heterogeneity on the Moon, and 3) initial ¹⁸²Hf/¹⁸⁰Hf heterogeneities of the early solar system are critically discussed. This revised version was published online in June 2006 with corrections to the Cover Date.     

A Comparative Study of the Influence of the Active Young Sun on the Early Atmospheres of Earth, Venus, and Mars

Because the solar radiation and particle environment plays a major role in all atmospheric processes such as ionization, dissociation, heating of the upper atmospheres, and thermal and non-thermal atmospheric loss processes, the long-time evolution of planetary atmospheres and their water inventories can only be understood within the context of the evolving Sun. We compare the effect of solar induced X-ray and EUV (XUV) heating on the upper atmospheres of Earth, Venus and Mars since the time when the Sun arrived at the Zero-Age-Main-Sequence (ZAMS) about 4.6 Gyr ago. We apply a diffusive-gravitational equilibrium and thermal balance model for studying heating of the early thermospheres by photodissociation and ionization processes, due to exothermic chemical reactions and cooling by IR-radiating molecules like CO₂, NO, OH, etc. Our model simulations result in extended thermospheres for early Earth, Venus and Mars. The exospheric temperatures obtained for all the three planets during this time period lead to diffusion-limited hydrodynamic escape of atomic hydrogen and high Jeans’ escape rates for heavier species like H₂, He, C, N, O, etc. The duration of this blow-off phase for atomic hydrogen depends essentially on the mixing ratios of CO₂, N₂ and H₂O in the atmospheres and could last from ∼100 to several hundred million years. Furthermore, we study the efficiency of various non-thermal atmospheric loss processes on Venus and Mars and investigate the possible protecting effect of the early martian magnetosphere against solar wind induced ion pick up erosion. We find that the early martian magnetic field could decrease the ion-related non-thermal escape rates by a great amount. It is possible that non-magnetized early Mars could have lost its whole atmosphere due to the combined effect of its extended upper atmosphere and a dense solar wind plasma flow of the young Sun during about 200 Myr after the Sun arrived at the ZAMS. Depending on the solar wind parameters, our model simulations for early Venus show that ion pick up by strong solar wind from a non-magnetized planet could erode up to an equivalent amount of ∼250 bar of O⁺ ions during the first several hundred million years. This accumulated loss corresponds to an equivalent mass of ∼1 terrestrial ocean (TO (1 TO ∼1.39×10²⁴ g or expressed as partial pressure, about 265 bar, which corresponds to ∼2900 m average depth)). Finally, we discuss and compare our findings with the results of preceding studies.     

