Cosac, The Cometary Sampling and Composition Experiment on Philae

Comets are thought to preserve the most pristine material currently present in the solar system, as they are formed by agglomeration of dust particles in the solar nebula, far from the Sun, and their interiors have remained cold. By approaching the Sun, volatile components and dust particles are released forming the cometary coma. During the phase of Heavy Bombardment, 3.8--4 billion years ago, cometary matter was delivered to the Early Earth. Precise knowledge on the physico-chemical composition of comets is crucial to understand the formation of the Solar System, the evolution of Earth and particularly the starting conditions for the origin of life on Earth. Here, we report on the COSAC instrument, part of the ESA cometary mission Rosetta, which is designed to characterize, identify, and quantify volatile cometary compounds, including larger organic molecules, by in situ measurements of surface and subsurface cometary samples. The technical concept of a multi-column enantio-selective gas chromatograph (GC) coupled to a linear reflectron time-of-flight mass-spectrometer instrument is presented together with its realisation under the scientific guidance of the Max-Planck-Institute for Solar System Research in Katlenburg-Lindau, Germany. The instrument's technical data are given; first measurements making use of standard samples are presented. The cometary science community is looking forward to receive fascinating data from COSAC cometary in situ measurements in 2014.     

X-ray and extreme ultraviolet emissions from comets

There is significant progress in the observations, theory, and understanding of the x-ray and EUV emissions from comets since their discovery in 1996. That discovery was so puzzling because comets appear to be more efficient emitters of x-rays than the Moon by a factor of 80 000. The detected emissions are general properties of comets and have been currently detected and analyzed in thirteen comets from five orbiting observatories. The observational studies before 2000 were based on x-ray cameras and low resolution (E/δE ≈ 1.5-3) instruments and focused on the morphology of xrays, their correlations with gas and dust productions in comets and with the solar x-rays and the solar wind. Even those observations made it possible to choose uniquely charge exchange between the solar wind heavy ions and cometary neutrals as the main excitation process. The recently published spectra are of much better quality and result in the identification of the emissions of the multiply charged ions of O, C, Ne, Mg, and Si which are brought to comets by the solar wind. The observed spectra have been used to study the solar wind composition and its variations. Theoretical analyses of x-ray and EUV photon excitation in comets by charge exchange, scattering of the solar photons by attogram dust particles, energetic electron impact and bremsstrahlung, collisions between cometary and interplanetary dust, and solar x-ray scattering and fluorescence in comets have been made. These analyses confirm charge exchange as the main excitation mechanism, which is responsible for more than 90% of the observed emission, while each of the other processes is limited to a few percent or less. The theory of charge exchange and different methods of calculation for charge exchange are considered. Laboratory studies of charge exchange relevant to the conditions in comets are reviewed. Total and state-selective cross sections of charge exchange measured in the laboratory are tabulated. Simulations of synthetic spectra of charge exchange in comets are discussed. X-ray and EUV emissions from comets are related to different disciplines and fields such as cometary physics, fundamental physics, x-rays spectroscopy, and space physics.This revised version was published online in July 2005 with a corrected cover date.     

Cometary dynamics

The modern theory of cometary dynamics is based on Oort's hypothesis that the solar system is surrounded by a spherically symmetric cloud of 10¹¹ to 10¹² comets extending out to interstellar distances. Dynamical modeling and analysis of cometary motion have confirmed the ability of the Oort hypothesis to explain the observed distribution of energies for the long-period comet orbits. The motion of comets in the Oort cloud is controlled by perturbations from random passing stars, interstellar clouds, and the galactic gravitational field. Additionally, comets which enter the planetary region are perturbed by the major planets and by nongravitational forces resulting from jetting of volatiles on the surfaces of the cometary nuclei. The current Oort cloud is estimated to have a radius of 6 to 8 × 10⁴ AU, and to contain some 2 × 10¹² comets with a total mass of 7 to 8 Earth masses. Evidence has begun to accumulate for the existence of a massive inner Oort cloud extending from just beyond the orbit of Neptune to 10⁴ AU or more, with a population up to 100 times that of the outer Oort cloud. This inner cloud may serve as a reservoir to replenish the outer cloud as comets are stripped away by the various perturbers, and may also provide a more efficient source for the short-period comets. Recent suggestions of an unseen solar companion star or a tenth planet orbiting in the inner cloud and causing periodic comet showers on the Earth are likely unfounded. The formation site of the comets in the Oort cloud was likely the extended nebula accretion disc reaching from about 15 to 500 AU from the forming protosun. Comets which escape from the Oort cloud contribute to the flux of interstellar comets, though capture of interstellar comets by the solar system is extremely unlikely. The existence of Oort clouds around other main sequence stars has been suggested by the detection by the IRAS spacecraft of cool dust shells around about 10% of nearby stars.     

