The global distribution and variability of stratospheric constituents measured by LIMS

The purpose of the Nimbus 7 LIMS experiment was to sound the composition and structure of the upper atmosphere and provide data for study of photochemistry, radiation, and dynamics processes. Vertical profiles were measured of temperature and ozone (O₃) over the 10-km to 65-km range and water vapor (H₂O), nitrogen dioxide (NO₂), and nitric acid (HNO₃) over the 10-km to ～50-km range. Latitude coverage extended from 64°S to 84°N. Several general features of the atmosphere have emerged from data analyses thus far. Nitrogen dioxide exhibits rapid latitudinal variations in winter and shows hemispheric asymmetry with generally higher vertical column amount in the summer hemisphere. HNO₃ data show that this gas is highly variable with altitude, latitude, and season. Smallest mixing ratios occur in the tropics, and the largest values occur in the high latitude winter hemisphere. The results show that O₃, NO₂, and HNO₃ are strongly affected during a stratospheric warming. There is a persistently low water vapor mixing ratio in the tropical lower stratosphere (～2–3 ppmv), a poleward gradient at all times in the mission, and evidence of increasing mixing ratio with altitude at tropical and middle latitudes.     

Thermal net flux measurements on the pioneer Venus entry probes

Corrected thermal net radiation measurements from the four Pioneer Venus entry probes at latitudes of 60°N, 31°S, 27°S, and 4°N are presented. Three main conclusions can be drawn from comparisons of the corrected fluxes with radiative transfer calculations: (1) sounder probe net fluxes are consistent with the number density of large cloud particles (mode 3) measured on the same probe, but the IR measurements as a whole are most consistent with a significantly reduced mode 3 contribution to the cloud opacity; (2) at all probe sites, the fluxes imply that the upper cloud contains a yet undetected source of IR opacity; and (3) beneath the clouds the fluxes at a given altitude increase with latitude, suggesting greater IR cooling below the clouds at high latitudes and water vapor mixing ratios of about 2–5×10^?5 near 60°, 2–5×10^?4 near 30°, and >5×10^?4 near the equator.     

Trace constituents measurements deduced from spectrometric observations on-board spacelab

The observation of infrared absorption lines by means of a grille spectrometer on board Spacelab 1 allows the determination of Co₂ and CO in the low thermosphere and in the middle atmosphere. Equal abundances of CO and CO₂ are found at 115 ± 5 km altitude. CO₂ is observed to depart from its homospheric volume mixing ratio near 100 km, dropping by a factor of 10,15 km higher. The CO largest number density is observed near 70 km altitude, close to the H Lyman alpha photoproduction peak.The analysis of one run dedicated to the observation of water vapor shows a middle atmospheric mixing ratio of this species within the limits : 3 to 8 ppmv up to 70 km altitude, with the indication of an increase from 30 to 50 km altitude. The H₂O mixing ratio drops very rapidly above 70 km.The comparison of the results from strong and weak H₂O and CO₂ lines shows the need to refine the line profile model.     

Detection of aerosol pollution sources during sandstorms in Northwestern China using remote sensed and model simulated data

The present paper has used a comprehensive approach to study atmosphere pollution sources including the study of vertical distribution characteristics, the epicenters of occurrence and transport of atmospheric aerosol in North-West China under intensive dust storm registered in all cities of the region in April 2014. To achieve this goal, the remote sensing data using Moderate Resolution Imaging Spectroradiometer satellite (MODIS) as well as model-simulated data, were used, which facilitate tracking the sources, routes, and spatial extent of dust storms. The results of the study have shown strong territory pollution with aerosol during sandstorm. According to ground-based air quality monitoring stations data, concentrations of PM₁₀ and PM_2.5 exceeded 400?μg/m³ and 150?μg/m³, respectively, the ratio PM_2.5/PM₁₀ being within the range of 0.123–0.661. According to MODIS/Terra Collection 6 Level-2 aerosol products data and the Deep Blue algorithm data, the aerosol optical depth (AOD) at 550?nm in the pollution epicenter was within 0.75–1. The vertical distribution of aerosols indicates that the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) 532?nm total attenuates backscatter coefficient ranges from 0.01 to 0.0001?km^?1?×?sr^?1 with the distribution of the main types of aerosols in the troposphere of the region within 0–12.5?km, where the most severe aerosol contamination is observed in the lower troposphere (at 3–6?km). According to satellite sounding and model-simulated data, the sources of pollution are the deserted regions of Northern and Northwestern China.     