The Accretion, Composition and Early Differentiation of Mars

The early development of Mars is of enormous interest, not just in its own right, but also because it provides unique insights into the earliest history of the Earth, a planet whose origins have been all but obliterated. Mars is not as depleted in moderately volatile elements as are other terrestrial planets. Judging by the data for Martian meteorites it has Rb/Sr 0.07 and K/U 19,000, both of which are roughly twice as high as the values for the Earth. The mantle of Mars is also twice as rich in Fe as the mantle of the Earth, the Martian core being small (20% by mass). This is thought to be because conditions were more oxidizing during core formation. For the same reason a number of elements that are moderately siderophile on Earth such as P, Mn, Cr and W, are more lithophile on Mars. The very different apparent behavior of high field strength (HFS) elements in Martian magmas compared to terrestrial basalts and eucrites may be related to this higher phosphorus content. The highly siderophile element abundance patterns have been interpreted as reflecting strong partitioning during core formation in a magma ocean environment with little if any late veneer. Oxygen isotope data provide evidence for the relative proportions of chondritic components that were accreted to form Mars. However, the amount of volatile element depletion predicted from these models does not match that observed — Mars would be expected to be more depleted in volatiles than the Earth. The easiest way to reconcile these data is for the Earth to have lost a fraction of its moderately volatile elements during late accretionary events, such as giant impacts. This might also explain the non-chondritic Si/Mg ratio of the silicate portion of the Earth. The lower density of Mars is consistent with this interpretation, as are isotopic data. ⁸⁷Rb-⁸⁷Sr, ¹²⁹I-¹²⁹Xe, ¹⁴⁶Sm-¹⁴²Nd, ¹⁸²Hf-¹⁸²W, ¹⁸⁷Re-¹⁸⁷Os, ²³⁵U-²⁰⁷Pb and ²³⁸U-²⁰⁶Pb isotopic data for Martian meteorites all provide evidence that Mars accreted rapidly and at an early stage differentiated into atmosphere, mantle and core. Variations in heavy xenon isotopes have proved complicated to interpret in terms of ²⁴⁴Pu decay and timing because of fractionation thought to be caused by hydrodynamic escape. There are, as yet, no resolvable isotopic heterogeneities identified in Martian meteorites resulting from ⁹²Nb decay to ⁹²Zr, consistent with the paucity of perovskite in the martian interior and its probable absence from any Martian magma ocean. Similarly the longer-lived ¹⁷⁶Lu-¹⁷⁶Hf system also preserves little record of early differentiation. In contrast W isotope data, Ba/W and time-integrated Re/Os ratios of Martian meteorites provide powerful evidence that the mantle retains remarkably early heterogeneities that are vestiges of core metal segregation processes that occurred within the first 20 Myr of the Solar System. Despite this evidence for rapid accretion and differentiation, there is no evidence that Mars grew more quickly than the Earth at an equivalent size. Mars appears to have just stopped growing earlier because it did not undergo late stage (>20 Myr), impacts on the scale of the Moon-forming Giant Impact that affected the Earth.     

Venus Interior Structure and Dynamics

No two rocky bodies offer a better laboratory for exploring the conditions controlling interior dynamics than Venus and Earth. Their similarities in size, density, distance from the sun, and young surfaces would suggest comparable interior dynamics. Although the two planets exhibit some of the same processes, Venus lacks Earth’s dominant process for losing heat and cycling volatiles between the interior and the surface and atmosphere: plate tectonics. One commonality is the size and number of mantle plume features which are inferred to be active today and arise at the core mantle boundary. Such mantle plumes require heat loss from the core, yet Venus lacks a measurable interior dynamo. There is evidence for plume-induced subduction on Venus, but no apparent mosaic of moving plates. Absent plate tectonics, one essential question for interior dynamics is how did Venus obtain its young resurfacing age? Via catastrophic or equilibrium processes? Related questions are how does it lose heat via past periods of plate tectonics, has it always had a stagnant lid, or might it have an entirely different mode of heat loss? Although there has been no mission dedicated to surface and interior processes since the Magellan mission in 1990, near infrared surface emissivity data that provides information on the iron content of the surface mineralogy was obtained fortuitously from Venus Express. These data imply both the presence of continental-like crust, and thus formation in the presence of water, and recent volcanism at mantle hotspots. In addition, the study of interior dynamics for both Earth and exoplanets has led to new insights on the conditions required to initiate subduction and develop plate tectonics, including the possible role of high temperature lithosphere, and a renewed drive to reveal why Venus and Earth differ. Here we review current data that constrains the interior dynamics of Venus, new insights into its interior dynamics, and the data needed to resolve key questions.     

Locations of Atmospheric Photoelectron Energy Peaks Within the Mars Environment

By identifying peaks in the photoelectron spectrum produced by photoionization of CO₂ in the Martian atmosphere, we have conducted a pilot study to determine the locations of these photoelectrons in the space around Mars. The significant result of this study is that these photoelectrons populate a region around Mars bounded externally by the magnetic pileup boundary, and internally by the lowest altitude of our measurements (∼250 km) on the dayside and by a cylinder of approximately the planetary radius on the nightside. It is particularly noteworthy that the photoelectrons on the nightside are observed from the terminator plane tailward to a distance of ∼3 R _M, the Mars Express apoapsis. The presence of the atmospherically generated photoelectrons on the nightside of Mars may be explained by direct magnetic field line connection between the nightside observation locations and the Martian dayside ionosphere. Thus the characteristic photoelectron peaks may be used as tracers of magnetic field lines for the study of the magnetic field configuration and particle transport in the Martian environment.     