X-Ray and extreme ultraviolet emissions from comets

There is significant progress in the observations, theory, and understanding of the x-ray and EUV emissions from comets since their discovery in 1996. That discovery was so puzzling because comets appear to be more efficient emitters of x-rays than the Moon by a factor of 80000. The detected emissions are general properties of comets and have been currently detected and analyzed in thirteen comets from five orbiting observatories. The observational studies before 2000 were based on x-ray cameras and low resolution (E/E1.5–3) instruments and focused on the morphology of x-rays, their correlations with gas and dust productions in comets and with the solar x-rays and the solar wind. Even those observations made it possible to choose uniquely charge exchange between the solar wind heavy ions and cometary neutrals as the main excitation process. The recently published spectra are of much better quality and result in the identification of the emissions of the multiply charged ions of O, C, Ne, Mg, and Si which are brought to comets by the solar wind. The observed spectra have been used to study the solar wind composition and its variations. Theoretical analyses of x-ray and EUV photon excitation in comets by charge exchange, scattering of the solar photons by attogram dust particles, energetic electron impact and bremsstrahlung, collisions between cometary and interplanetary dust, and solar x-ray scattering and fluorescence in comets have been made. These analyses confirm charge exchange as the main excitation mechanism, which is responsible for more than 90% of the observed emission, while each of the other processes is limited to a few percent or less. The theory of charge exchange and different methods of calculation for charge exchange are considered. Laboratory studies of charge exchange relevant to the conditions in comets are reviewed. Total and state-selective cross sections of charge exchange measured in the laboratory are tabulated. Simulations of synthetic spectra of charge exchange in comets are discussed. X-ray and EUV emissions from comets are related to different disciplines and fields such as cometary physics, fundamental physics, x-rays spectroscopy, and space physics.     

Perspectives on the Comet-Asteroid-Meteorite Link

We discuss the possibility that CI and CM carbonaceous chondrites are fragments of extinct cometary nuclei. Theoretical and observational work suggests that comets evolve into asteroids, and several extinct cometary nuclei are now suspected to be among the near Earth object population. This population is the most likely source of meteorites and consequently, we may expect that some meteorites are from extinct comets in this population. The mineralogy and chemistry of CI and CM chondrites is consistent with the view that they originate from asteroidal objects of carbonaceous spectral classes, and these objects in turn may have a cometary origin. We do not suggest that CI or CM chondrites are directly delivered by active comets during perihelion passage or that these chondrites come from cometary debris in meteor streams. Instead, we summarize arguments suggesting that CI and CM chondrites represent fragments of cometary nuclei which evolved into near Earth asteroids after losing their volatiles. This revised version was published online in June 2006 with corrections to the Cover Date.     

Studies of Comets in the Ultraviolet: The Past and the Future

The remote sensing of comets in the ultraviolet bandpass has been a valuable tool for studying the structure, composition, variability, and physical processes at work in cometary comae. By extension, these studies of comae have revealed key insights into the composition of cometary nuclei. Here we briefly review the ultraviolet studies of comets, and then take a look toward the future of such work as anticipated by the advent of several key new instruments. This revised version was published online in June 2006 with corrections to the Cover Date.     