Composition of the Venus atmosphere below 100 km altitude

Our current knowledge on the composition of the Venus atmosphere in the altitude range from the surface to 100 km is compiled. Gases that have been measured, and whose mixing ratios are assumed to be constant with altitude, are CO₂, N₂, He, Ne, Ar, and Kr. Gases that have been identified in the lower and/or middle atmosphere, but whose mixing ratios may depend on altitude, latitude and/or local time, are CO, H₂O, HCl, HF, and SO₂. Conflicting data or only upper limits exist on some important trace gases, such as O₂, H₂, and Cl₂. The latter two are key constituents in the photochemistry of the middle atmosphere of Venus. The chapter concludes with a listing of the isotopic abundances of elements measured in the Venus atmosphere.     

Atomic oxygen concentrations in the lower auroral thermosphere

Atomic oxygen concentrations derived from the nightglow components of O₂(b¹Σ_g⁺ ? X³Σ_g^?) (0-0) Atmospheric Band emission profiles obtained during two rocket-borne photometer measurements of aurora are presented. The peak atomic oxygen concentrations of 2–3 × 10¹¹ cm^?3 are in better agreement with those of the MSIS-83 model than the CIRA 1972 mean reference atmosphere, although the shapes of the two derived profiles differ considerably from that of MSIS-83. The derived concentrations do not contradict the suggestion made by some investigators that the atomic oxygen concentrations in the auroral zone are depleted relative to their mid-latitude values.     

Assessing the feasibility of involving gaseous products resulting from physicochemical oxidation of human liquid and solid wastes in the cycling of a bio-technical life support system

The study addresses the possible ways of involving gaseous products produced by “wet” incineration of human wastes mixed with H₂O₂ in an alternating electric field in the cycling of the physical model of a bio-technical life support system (BTLSS). The resulting gas mixture contains CO₂ and O₂, which are easily involved in the cycling in the closed ecosystem, and NH₃, which is unacceptable in the atmosphere of the BTLSS. NH₃ fixation has been proposed, which is followed by nitrification and involvement of the resulting products in the mass exchange of the closed system. Experiments have been performed to show that plants can be grown in the atmosphere resulting from the closing of the gas loop that includes a physicochemical installation and a growth chamber with plants representing the phototrophic compartment of the BTLSS. The results of the study suggest the conclusion that the proposed method of organic waste oxidation can be a useful tool in creating a physical model of a closed-loop integrated BTLSS.     

The chemical conditions on the parent body of the murchison meteorite: Some conclusions based on amino, hydroxy and dicarboxylic acids

Amino and hydroxy acids have been identified in the Murchison meteorite. Their presence is consistent with a synthetic pathway involving aldehydes, hydrogen cyanide and ammonia in an aqueous environment (Strecker-cyanohydrin synthesis). From the various equilibrium and rate constants involved in this synthesis, four independent estimates of the ammonium ion concentrations on the parent body at the time of compound synthesis are obtained; all values are about 2 × 10^?3 M. Succinic acid and β-alanine have also been detected in the Murchison meteorite. Their presence is consistent with a synthesis from acrylonitrile, hydrogen cyanide and ammonia. Using the equilibrium and rate constants for this synthetic pathway, and the succinic acid/β-alanine ratio measured in the Murchison meteorite, an estimate of the hydrogen cyanide concentration of 10^?3 to 10^?2 M is obtained. Since hydrogen cyanide hydrolyzes relatively rapidly in an aqueous environment ($\text{t}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{< 10}{}^4\text{yrs}$) this high concentration implies a period of synthesis of organic compounds as short as 10⁴ years on the Murchison meteorite parent body.     