Interior Evolution of Mercury

The interior evolution of Mercury—the innermost planet in the solar system, with its exceptional high density—is poorly known. Our current knowledge of Mercury is based on observations from Mariner 10’s three flybys. That knowledge includes the important discoveries of a weak, active magnetic field and a system of lobate scarps that suggests limited radial contraction of the planet during the last 4 billion years. We review existing models of Mercury’s interior evolution and further present new 2D and 3D convection models that consider both a strongly temperature-dependent viscosity and core cooling. These studies provide a framework for understanding the basic characteristics of the planet’s internal evolution as well as the role of the amount and distribution of radiogenic heat production, mantle viscosity, and sulfur content of the core have had on the history of Mercury’s interior. The existence of a dynamo-generated magnetic field suggests a growing inner core, as model calculations show that a thermally driven dynamo for Mercury is unlikely. Thermal evolution models suggest a range of possible upper limits for the sulfur content in the core. For large sulfur contents the model cores would be entirely fluid. The observation of limited planetary contraction (∼1–2 km)—if confirmed by future missions—may provide a lower limit for the core sulfur content. For smaller sulfur contents, the planetary contraction obtained after the end of the heavy bombardment due to inner core growth is larger than the observed value. Due to the present poor knowledge of various parameters, for example, the mantle rheology, the thermal conductivity of mantle and crust, and the amount and distribution of radiogenic heat production, it is not possible to constrain the core sulfur content nor the present state of the mantle. Therefore, it is difficult to robustly predict whether or not the mantle is conductive or in the convective regime. For instance, in the case of very inefficient planetary cooling—for example, as a consequence of a strong thermal insulation by a low conductivity crust and a stiff Newtonian mantle rheology—the predicted sulfur content can be as low as 1 wt% to match current estimates of planetary contraction, making deep mantle convection likely. Efficient cooling—for example, caused by the growth of a crust strongly in enriched in radiogenic elements—requires more than 6.5 wt% S. These latter models also predict a transition from a convective to a conductive mantle during the planet’s history. Data from future missions to Mercury will aid considerably our understanding of the evolution of its interior.     

Geochemical Reservoirs and Timing of Sulfur Cycling on Mars

Sulfate-dominated sedimentary deposits are widespread on the surface of Mars, which contrasts with the rarity of carbonate deposits, and indicates surface waters with chemical features drastically different from those on Earth. While the Earth’s surface chemistry and climate are intimately tied to the carbon cycle, it is the sulfur cycle that most strongly influences the Martian geosystems. The presence of sulfate minerals observed from orbit and in-situ via surface exploration within sedimentary rocks and unconsolidated regolith traces a history of post-Noachian aqueous processes mediated by sulfur. These materials likely formed in water-limited aqueous conditions compared to environments indicated by clay minerals and localized carbonates that formed in surface and subsurface settings on early Mars. Constraining the timing of sulfur delivery to the Martian exosphere, as well as volcanogenic H₂O is therefore central, as it combines with volcanogenic sulfur to produce acidic fluids and ice. Here, we reassess and review the Martian geochemical reservoirs of sulfur from the innermost core, to the mantle, crust, and surficial sediments. The recognized occurrences and the mineralogical features of sedimentary sulfate deposits are synthesized and summarized. Existing models of formation of sedimentary sulfate are discussed and related to weathering processes and chemical conditions of surface waters. We also review existing models of sulfur content in the Martian mantle and analyze how volcanic activities may have transferred igneous sulfur into the exosphere and evaluate the mass transfers and speciation relationships between volcanic sulfur and sedimentary sulfates. The sedimentary clay-sulfate succession can be reconciled with a continuous volcanic eruption rate throughout the Noachian-Hesperian, but a process occurring around the mid-Noachian must have profoundly changed the composition of volcanic degassing. A hypothetical increase in the oxidation state or in water content of Martian lavas or a decrease in atmospheric pressure is necessary to account for such a change in composition of volcanic gases. This would allow the pre mid-Noachian volcanic gases to be dominated by water and carbon-species but late Noachian and Hesperian volcanic gases to be sulfur-rich and characterized by high SO₂ content. Interruption of early dynamo and impact ejection of the atmosphere may have decreased the atmospheric pressure during the early Noachian whereas it remains unclear how the redox state or water content of lavas could have changed. Nevertheless, volcanic emission of SO₂ rich gases since the late Noachian can explain many features of Martian sulfate-rich regolith, including the mass of sulfate and the particular chemical features (i.e. acidity) of surface waters accompanying these deposits. How SO₂ impacted on Mars’s climate, with possible short time scale global warming and long time scale cooling effects, remains controversial. However, the ancient wet and warm era on Mars seems incompatible with elevated atmospheric sulfur dioxide because conditions favorable to volcanic SO₂ degassing were most likely not in place at this time.     