MIDAS – The Micro-Imaging Dust Analysis System for the Rosetta Mission

The International Rosetta Mission is set for a rendezvous with Comet 67 P/Churyumov-Gerasimenko in 2014. On its 10 year journey to the comet, the spacecraft will also perform a fly-by of the two asteroids Stein and Lutetia in 2008 and 2010, respectively. The mission goal is to study the origin of comets, the relationship between cometary and interstellar material and its implications with regard to the origin of the Solar System. Measurements will be performed that shed light into the development of cometary activity and the processes in the surface layer of the nucleus and the inner coma. The Micro-Imaging Dust Analysis System (MIDAS) instrument is an essential element of Rosetta’s scientific payload. It will provide 3D images and statistical parameters of pristine cometary particles in the nm-μm range from Comet 67P/Churyumov-Gerasimenko. According to cometary dust models and experience gained from the Giotto and Vega missions to 1P/Halley, there appears to be an abundance of particles in this size range, which also covers the building blocks of pristine interplanetary dust particles. The dust collector of MIDAS will point at the comet and collect particles drifting outwards from the nucleus surface. MIDAS is based on an Atomic Force Microscope (AFM), a type of scanning microprobe able to image small structures in 3D. AFM images provide morphological and statistical information on the dust population, including texture, shape, size and flux. Although the AFM uses proven laboratory technology, MIDAS is its first such application in space. This paper describes the scientific objectives and background, the technical implementation and the capabilities of MIDAS as they stand after the commissioning of the flight instrument, and the implications for cometary measurements.     

On the Organic Refractory Component of Cometary Dust

Cometary nuclei consist of ices intermixed with dust grains and are thought to be the least modified solar system bodies remaining from the time of planetary formation. Flyby missions to Comet P/Halley in 1986 showed that cometary dust is extremely rich in organics (∼50% by mass). However, this proportion appears to be variable among different comets. In comparison with the CI-chondritic abundances, the volatile elements H, C, and N are enriched in cometary dust indicating that cometary solid material is more primitive than CI-chondrites. Relative to dust in dense molecular clouds, bulk cometary dust preserves the abundances of C and N, but exhibits depletions in O and H. In most cases, the carbonaceous component of cometary particles can be characterized as a multi-component mixture of carbon phases and organic compounds. Cluster analysis identified a few basic types of compounds, such as elemental carbon, hydrocarbons, polymers of carbon suboxide and of cyanopolyynes. In smaller amounts, polymers of formaldehyde, of hydrogen cyanide and various unsaturated nitriles also are present. These compositionally simple types, probably, are essential "building blocks", which in various combinations give rise to the variety of involatile cometary organics. This revised version was published online in June 2006 with corrections to the Cover Date.     

Cometary Deuterium

Deuterium fractionations in cometary ices provide important clues to the origin and evolution of comets. Mass spectrometers aboard spaceprobe Giotto revealed the first accurate D/H ratios in the water of Comet 1P/Halley. Ground-based observations of HDO in Comets C/1996 B2 (Hyakutake) and C/1995 O1 (Hale-Bopp), the detection of DCN in Comet Hale-Bopp, and upper limits for several other D-bearing molecules complement our limited sample of D/H measurements. On the basis of this data set all Oort cloud comets seem to exhibit a similar ratio in H₂O, enriched by about a factor of two relative to terrestrial water and approximately one order of magnitude relative to the protosolar value. Oort cloud comets, and by inference also classical short-period comets derived from the Kuiper Belt cannot be the only source for the Earth's oceans. The cometary O/C ratio and dynamical reasons make it difficult to defend an early influx of icy planetesimals from the Jupiter zone to the early Earth. D/H measurements of OH groups in phyllosilicate rich meteorites suggest a mixture of cometary water and water adsorbed from the nebula by the rocky grains that formed the bulk of the Earth may be responsible for the terrestrial D/H. The D/H ratio in cometary HCN is 7 times higher than the value in cometary H₂O. Species-dependent D-fractionations occur at low temperatures and low gas densities via ion-molecule or grain-surface reactions and cannot be explained by a pure solar nebula chemistry. It is plausible that cometary volatiles preserved the interstellar D fractionation. The observed D abundances set a lower limit to the formation temperature of (30 ± 10) K. Similar numbers can be derived from the ortho-to-para ratio in cometary water, from the absence of neon in cometary ices and the presence of S₂. Noble gases on Earth and Mars, and the relative abundance of cometary hydrocarbons place the comet formation temperature near 50 K. So far all cometary D/H measurements refer to bulk compositions, and it is conceivable that significant departures from the mean value could occur at the grain-size level. Strong isotope effects as a result of coma chemistry can be excluded for molecules H₂O and HCN. A comparison of the cometary ratio with values found in the atmospheres of the outer planets is consistent with the long-held idea that the gas planets formed around icy cores with a high cometary D/H ratio and subsequently accumulated significant amounts of H₂ from the solar nebula with a low protosolar D/H. This revised version was published online in June 2006 with corrections to the Cover Date.     

