F-Region ion composition modeling

Measurements of the principal ion species of the F₁- and F₂- regions have been used to develop an empirical model of the ion composition for altitudes between 150 and 500 km. The species measured by the S3-1 satellite include N⁺, O⁺, N₂⁺, NO⁺ and O₂⁺. The data were obtained near the minimum of the solar cycle, thus limited information on the ionospheric variation with solar flux is available. However, the range of latitude, altitude, local time and geomagnetic activity does provide a useful basis for modeling the F-region. The ion composition measurements have been used to provide a model for relative ion composition which is compatible with the total ion density from the International Reference Ionosphere model.     

Positive ion composition and electron density in a combined auroral and NLC event

The positive ion composition and electron density were measured in the lower ionosphere above Kiruna in salvo A of CAMP (Cold Arctic Mesopause Project). The CAMP/P (S37/P) payload carrying a magnetic ion spectrometer, positive ion and electron probes, and propagation experiments was launched on 3 August 1982 2332 UT during extended Noctilucent Clouds (NLC) and auroral activities over Kiruna. The measured electron density was 5×10³cm^?3 at 80 km and 2.5×10⁵cm^?3 at 90 km. The increase of ion and electron densities in the D- and E-region during twilight was caused by precipitating auroral particles. The height distribution of the positive ions measured by the mass spectrometer in the mass range 19–280 amu is different from a winter flight with similar auroral conditions. Below 85.5 km proton hydrates H⁺(H₂O)₃ ? H⁺(H₂O)₈ were the dominant ions. The heaviest proton hydrates H⁺(H₂O)₇ and H⁺(H₂O)₈ were most abundant at 82–85.5 km, the altitude of visible NLC. Above 85.5 km O₂⁺ and NO⁺ became dominant. A small metal ion layer was observed between 90.5–93 km with a maximum ion density of 10% of the total positive ion density at 91 km altitude. The metal ion density disappeared within about a km below 90.5 km.     

磁层亚暴膨胀相的近地触发模型

本文指出现有亚暴的中性线模型其源区在赤疲乏面上离地球太远；以ＧＥＯＳ－２的观测资料为依据，提出了亚暴膨胀相的一个近地触发模型－气球模不稳定性模型，该模型认为，在增长相期间到达Ｒ≈（６－１０）ＲＥ的近地等离子体片内边缘区，出现指向地球方向的离子压强梯度，越尾电流强度增大，磁力线向磁尾拉伸。当等离子体片变薄，电子沉降增强，极光带电离层电导率骤增时，气球模不稳定性在近地等离子体片内边缘区被激发，场向电流     

Positive ion distributions in the morning auroral zone: Local acceleration and drift effects

We report on the typical structure of the large scale ion precipitation in the morning sector of the auroral zone and associated low frequency electromagnetic waves. Data obtained during near radial passes of the AUREOL-3 satellite point to a distinction between two main precipitation regions: 1) In the poleward part of the auroral zone the latitudinal variation of the average energy (or temperature) of the precipitated ions (mainly H⁺) indicate that they are adiabatically accelerated in the outer magnetosphere. This “high energy” (? 3 to > 20 keV) precipitation is usually associated with a low energy (E < 110 eV) upward flowing 0⁺ and H⁺ component, and 2) near the boundary between discrete and diffuse electron aurorae a drastic change in the ion characteristics is observed. The flux of energetic precipitated H⁺ ions is sharply reduced, which suggests the formation of an Alfvén layer. However, intense fluxes of precipitated H⁺, O⁺, and He⁺ ions with energies < 3 keV are observed equatorward of the Alfvén layer, in coincidence with the diffuse aurora and in association with quasi-monochromatic electromagnetic waves with frequencies around the proton gyrofrequency. As the characteristic convection and bounce times of the low energy upward flowing ion component are comparable (τ > 3 hours) we suggest that the precipitation of ionospheric ions inside the diffuse aurora results from convection and corotation of the ions accelerated to suprathermal energies at higher latitudes.     