Long Term Climate Records from Polar Ice

One of the great challenges in climate research is to investigate the principal mechanisms that control global climatic changes and an effective way to learn more about it, is the reconstruction of past climate changes. The most important sources of information about such changes and the associated composition of the atmosphere are the two large ice caps of Greenland and Antarctica. Analysis of ice cores is the most powerful means we have to determine how climate has changed over the last few climatic cycles, and to relate this to changes in atmospheric composition, in particular to concentrations of the principal greenhouse gases – CO₂, CH₄ and N₂O (carbon dioxide, methane, and nitrous oxide).Transitions from cold ice age climates to warmer interstadials have always been accompanied by an increase of the atmospheric concentration of the three principal greenhouse gases. This increase has been, at least for CO₂, vital for the ending of glacial epochs. A highly simplified course of events for the past four transitions would then be as follows: first, changing orbital parameters initiated the end of the glacial epoch; second, an increase in greenhouse gases then amplified the weak orbital signal; third, in the second half of the transition, warming was further amplified by decreasing albedo, caused by melting of the large ice sheets in the Northern Hemisphere going parallel with a change of the ocean circulation.The isotopic records of Greenland ice cores show evidence for fast and drastic climatic changes during the last glacial epoch. Possible causes and mechanisms of such changes and their significance as global climatic events are discussed here. Ice core results also enable the reaction of the environment to past global changes to be investigated.It will also be discussed how reliable stable isotope records are as a local temperature proxy and how representative paleoclimatic results from Greenland and Antarctica are in relation to global climate.     

Water and Volatile Inventories of Mercury,Venus, the Moon,and Mars

We review the geochemical observations of water, \(\mbox{D}/\mbox{H}\) and volatile element abundances of the inner Solar System bodies, Mercury, Venus, the Moon, and Mars. We focus primarily on the inventories of water in these bodies, but also consider other volatiles when they can inform us about water. For Mercury, we have no data for internal water, but the reducing nature of the surface of Mercury would suggest that some hydrogen may be retained in its core. We evaluate the current knowledge and understanding of venusian water and volatiles and conclude that the venusian mantle was likely endowed with as much water as Earth of which it retains a small but non-negligible fraction. Estimates of the abundance of the Moon’s internal water vary from Earth-like to one to two orders of magnitude more depleted. Cl, K, and Zn isotope anomalies for lunar samples argue that the giant impact left a unique geochemical fingerprint on the Moon, but not the Earth. For Mars, an early magma ocean likely generated a thick crust; this combined with a lack of crustal recycling mechanisms would have led to early isolation of the Martian mantle from later delivery of water and volatiles from surface reservoirs or late accretion. The abundance estimates of Martian mantle water are similar to those of the terrestrial mantle, suggesting some similarities in the water and volatile inventories for the terrestrial planets and the Moon.     