Dust Environment Modelling of Comet 67P/Churyumov-Gerasimenko

Dust is an important constituent of cometary emission; its analysis is one of the major objectives of ESA’s Rosetta mission to comet 67P/Churyumov-Gerasimenko (C–G). Several instruments aboard Rosetta are dedicated to studying various aspects of dust in the cometary coma, all of which require a certain level of exposure to dust to achieve their goals. At the same time, impacts of dust particles can constitute a hazard to the spacecraft. To conciliate the demands of dust collection instruments and spacecraft safety, it is desirable to assess the dust environment in the coma even before the arrival of Rosetta. We describe the present status of modelling the dust coma of 67P/C–G and predict the speed and flux of dust in the coma, the dust fluence on a spacecraft along sample trajectories, and the radiation environment in the coma. The model will need to be refined when more details of the coma are revealed by observations. An overview of astronomical observations of 67P/C–G is given, because model parameters are derived from this data if possible. For quantities not yet measured for 67P/C–G, we use values obtained for other comets, e.g. concerning the optical and compositional properties of the dust grains. One of the most important and most controversial parameters is the dust mass distribution. We summarise the mass distribution functions derived from the in-situ measurements at comet 1P/Halley in 1986. For 67P/C–G, constraining the mass distribution is currently only possible by the analysis of astronomical images. We find that both the dust mass distribution and the time dependence of the dust production rate of 67P/C–G are those of a fairly typical comet.     

The Silicate Material in Comets

Silicates in comets appear to be a mix of high-temperature crystalline enstatite and forsterite plus glassy or amorphous grains that formed at lower temperatures. The mineral identifications from the 10 and 20 μm cometary spectra are consistent with the composition of anhydrous chondritic aggregate IDPs. The origin of the cometary silicates remains puzzling. While the evidence from the IDPs points to a pre-solar origin of both crystalline and glassy components, the signatures of crystalline silicates appear in the spectra of young stellar objects only at a late evolutionary stage, when comets are the likely source of the dust. This revised version was published online in June 2006 with corrections to the Cover Date.     

Origins of Cometary Materials

In this introductory presentation, material is categorized according to our state of knowledge: What do we know, what do we think we know but don’t know certainly, and what do we not know but often describe it as if it were a well-established fact about comets, their nuclei, their composition, and processes within comets and their nuclei. The material is presented not with the intend to criticize laboratory work simulating condition in comet nuclei, or observers analyzing their observations, nor modelers using data from both these sources to improve our understanding and make predictions. The intent is to provoke discussion and dialog between these groups to avoid overstating the results. What is a Comet? A comet is a diffuse appearing celestial phenomenon moving in an orbit about the Sun. The central body, the nucleus, is composed of ice and dust. It is the source of all cometary activity, including comae and tails. We distinguish between molecular (including atoms and ions) and dust comae. At heliocentric distances of about 1 AU and less, the hydrogen coma typically has dimensions larger than the Sun. The tails are composed of dust, neutral atoms and molecules, and plasma.     