Mesospheric H2O and H2O2 densities inferred from in situ positive ion composition measurement

The measurements of positive ion composition in the high latitude D-region have revealed an excess of 34⁺ under distrubed conditions which has been interpreted as H₂O₂⁺. At the same altitude range near the transition height oxonium ions were measured as well. This paper presents a new model for the production and loss of oxonium ions with their production from H₂O₂⁺ + H₂O → H₃O⁺ + HO₂ and their loss by attachment of N₂ and/or CO₂. A reaction constant of 8.5×10^?28 (300/T)⁴ cm⁶s^?1 has been obtained for the three body attachment H₃O⁺ + CO₂ + M → H₃O⁺.CO₂ + M from the measured density profile of 63⁺ in flight 18.1020. Mesospheric H₂O and H₂O₂ densities are inferred from measurements of four high latitude ion compositions based on the oxonium model. The mixing ratios of hydrogen peroxide are up to two orders of magnitude higher compared to previous model calculations. In order to explain the missing production of odd hydrogen, we consider larger O(¹D) densities, surface reactions of O(³P) on particles, and cathalytic photodissociation of water vapor on aerosol particles.     

Mass spectrometric measurements of stratospheric ions

Recent in situ measurements with balloon borne quadrupole mass spectrometers, between 20 and 45 km altitude, are reviewed and discussed.The major stratospheric positive ions observed are proton hydrates [H⁺(H₂O)_n] and non proton hydrates of the form H⁺X_m(H₂O)₂. The data analysis allows a derivation of the vertical mixing ratio profile of X (most probably CH₃CN), which is compared with recent model calculations. From negative ion composition data, showing the presence of NO₃^? and HSO₄^? cluster ions, the density of sulfuric acid in the stratosphere is deduced. The implications of these findings on our understanding of the sulfur chemistry is briefly treated.Finally some other aspects such as contamination, cluster break up and the use of stratospheric ion mass spectra for determination of thermochemical data and other minor constituents are discussed.     

Venus EUV measurements of hydrogen and helium from Venera 11 and Venera 12

Lyman α and 58.4 nm HeI radiations resonantly scattered were observed with EUV spectrophotometers flown on Venera 11 and Venera 12. The altitude distribution of hydrogen was derived by limb observations from 250 km (exobase level) to 50,000 km. In the inner exosphere (up to ? 2,000 km of altitude) the distribution can be described by a classical exospheric distribution with T_C = 275 ± 25 K and n = 4_?2⁺³ × 10⁴ atom. cm^?3 at 250 km. The integrated number density from 250 to 110 km (the level of CO₂ absorption) is 2.1 × 10¹² atom. cm^?2, a factor of 3 to 6 lower than that predicted by aeronomical models. This number density decreases from the morning side to the afternoon side, or alternately from equatorial to polar regions. Above 2,000 km a “hot” hydrogen population dominates, which can be simulated by T = 10³K and n = 10³ atom. cm^?3 at the exobase level.The optical thickness of helium above 141 km (the level of CO₂ absorption for 58.4 nm radiation) was determined to be τ_o = 3, corresponding to a density at 150 km of 1.6 × 10⁶ cm^?3. This is about 3 times less than what was obtained with the Bus Neutral Mass Spectrometer of Pioneer Venus, and about twice less than ONMS measurements, but is in agreement with earlier EUV measurement by Mariner 10 (2 ± 1 × 10⁶ cm^?3).     

The neutral particle impact de-excitation cross-section of the fine structure level3P1 of atomic oxygen in the thermosphere

A new upper limit value (9.9 × 10^?21cm²) of the mean equivalent de-excitation cross-section of O(³P₁) by collision with neutral particles in the thermosphere is obtained by comparing the³P₁ state de-excitation rate due to neutral practice impact with that due to electron impact. The existing data of the cross-section obtained from the aeronomic study are compared with the theoretical data, and it indicated that the former is much less than the latter.     