Mesospheric H2O and H2O2 densities inferred from in situ positive ion composition measurement

The measurements of positive ion composition in the high latitude D-region have revealed an excess of 34⁺ under distrubed conditions which has been interpreted as H₂O₂⁺. At the same altitude range near the transition height oxonium ions were measured as well. This paper presents a new model for the production and loss of oxonium ions with their production from H₂O₂⁺ + H₂O → H₃O⁺ + HO₂ and their loss by attachment of N₂ and/or CO₂. A reaction constant of 8.5×10^?28 (300/T)⁴ cm⁶s^?1 has been obtained for the three body attachment H₃O⁺ + CO₂ + M → H₃O⁺.CO₂ + M from the measured density profile of 63⁺ in flight 18.1020. Mesospheric H₂O and H₂O₂ densities are inferred from measurements of four high latitude ion compositions based on the oxonium model. The mixing ratios of hydrogen peroxide are up to two orders of magnitude higher compared to previous model calculations. In order to explain the missing production of odd hydrogen, we consider larger O(¹D) densities, surface reactions of O(³P) on particles, and cathalytic photodissociation of water vapor on aerosol particles.     

A model study of the negative chlorine ion chemistry in the Earth’s mesosphere

An ion chemistry model is used to investigate the negative chlorine ion chemistry of the mesosphere for quiet ionospheric conditions. Model results are presented for high latitudes in February as well as for the equator in Summer. For nighttime, Cl^-${\text{Cl}}^{-}$, Cl^-${\text{Cl}}^{-}$(HCl), and NO₃⁻(HCl) are the most abundant chlorine anions in the mesosphere. The concentration of ClO₃⁻ depends significantly on its stability against collision-induced dissociation. In contrast to previous model predictions, the abundance of Cl^-(_H2O)${\text{Cl}}^{-}({\mathrm{H}}_2\mathrm{O})$ is small. For daytime, photoelectron detachment and photodissociation have pronounced impact on the negative chlorine ion chemistry in the mesosphere. The abundance of all anion cluster is considerably smaller than at night. While Cl^-${\text{Cl}}^{-}$ decreases in the upper mesosphere, its abundance increases at lower altitudes.     

Hybrid simulations of the O ion escape from Venus: Influence of the solar wind density and the IMF x component

As an initial effort to study the evolution of the Venus atmosphere, the influence of the solar wind density and the interplanetary magnetic field (IMF) x component (the x-axis points from Venus towards the Sun) on the O⁺ ion escape rate from Venus is investigated using a three-dimensional quasi-neutral hybrid (HYB-Venus) model. The HYB-Venus model is first applied to a case of the high-density (100 cm⁻³) solar wind interaction with Venus selected from the Pioneer Venus Orbiter observations to demonstrate its capability for the study. Two sets of simulations with a wide range of solar wind densities and different IMF x components are then performed. It is found that the O⁺ ion escape rate increases with increasing solar wind density. The O⁺ ion escape rate saturates when the solar wind density becomes high (above 100 cm⁻³). The results also suggest that the IMF x component enhances the O⁺ ion escape rate, given a fixed IMF component perpendicular to the x-axis. Finally, the results imply a higher ion loss rate for early-Venus, when solar conditions were dramatically different.     

Solar cycle effect on temporal and spatial variation of topside ion density measured by SROSS C2 and ROCSAT 1 over the Indian longitude sector