Structural evolution of cometary surfaces

Comets with a high content of organics and light molecules are expected under cosmic radiation to gain a relatively unreactive crust and less volatile material to some ten metres deep. Interstellar dust impacts act to loosen and turn over 1 cm of the surface. We discuss how far this accords with observations of cometary dust halos and new versus old comets. Two key material properties have emerged from recent studies. Firstly, the source of cometary volatiles is not ice in the sense of material with a single sublimation energy. Secondly, the particulates are not simply mineral dust but include much organic material, some of which undergoes chemical processing and exchanges with the gaseous environment. Consistent with these properties, a coherent crust rather than a mantle of loose grains would build up to cover much of the nucleus of periodic comets. It would consolidate by cooking in the solar radiation, especially at peak temperatures around perihelion. There are two disjoint surface phases: one of volatile material, the other the refractory crust, the former deepening into crater-like hollows over successive apparitions. The transition to non-volatile crust is unstable, subject to competing consolidation and disruption processes, and sensitive to seasonal changes. A comet dims and becomes asteroidal as the inert crust extends over the erosion craters, and may only be rejuvenated via collision with a boulder-sized impactor or perturbation of the orbit to smaller perihelion distance.     

Dust Near The Sun

We review the current knowledge and understanding of dust in the inner solar system. The major sources of the dust population in the inner solar system are comets and asteroids, but the relative contributions of these sources are not quantified. The production processes inward from 1 AU are: Poynting-Robertson deceleration of particles outside of 1 AU, fragmentation into dust due to particle-particle collisions, and direct dust production from comets. The loss processes are: dust collisional fragmentation, sublimation, radiation pressure acceleration, sputtering, and rotational bursting. These loss processes as well as dust surface processes release dust compounds in the ambient interplanetary medium. Between 1 and 0.1 AU the dust number densities and fluxes can be described by inward extrapolation of 1 AU measurements, assuming radial dependences that describe particles in close to circular orbits. Observations have confirmed the general accuracy of these assumptions for regions within 30° latitude of the ecliptic plane. The dust densities are considerably lower above the solar poles but Lorentz forces can lift particles of sizes < 5 μm to high latitudes and produce a random distribution of small grains that varies with the solar magnetic field. Also long-period comets are a source of out-of-ecliptic particles. Under present conditions no prominent dust ring exists near the Sun. We discuss the recent observations of sungrazing comets. Future in-situ experiments should measure the complex dynamics of small dust particles, identify the contribution of cometary dust to the inner-solar-system dust cloud, and determine dust interactions in the ambient interplanetary medium. The combination of in-situ dust measurements with particle and field measurements is recommended.     

Reservoirs for Comets: Compositional Differences Based on Infrared Observations

Tracing measured compositions of comets to their origins continues to be of keen interest to cometary scientists and to dynamical modelers of Solar System formation and evolution. This requires building a taxonomy of comets from both present-day dynamical reservoirs: the Kuiper Belt (hereafter KB), sampled through observation of ecliptic comets (primarily Jupiter Family comets, or JFCs), and the Oort cloud (OC), represented observationally by the long-period comets and by Halley Family comets (HFCs). Because of their short orbital periods, JFCs are subjected to more frequent exposure to solar radiation compared with OC comets. The recent apparitions of the JFCs 9P/Tempel 1 and 73P/Schwassmann-Wachmann 3 permitted detailed observations of material issuing from below their surfaces—these comets added significantly to the compositional database on this dynamical class, which is under-represented in studies of cometary parent volatiles. This chapter reviews the latest techniques developed for analysis of high-resolution spectral observations from ～2–5 μm, and compares measured abundances of native ices among comets. While no clear compositional delineation can be drawn along dynamical lines, interesting comparisons can be made. The sub-surface composition of comet 9P, as revealed by the Deep Impact ejecta, was similar to the majority of OC comets studied. Meanwhile, 73P was depleted in all native ices except HCN, similar to the disintegrated OC comet C/1999 S4 (LINEAR). These results suggest that 73P may have formed in the inner giant planets’ region while 9P formed farther out or, alternatively, that both JFCs formed farther from the Sun but with 73P forming later in time.     