Simultaneous Observations of Solar Energetic Particle Events by imp 8 and the Ulysses Cospin High Energy Telescope at High Solar Latitudes

With Ulysses approaching the south solar polar latitudes during a period of high solar activity, it is for the first time possible to study the distribution of solar energetic particles (SEPs) in solar latitude as well as in radius and longitude. From July 1997 to August 2000, Ulysses moved from near the solar equator at ∼5 AU to ∼67° S latitude at ∼3 AU. Using observations of >∼30 MeV protons from Ulysses and IMP-8 at Earth we find good correlation between large SEP increases observed at IMP and Ulysses, almost regardless of the relative locations of the spacecraft. The observations show that within a few days after injection of SEPs, the flux in the inner heliosphere is often almost uniform, depending only weakly on the position of the observer. No clear effect of the increasing solar latitude of Ulysses is evident. Since the typical latitudinal extent of CMEs, which most likely accelerate the SEPs, is only ∼30°, this suggests that the enhanced cross-field propagation for cosmic rays and CIR-accelerated particles deduced from Ulysses’ high latitude studies near solar minimum is also true for SEPs near solar maximum. This revised version was published online in August 2006 with corrections to the Cover Date.     

The Cosmic Ray Nucleonic Component: The Invention and Scientific Uses of the Neutron Monitor – (Keynote Lecture)

The invention of the neutron monitor pile for the study of cosmic-ray intensity-time and energy changes began with the discovery in 1948 that the nucleonic component cascade in the atmosphere had a huge geomagnetic latitude dependence. For example, between 0° and 60° this dependence was a ∼ 200–400% effect – depending on altitude – thus opening the opportunity to measure the intensity changes in the arriving cosmic-ray nuclei down to ∼1–2 GeV nucl⁻¹ for the first time. In these measurements the fast (high energy) neutron intensity was shown to be a surrogate for the nuclear cascade intensity in the atmosphere. The development of the neutron monitor in 1948–1951 and the first geomagnetic latitude network will be discussed. Among its early applications were: (1) to prove that there exists interplanetary solar modulation of galactic cosmic-rays (1952), and; (2) to provide the evidence for a dynamical heliosphere (1956). With the world-wide distribution of neutron monitor stations that are presently operating (∼ 50) many novel investigations are still to be carried out, especially in collaborations with spacecraft experiments. This revised version was published online in August 2006 with corrections to the Cover Date.     

Thermal Evolution and Magnetic Field Generation in Terrestrial Planets and Satellites