Circulation of the atmosphere from the surface to 100 km

A reference model of the atmospheric circulation on Venus based on available observations is presented. The reference atmosphere has the following main features: (i) the entire atmosphere below 85 km moves predominantly from east to west in the planet's reference system (in the same direction as the rotation of the solid planet itself) with the possible exception of the lowest 10 km where velocities are low, (ii) a jet is present near the cloud-top level at 45° latitude in both hemispheres, with a magnitude of approximately 100 ms^?1, (iii) a weak meridional (north-south component) flow directed towards either pole is superimposed on the zonal (east-west) motion at cloud-top level (about 68 km) altitudes, and, (iv) eddies or wave motions are present in the atmosphere, with amplitudes of less than 15 ms^?1 in the upper atmosphere.     

The influence of radiative cooling and turbulence on the heat budget of the thermosphere

Numerical models of the thermal budget of the Earth's upper atmosphere in the height range of 90–500km are developed. The main sources and sinks of energy including infra-red radiative cooling by vibrational-rotational bands of NO, CO₂, OH and O₃ as well as heating and cooling arising from dissipation of turbulent energy and eddy heat transport are taken into account. The calculated temperature and density height profiles are in good agreement with the respective profiles from CIRA 72 and Jacchia 1977 models. It is shown for the models considered that IR-radiative cooling by CO₂ and NO in the 15μ and 5.3μ bands, not eddy turbulence provides the major loss of heat from 90 to 180km.     

Vegetation and the atmospheric cycling of mercury

Beyond their role in the cycling of the major elements, carbon, nitrogen, oxygen, etc., little is known about geobiological interactions involving plants with the elements of lower abundance. Plants influence the distribution of volcanic mercury by uptake from the atmosphere and soil fluids, transport to the shoot and re-release as Hg° into the atmosphere. Release rates as high as 2.5 × 10^?4 g.h^?1 per kg are known but even at more typical rates, fluxes far greater than the Environmental Protection Agency calculated U.S. average annual degassing rate of 130 × 10^?6 g.m^?2 should exist. On a global basis, the presence or absence of vegetative cover may be a significant regulator of Hg° transport between land surfaces and the atmosphere.     

Multiple wavelength observations of flaring active regions

We present observations of flaring active regions with the Very Large Array (V.L.A. at 6 cm and 20 cm wavelengths) and the Westerbork Synthesis Radio Telescope (W.S.R.T. at 6 cm wavelength). These are compared with photospheric magnetograms (Meudon) and with Hα and offband Hα photographs (Big Bear and Ottawa River Solar Observatories). The 6 cm radiation of these active regions marks the legs of dipolar loops which have their footpoints in lower-lying sunspots. The intense, million degree radiation at 6 cm lies above sunspot umbrae in coronal regions where the longitudinal magnetic field strength H_? = 600 Gauss and the height above the sunspot umbrae h = 3.5±0.5 × 10⁹ cm. Circularly polarized horseshoe structures at 6 cm ring the sunspot umbrae. The high degree of circular polarization (?_c = 95%) of the horseshoes is attributed to gyroresonant emission above sunspot^? penumbrae. The 20 cm radiation of these active regions exhibits looplike coronal structures which extend across regions of opposite magnetic polarity in the underlying photosphere. The 20 cm loops are the radio wavelength counterparts of the X-ray coronal loops. We infer semilengths L = 5 × 10⁹ cm, maximum electron temperatures T_e(max) = 3 × 10⁶ K, emission measures ∫N_e²d$\text{l}$ = 10²⁸ cm^?5, and electron densities N_e = 10⁹ cm^?3 (or pressures p = 1 dyn cm^?2) for the 20 cm bremsstrahlung. A total of eight solar bursts were observed at 6 cm or 20 cm wavelength with second-of-arc angular resolution. The regions of burst energy were all resolved with angular sizes between 5″ and 30″, brightness temperatures between 2 × 10⁷ K and 2 × 10⁸ K, and degrees of circular polarization between 10% and 90%. The impulsive phase of the radio bursts are located near the magnetic neutral lines of the active regions, and between the flaring Hα kernels which mark the footpoints of magnetic loops. In one case there was preburst heating in the coronal loop in which a burst occurred. Snapshot maps at 10 s intervals reveal interesting burst evolution including rapid changes of circular polarization and an impulsive burst which was physically separated from both the preburst radio emission and the gradual decay phase of the burst.     