Polarization of Light Scattered by Cometary Dust Particles: Observations and Tentative Interpretations

Analysis of the polarization of light scattered by cometary particles reveals similarities amongst the phase curves, together with some clear differences: i) comets with a strong silicate emission feature present a high maximum in polarization, ii) the polarization is always slightly lower than the average in inner comae and stronger in jet-like structures. These results are in excellent agreement with the Greenberg model of dust particles built up of fluffy aggregates of much smaller grains. Also, they suggest the existence of different regions of formation, and of different stages of evolution for the scattering particles inside a given cometary coma. This revised version was published online in June 2006 with corrections to the Cover Date.     

The Rosetta Alpha Particle X-Ray Spectrometer (APXS)

The Alpha Particle X-Ray Spectrometer (APXS) is a small instrument to determine the elemental composition of a given sample. For the ESA Rosetta mission, the periodical comet 67P/Churyumov-Gerasimenko was selected as the target comet, where the lander PHILAE (after landing) will carry out in-situ observations. One of the instruments onboard is the APXS to make measurements on the landing site. The APXS science goal is to provide basic compositional data of the comet surface. As comets consist of a mixture of ice and dust, the dust component can be characterized and compared with known meteoritic compositions. Various element ratios can be used to evaluate whether chemical fractionations occurred in cometary material by comparing them with known chondritic material. To enable observations of the local environment, APXS measurements of several spots on the surface and one spot as function of temperature can be made. Repetitive measurements as function of heliocentric distance can elucidate thermal processes at work. By measuring samples that were obtained by drilling subsurface material can be analyzed. The accumulated APXS data can be used to shed light on state, evolution, and origin of 67P/Churyumov- Gerasimenko.     

Solar wind interaction with comets

The planned missions to Comet Halley, which will arrive at the nearest space of the Sun in 1986, have recently revived interest in studying solar wind interaction with comets. Several unsolved problems exist and the most urgent of them are as follows:

1. The character of the solar wind interaction with comets: bow shocks and contact surface formation near comets; similarities and differences of solar- wind interaction with comets and with Venus. The differences are probably associated with a great extension of neutral atmospheres of comets (due to a practical lack of cometary gravitation) and the ‘loading’ of the solar wind flux by cometary ions during the interaction.
2. The anomalous ionization in cometary heads.
3. The problem of the anamalously high accelerations of ions in the plasma tails of comets.
4. The variability of plasma structures observed in cometary tails.

     

Reservoir for Comet Material: Circumstellar Grains

Primitive meteorites and interplanetary dust particles contain small quantities of dust grains with highly anomalous isotopic compositions. These grains formed in the winds of evolved stars and in the ejecta of stellar explosions, i.e., they represent a sample of circumstellar grains that can be analyzed with high precision in the laboratory. Such studies have provided a wealth of information on stellar evolution and nucleosynthesis, Galactic chemical evolution, grain growth in stellar environments, interstellar chemistry, and the inventory of stars that contributed dust to the Solar System. Among the identified circumstellar grains in primitive solar system matter are diamond, graphite, silicon carbide, silicon nitride, oxides, and silicates. Circumstellar grains have also been found in cometary matter. To date the available information on circumstellar grains in comets is limited, but extended studies of matter returned by the Stardust mission may help to overcome the existing gaps.     

Morphology–Composition–Isotopes: Recent Results from Observations

This article presents some recent imaging and spectroscopic observations that led to results which are significant for understanding the properties of comet nuclei. The coma morphology and/or composition were investigated for 12 comets belonging to different dynamical classes. The data analysis showed that the coma morphology of three non-periodic comets is not consistent with the general assumption that dynamically new comets still have a relatively uniform nucleus surface and therefore do not exhibit gas and/or dust jets in their coma. The determination of carbon and nitrogen isotopic ratios revealed the same values for all comets investigated at various heliocentric distances. However, the relative abundance of the rare nitrogen isotope ¹⁵N is about twice as high as in the Earth’s atmosphere. Observations of comets at splitting events and during outbursts led to indications for differences between material from the nucleus surface and the interior. The monitoring of the induced outburst of 9P/Temple revealed that under non-steady state conditions the fast disintegration of species is detectable.