Of the terrestrial planets, Earth and Mercury have self-sustained fields while Mars and Venus do not. Magnetic field data recorded at Ganymede have been interpreted as evidence of a self-generated magnetic field. The other icy Galilean satellites have magnetic fields induced in their subsurface oceans while Io and the Saturnian satellite Titan apparently are lacking magnetic fields of internal origin altogether. Parts of the lunar crust are remanently magnetized as are parts of the crust of Mars. While it is widely accepted that the magnetization of the Martian crust has been caused by an early magnetic field, for the Moon alternative explanations link the magnetization to plasma generated by large impacts. The necessary conditions for a dynamo in the terrestrial planets and satellites are the existence of an iron-rich core that is undergoing intense fluid motion. It is widely accepted that the fluid motion is caused by convection driven either by thermal buoyancy or by chemical buoyancy or by both. The chemical buoyancy is released upon the growth of an inner core. The latter requires a light alloying element in the core that is enriched in the outer core as the solid inner core grows. In most models, the light alloying element is assumed to be sulfur, but other elements such as, e.g., oxygen, silicon, and hydrogen are possible. The existence of cores in the terrestrial planets is either proven beyond reasonable doubt (Earth, Mars, and Mercury) or the case for a core is compelling as for Venus and the Moon. The Galilean satellites Io and Ganymede are likely to have cores judging from Galileo radio tracking data of the gravity fields of these satellites. The case is less clear cut for Europa. Callisto is widely taken as undifferentiated or only partially differentiated, thereby lacking an iron-rich core. Whether or not Titan has a core is not known at the present time. The terrestrial planets that do have magnetic fields either have a well-established inner core with known radius and density such as Earth or are widely agreed to have an inner core such as Mercury. The absence of an inner core in Venus, Mars, and the Moon (terrestrial bodies that lack fields) is not as well established although considered likely. The composition of the Martian core may be close to the Fe–FeS eutectic which would prevent an inner core to grow as long as the core has not cooled to temperatures around 1500 Kelvin. Venus may be on the verge of growing an inner core in which case a chemical dynamo may begin to operate in the geologically near future. The remanent magnetization of the Martian and the lunar crust is evidence for a dynamo in Mars’ and possibly the Moon’s early evolution and suggests that powerful thermally driven dynamos are possible. Both the thermally and the chemically driven dynamo require that the core is cooled at a sufficient rate by the mantle. For the thermally driven dynamo, the heat flow from the core into the mantle must by larger than the heat conducted along the core adiabat to allow a convecting core. This threshold is a few mW?m^?2 for small planets such as Mercury, Ganymede, and the Moon but can be as large as a few tens mW?m^?2 for Earth and Venus. The buoyancy for both dynamos must be sufficiently strong to overcome Ohmic dissipation. On Earth, plate tectonics and mantle convection cool the core efficiently. Stagnant lid convection on Mars and Venus are less efficient to cool the core but it is possible and has been suggested that Mars had plate tectonics in its early evolution and that Venus has experienced episodic resurfacing and mantle turnover. Both may have had profound implications for the evolution of the cores of these planets. It is even possible that inner cores started to grow in Mars and Venus but that the growth was frustrated as the mantles heated following the cessation of plate tectonics and resurfacing. The generation of Ganymede’s magnetic field is widely debated. Models range from magneto-hydrodynamic convection in which case the field will not be self-sustained to chemical and thermally-driven dynamos. The wide range of possible compositions for Ganymede’s core allows models with a completely liquid near eutectic Fe–FeS composition as well as models with Fe inner cores or cores in with iron snowfall.     

The Substorm Onset Location Controversy

Recent development of popular substorm onset models was driven by the apparent controversy between ground onset mapping in the near-Earth tail and statistics of tailward flow observations (reconnection signatures), pointing to ∼ -25 R _E downtail. However, several comprehensive multi-point event studies, taking into account backward tracing of flows, place plasmoid origin closer to the near-Earth location, in better consistency with auroral onset observations. Accuracy of such remote onset positioning is about a couple of Earth radii. We further discuss possibilities of reconciliation of different onset scenarios and future critical experiments.     

Thermospheric X-Ray and Euv Heating by the Young Sun on Early Venus and Mars

In view of the low H₂O abundance in the present Venusian and Martian atmospheres several observations by spacecraft and studies suggest that both planets should have lost most of their water over the early active period of the young Sun. During the first Gyr after the Sun arrived at the Zero- Age-Main-Sequence high X-ray and EUV fluxes between 10 and 100 times that of the present Sun were responsible for much higher temperatures in the thermosphere-exosphere environments on both planets. By applying a diffusive-gravitational equilibrium and thermal balance model for investigating radiation impact on the early thermospheres by photodissociation and ionization processes, due to exothermic chemical reactions and cooling by CO₂ IR emission in the 15μm band we found expanded thermospheres with exobase levels between about 200 km (present) and 2000 km (4.5 Gyr ago). The higher temperatures in the upper atmospheres of both planets could reach “blow-off” conditions for H atoms even at high CO₂ mixing ratios of 96%. Lower CO₂/N₂ mixing ratio or higher contents of H2O vapor in the early atmospheres could have had a dramatic impact from the loss of atmosphere and water on both planets. The duration of this phase of high thermal loss rates essentially depended on the mixing ratios of CO₂, N₂, and H₂O in the early atmospheres and could have lasted between about 150 and several hundred Myr.     