We investigated the diurnal, seasonal and latitudinal variations of ion density Ni over the Indian low and equatorial topside ionosphere within 17.5°S to 17.5°N magnetic latitudes by combining the data from SROSS C2 and ROCSAT 1 for the 9 year period from 1995 to 2003 during solar cycle 23. The diurnal maximum density is found in the local noon or in the afternoon hours and the minimum occurs in the pre sunrise hours. The density is higher during the equinoxes as compared to that in the June and December solstice. The local time spread of the daytime maximum ion density increases with increase in solar activity. A north south asymmetry with higher ion density over northern hemisphere in the June solstice and over southern hemisphere in December solstice has been observed in moderate and high solar activity years. The crest to crest distance increases with increase in solar flux. Ion density bears a nonlinear relationship with F_10.7 cm solar flux and EUV flux in general. The density increases linearly with solar flux up to ∼150 sfu (1 sfu = 10⁻²²Wm⁻²Hz⁻¹) and EUV flux up to ∼50 units (10⁹ photons cm⁻² s⁻¹). But beyond this the density saturates. Inverse saturation and linear relationship have been observed in some season or latitude also. Inter-comparison of the three solar activity indices F_10.7 cm flux, EUV flux and F_10.7P (= (F_10.7 + F_10.7A)/2, where F_10.7A is the 81 day running average value of F_10.7) shows that the ion density correlates better with F_10.7P and F_10.7 cm fluxes. The annual average daytime total ion density from 1995 to 2003 follows a hysteresis loop as the solar cycle reverses. The ion density at 500 km over the Indian longitude sector as obtained by the international reference ionosphere is in general lower than the measured densities during moderate and high solar activity years. In low solar activity years the model densities are equal or higher than measured densities. The IRI EIA peaks are symmetric (±10°) in equinox while densities are higher at 10°N in June solstice and at 10°S in the December solstice. The model density follows F_10.7 linearly up to about F_10.7 > ∼150 sfu and then saturates.     

Temporal and spatial variations observed in the ionospheric composition of Venus: Implications for empirical modelling

In situ measurements of the thermal ion composition of the ionosphere of Venus have been obtained for a period of two Venus years from the Bennett rf ion mass spectrometer on the Pioneer Venus Orbiter. Ion measurements within an altitude interval of 160 to 300 kilometers, corresponding to an overall latitude interval of about ?4° to 34°N, are assembled from the interval December 1978 to March 1980. This time interval corresponds to two revolutions of Venus about the Sun, designated as two “diurnal cycles”. The distributions of several ion species in this data base have been sorted to identify temporal and spatial variations, and to determine the feasibility of an analytical representation of the experimental results. The first results from the sorting of several prominent ions including O⁺, O₂⁺, and H⁺ and several minor ions including CO₂⁺, C⁺, and H₂⁺ reveal significant diurnal variations, with superimposed modulation associated with solar activity and solar wind variations. The diurnal variation consists of strong day to night contrast in the ion concentrations, with differences of one to two orders of magnitude, depending upon ion mass and altitude. The concentrations of O₂⁺, O⁺, CO₂⁺ and C⁺ peak throughout the dayside decreasing sharply at the terminators to nightside levels, lower by one to two orders of magnitude relative to the dayside. The diurnal variations of the light ions H⁺ and H₂⁺ peak during the night, exhibiting asymmetric nightside bulges favoring the pre-dawn sector, near 0400 solar hour angle. Superimposed upon the diurnal distributions are modulation signatures which correlate well with modulation in the F_10.7 index, indicating a strong influence of solar variability on the ion production and distribution. The influence of solar wind perturbations upon the ion distributions are also indicated, by a significant increase in the scatter of the observations with increasing altitude as higher altitudes, approaching 300 kilometers, are sampled. Together, these temporal and spatial variations make the task of modelling the ionosphere of Venus both very interesting and challenging.     

The glow of the night ionosphere due to energetic ion beams

This paper discusses photometric measurements made of the ionospheric excitation of the line $\text{λ = 5577}\text{A}\text{?}$ at the time of electron beam injection from a rocket into the Earth's ionosphere. The gradual increase of the glow intensity per impulse occurs due to accumulation of the energy of excited states of N₂(A³Σ⁺_u) and O(′S) during their lifetimes. The large disturbed zone in the near-rocket environment (size >500 m) is connected via the interaction of ions accelerated in the rocket potential field with ionospheric components. The glow intensity modulation is observed at a height of ～98 km during the electron beam injection simultaneously with the ignition of the beam-plasma discharge (BPD). The intensity minima are explained by a decrease of the energy of accelerated ions due to effective neutralization of the rocket body by the BPD plasma. The height profile of the glow intensity revealed two maxima at heights of ～103 km and ～115 km. The second maximum (at ～115 km) indicates that, at these heights, both collision and collision-free mechanisms of accelerated ion energy transport to ionospheric components exist.     