The Advanced Composition Explorer

The Advanced Composition Explorer was launched August 25, 1997 carrying six high-resolution spectrometers that measure the elemental, isotopic, and ionic charge-state composition of nuclei from H to Ni (1≤Z≤28) from solar wind energies (∼1 keV nucl−1) to galactic cosmic-ray energies (∼500 MeV nucl−1). Data from these instruments is being used to measure and compare the elemental and isotopic composition of the solar corona, the nearby interstellar medium, and the Galaxy, and to study particle acceleration processes that occur in a wide range of environments. ACE also carries three instruments that provide the heliospheric context for ion composition studies by monitoring the state of the interplanetary medium. From its orbit about the Sun-Earth libration point ∼1.5 million km sunward of Earth, ACE also provides real-time solar wind measurements to NOAA for use in forecasting space weather. This paper provides an introduction to the ACE mission, including overviews of the scientific goals and objectives, the instrument payload, and the spacecraft and ground systems. This revised version was published online in June 2006 with corrections to the Cover Date.     

Pollution of the upper atmosphere by rockets

This report estimates the amounts of various constituents that would have to be continually injected by rockets into the upper atmosphere in order to double the worldwide natural concentrations there. Involved in the calculations are: (a) the natural atmospheric abundances of constituents such as H₂O, CO₂, NO, Na, K, Li, H, etc.; (b) the residence times in various regions of the atmosphere, since these determine how rapidly a constituent will be removed; and (c) the chemical or photochemical stability of a substance exposed to the upper atmosphere environment. It is concluded that a doubling of the CO₂, H₂O, or NO content would require per year on the order of 10³ to 10⁵ Saturn-type rockets, each injecting 100 tons of exhaust above 100 km. On the other hand, a few hundred small rockets per year, each containing 10 kg of the chemical, would probably double the Na content; similarly, less than two such rockets per year would be expected to double the Li content. These last conclusions have implications for future tracer experiments using these substances.The author is now an Associate Director of the National Center for Atmospheric Research (NCAR) in Boulder, Colorado. The work reported here was supported by the United States Air Force under Contract AF 49(638)-700 with the RAND Corporation. The views or conclusions contained in this paper should not, however, be interpreted as representing the official opinion of the United States Air Force.     

Alteration Assemblages in Martian Meteorites: Implications for Near-Surface Processes

The SNC (Shergotty-Nakhla-Chassigny) meteorites have recorded interactions between martian crustal fluids and the parent igneous rocks. The resultant secondary minerals — which comprise up to 1 vol.% of the meteorites — provide information about the timing and nature of hydrous activity and atmospheric processes on Mars. We suggest that the most plausible models for secondary mineral formation involve the evaporation of low temperature (25 – 150 °C) brines. This is consistent with the simple mineralogy of these assemblages — Fe-Mg-Ca carbonates, anhydrite, gypsum, halite, clays — and the chemical fractionation of Ca-to Mg-rich carbonate in ALH84001 "rosettes". Longer-lived, and higher temperature, hydrothermal systems would have caused more silicate alteration than is seen and probably more complex mineral assemblages. Experimental and phase equilibria data on carbonate compositions similar to those present in the SNCs imply low temperatures of formation with cooling taking place over a short period of time (e.g. days). The ALH84001 carbonate also probably shows the effects of partial vapourisation and dehydration related to an impact event post-dating the initial precipitation. This shock event may have led to the formation of sulphide and some magnetite in the Fe-rich outer parts of the rosettes.Radiometric dating (K-Ar, Rb-Sr) of the secondary mineral assemblages in one of the nakhlites (Lafayette) suggests that they formed between 0 and 670 Myr, and certainly long after the crystallisation of the host igneous rocks. Crystallisation of ALH84001 carbonate took place 0.5 Gyr after the parent rock. These age ranges and the other research on these assemblages suggest that environmental conditions conducive to near-surface liquid water have been present on Mars periodically over the last 1 Gyr. This fluid activity cannot have been continuous over geological time because in that case much more silicate alteration would have taken place in the meteorite parent rocks and the soluble salts would probably not have been preserved.The secondary minerals could have been precipitated from brines with seawater-like composition, high bicarbonate contents and a weakly acidic nature. The co-existence of siderite (Fe-carbonate) and clays in the nakhlites suggests that the pCO₂ level in equilibrium with the parent brine may have been 50 mbar or more. The brines could have originated as flood waters which percolated through the top few hundred meters of the crust, releasing cations from the surrounding parent rocks. The high sulphur and chlorine concentrations of the martian soil have most likely resulted from aeolian redistribution of such aqueously-deposited salts and from reaction of the martian surface with volcanic acid volatiles.The volume of carbonates in meteorites provides a minimum crustal abundance and is equivalent to 50–250 mbar of CO₂ being trapped in the uppermost 200–1000 m of the martian crust. Large fractionations in ¹⁸O between igneous silicate in the meteorites and the secondary minerals (30) require formation of the latter below temperatures at which silicate-carbonate equilibration could have taken place (400°C) and have been taken to suggest low temperatures (e.g. 150°C) of precipitation from a hydrous fluid.     