由磁层整体电场模型得到的场向电流分布

本文概述了用GEOS-2号卫星等实测资料所修正的Volland大尺度对流电场模型, 并用该模型来计算场向电流.文中给出了由势函数计算场向电流的表达式, 并对弱磁活动下的电流分布进行了计算.结果与Iijima和Potemra的观测较吻合.这说明修正后的Volland电场模型是合理的, 从而进一步肯定了由GEOS-2号的观测结果所导出的若干磁层动力学特性的可靠性.      

Model calculations of the dayside ionosphere of Venus

Model calculations of the dayside ionosphere of Venus are presented. The coupled continuity and momentum equations were solved for O₂⁺, O⁺, CO₂⁺, C⁺, N⁺, He⁺, and H⁺ density distributions, which are compared with measurements from the Pioneer Venus ion mass spectrometer. The agreement between the model results and the measurements is good for some species, such as O⁺, and rather poor for others, such as N⁺, indicating that our understanding of the dayside ion composition of Venus is incomplete. The coupled heat conduction equations for ions and electrons were solved and the calculated temperatures compared with Pioneer Venus measurements. It is shown that fluctuations in the magnetic field have a significant effect on the energy balance of the ionosphere.     

钛合金的离子束改性

钛合金是航空航天工业常用的结构材料,它具有重量轻、强度高、抗腐蚀强等优良性能,但耐磨性较差.为提高其耐磨性,对TC4、TA7航材试件,采用溅射方法在其表面镀上钛膜,并用(N^＋＋N^＋₂)混合离子束进行动态反冲注入及单元素C^＋离子束注入两种方法,进行表面改性.精密摩擦、磨损试验及显微硬度测量结果,试件表面的滑动摩擦系数降低了64%~77%;磨损率减少了22%~48%;显微硬度提高0.3~1.4倍.证明离子注入有效地改善了合金表层的摩擦、磨损性能.对注入样品进行X射线光电子能谱(XPS)分析,发现注入后的钛合金表层,生成了大量的TiO₂,并析出TiN,TiC等金属化合物,这是降低摩擦系数,提高耐磨性的主要因素.添加C^＋离子注入的试件,其力学性能并无进一步改善,原因有待分析.     

Energetic particles in the night-time middle- and low-latitude ionosphere

Data are presented on the zones of energetic particle precipitation at middle and low latitudes observed during and after magnetic storm injection events. Satellite measurements of the equatorial zone ion flux (～ 10³ - 10⁴ cm^?2 s^?1 sr^?1 for E > 45 keV at 240 km) are consistent with the development of a temporary low altitude ion radiation belt at the magnetic equator. In the midlatitude ion zone the flux (～ 10³ - 10⁵ ions cm^?2 s^?1 sr^?1 for E > 45 keV at 220 km) is directly related to magnetic activity while the midlatitude electron zone flux has a delayed response (～ 4 days).     

Circulation of energetic ions of terrestrial origin in the magnetosphere

Energetic ion composition measurements have now been performed from earth orbiting satellites for more than a decade. As early as 1972 we knew that energetic (keV) ions of terrestrial origin represented a non-negligible component of the storm time ring current. We have now assembled a significant body of knowledge concerning energetic ion composition throughout much of the earth's magnetosphere. We know that terrestrial ions are a common component of the hot equatorial magnetospheric plasma in the ring current and the plasma sheet out to ? 23 R_E. During periods of enhanced geomagnetic activity this component may become dominant. There is also clear evidence that the terrestrial component (specifically O⁺) is strongly dependent on solar cycle. Terrestrial ion source, transport, and acceleration regions have been identified in the polar auroral region, over the polar caps, in the magnetospheric boundary layers, and within the magnetotail lobes and plasma sheet boundary layer. Combining our present knowledge of these various magnetospheric ion populations, it is concluded that the primary terrestrial ion circulation pattern associated with enhanced geomagnetic activity involves direct injection from the auroral ion acceleration region into the plasma sheet boundary layer and central plasma sheet. The observed terrestrial component of the magnetospheric boundary layer and magnetotail lobes are inadequate to provide the required influx. They may, however, contribute significantly to the maintenence of the plasma sheet terrestrial ion population, particularly during periods of reduced geomagnetic activity. It is further concluded, on the basis of the relative energy distributions of H⁺ and O⁺ in the plasma sheet, that O⁺ probably contributes significantly to the ring current population at energies inaccessible to present ion composition instrumentation (? 30 keV).     

IR-spectroscopy of ionosphere from stratospheric balloons

The radiation spectra of the ionosphere in the 4–5 μm region have been determined from stratospheric balloons by means of the specially elaborated method of the registration of angular and spectral distribution of the radiation. The radiation bands of 4.4 μm and 4.8 μm which have 0.1–0.2 erg cm^?2 sr^?1s^?1. brightness obtained in two flights, are identified with the vibration-rotation transitions of the ion NO⁺ (0 - 1) and the molecules N¹⁴N¹⁵ (0 - 1) and CO (0 - 1) and (3 - 2) from altitudes between 120 and 500 km.     

Modulation of dayside ion and neutral distributions at Venus: Evidence of direct and indirect solar energy inputs

In-situ measurements of ion and neutral composition and temperature across the dayside of Venus during 1979–1980 exhibit long and short-term changes attributed to solar variations. Following solar maximum, dayside concentrations of CO⁺ and the neutral gas temperature are relatively smoothly modulated with a 28-day cycle reasonably matching that of the solar F_10.7 and EUV fluxes. Measurements some 6–8 months earlier show less pronounced and more irregular modulation, and short-term day-to-day fluctuations in the ions and neutrals are relatively more conspicuous than in the later period. During the earlier period, the solar wind at Venu exhibits relatively large velocity enhancements, which appear to be consistent with differences in solar coronal behavior during the two periods. It is suggested that through the solar wind variations and associated changes in the draping of the interplanetary magnetic field about the dayside, fluctuating patterns of joule heating may occur, producing the observed short term ion and neutral variations. This indirect energy effect, if verified, presents a complication for quantitatively analyzing the modulation in neutral temperature and ion concentration produced by changes in direct EUV radiation.     

Atomic structure of the doubly ionized titanium Ti III ion

In this work, the atomic structure of Ti III is calculated using two methods, the Thomas-Fermi–Dirac-Amaldi (TFDA) method using the AUTOSTRUCTURE (AS) atomic structure code and the pseudo-relativistic Hartree–Fock (HFR) method using the Cowan (CW) atomic structure code. We used the terms and levels generated by the 19 configurations: 3p⁶ 3d², 3dns (n = 4–7), 3dnp (n = 4–7), 3dnd (n = 4–7), 3d nf (n = 4–7), 3p⁶ 4s²,3p⁶ 4s4p. Our calculated values are compared with available experimental and theoretical results and new theoretical data of our own are obtained.     

Quantitative determination of the outgassing water vapor concentrations surrounding space vehicles from ion mass spectrometer measurements

Outgassing from materials as well as deliberate gaseous and liquid releases create contaminant clouds around spacecraft that can degrade both instrumentation and measurements. This paper describes a new method for estimating outgassing water vapor concentrations around space vehicles. Water vapor ions measured in the course of a rocket experiment performed at Eglin AFB, Florida, on December 12, 1980 at 2311 UT are utilized to demonstrate the technique. The H₂O concentration near the payload's surface is calculated using the rate coefficient for the fast charge transfer process, O⁺ + H₂O + H₂O⁺ + O, the source of the observed water vapor ions. It is found that the measured H₂O⁺ ions were produced within 3–4 cm of the sampling plate's surface and that the average H₂O pressure over this distance was relatively constant on ascent at 8 × 10^?6 torr, within a factor two, implying a steady outgassing rate.