Earthshine Observation of Vegetation and Implication for Life Detection on Other Planets

The detection of exolife is one of the goals of very ambitious future space missions that aim to take direct images of Earth-like planets. While associations of simple molecules present in the planet’s atmosphere (O₂, O₃, CO₂, etc.) have been identified as possible global biomarkers, this paper reviews the detectability of a signature of life from the planet’s surface, i.e. the green vegetation. The vegetation reflectance has indeed a specific spectrum, with a sharp edge around 700 nm, known as the “Vegetation Red Edge” (VRE). Moreover, vegetation covers a large surface of emerged lands, from tropical evergreen forest to shrub tundra. Thus, considering vegetation as a potential global biomarker is relevant. Earthshine allows us to observe the Earth as a distant planet, i.e. without spatial resolution. Since 2001, Earthshine observations have been used by several authors to test and quantify the detectability of the VRE in the Earth spectrum. The vegetation spectral signature is detected as a small “positive shift” of a few percentage points above the continuum, starting at 700 nm. This signature appears in most spectra, and its strength is correlated with the Earth’s phase (visible land versus visible ocean). The observations show that detecting the VRE on Earth requires a photometric relative accuracy of 1% or better. Detecting something equivalent on an Earth-like planet will therefore remain challenging, especially considering the possibility of mineral artifacts and the question of “red edge” universality in the Universe.     

Outgassing History and Escape of the Martian Atmosphere and Water Inventory

The evolution and escape of the martian atmosphere and the planet’s water inventory can be separated into an early and late evolutionary epoch. The first epoch started from the planet’s origin and lasted ～500 Myr. Because of the high EUV flux of the young Sun and Mars’ low gravity it was accompanied by hydrodynamic blow-off of hydrogen and strong thermal escape rates of dragged heavier species such as O and C atoms. After the main part of the protoatmosphere was lost, impact-related volatiles and mantle outgassing may have resulted in accumulation of a secondary CO₂ atmosphere of a few tens to a few hundred mbar around ～4–4.3 Gyr ago. The evolution of the atmospheric surface pressure and water inventory of such a secondary atmosphere during the second epoch which lasted from the end of the Noachian until today was most likely determined by a complex interplay of various nonthermal atmospheric escape processes, impacts, carbonate precipitation, and serpentinization during the Hesperian and Amazonian epochs which led to the present day surface pressure.     

Vibrational relaxation of CO2 (m,nl, p) in a CO2-N2 mixture. Part 1: Survey of available data

The knowledge of the vibrational relaxation reaction rates of diatomic and triatomic molecules is required for the modelling of numerous gaseous mixtures such as the Earth atmosphere (involving radiation transfer phenomena), exhaust plumes, afterbody wakes, Mars atmosphere, shock waves and chemical lasers. It enables a better understanding of the chemical reaction product rates and provides the populations of the radiating levels. In this study, we consider the few lowest vibrational levels of a CO₂-N₂ mixture and the V-T and V-V energy transfer processes between these levels. The reaction rates given by experimental and theoretical studies and by different surveys of data supplied by a bibliographic search are presented. Then, comparisons of the data available for the most important processes are shown. The usual assumptions concerning the vibrational relaxation of CO₂ (m, n^l, p) are recalled and briefly discussed.