Measurement of minor species (H2, Cl,O3, NO) in the earth's atmosphere by the occultation technique

The stellar occultation technique is a clean and powerful means of detecting and quantifying minor gases in the earth's atmosphere. The results obtained are totally insensitive to knowledge of the absolute flux of the star, and are not influenced by instrument calibration problems. Pioneering observations of nocturnal mesospheric ozone and thermospheric molecular oxygen by the stellar occultation technique were made in 1970 and 1971 with the Wisconsin stellar photometers on board the Orbiting Astronomical Observatory-2. A limb crossing geometry was used. The high resolution Princeton ultraviolet spectrometer aboard Copernicus was used in the summers of 1975, 1976 and 1977 to measure altitude profiles of molecular hydrogen, atomic chlorine and nitric oxide in addition to ozone and molecular oxygen. A limb grazing geometry was employed. The ozone densities show wide variation from orbit to orbit and particularly betewen the OAO-2 and Copernicus observations. A H₂ density of 1×10⁸ cm^?3 at 95 km, and a NO density less than 10⁶ cm^?3 for altitudes greater than 85 km were measured.     

Positive ion composition and electron density in a combined auroral and NLC event

The positive ion composition and electron density were measured in the lower ionosphere above Kiruna in salvo A of CAMP (Cold Arctic Mesopause Project). The CAMP/P (S37/P) payload carrying a magnetic ion spectrometer, positive ion and electron probes, and propagation experiments was launched on 3 August 1982 2332 UT during extended Noctilucent Clouds (NLC) and auroral activities over Kiruna. The measured electron density was 5×10³cm^?3 at 80 km and 2.5×10⁵cm^?3 at 90 km. The increase of ion and electron densities in the D- and E-region during twilight was caused by precipitating auroral particles. The height distribution of the positive ions measured by the mass spectrometer in the mass range 19–280 amu is different from a winter flight with similar auroral conditions. Below 85.5 km proton hydrates H⁺(H₂O)₃ ? H⁺(H₂O)₈ were the dominant ions. The heaviest proton hydrates H⁺(H₂O)₇ and H⁺(H₂O)₈ were most abundant at 82–85.5 km, the altitude of visible NLC. Above 85.5 km O₂⁺ and NO⁺ became dominant. A small metal ion layer was observed between 90.5–93 km with a maximum ion density of 10% of the total positive ion density at 91 km altitude. The metal ion density disappeared within about a km below 90.5 km.     

Soft X-ray characteristics of white dwarfs observed by EXOSAT

EXOSAT has observed 19 hot white dwarfs with alleged strong soft X-ray emission. Positive detection of a large fraction of this sample was obtained, among these practically all hot DA dwarfs. High-resolution spectral data, acquired with the 500 1/mm grating spectrometer, indicates no traces of He in the atmosphere of HZ43, i.e. n(He)/n(H) ? 10^?5 at a photospheric temperature of 60000 K (log g = 8). In contrast, the hot DA1 dwarf Feige 24 shows the presence of an appreciable He-abundance (n(He)/n(H) ? 10^?3); however no simple homogeneously mixed H/He atmosphere can explain the observed spectral shape.     

Ionosphere-plasmasphere electron fluxes at middle latitudes obtained from whistlers

985 whistlers observed between 1970 and 1975 in Hungary have been processed for equatorial plasmaspheric electron density and tube electron content above 1000 km (N_T). The hourly median value of N_T exhibits a diurnal variation with an amplitude of 1×10¹³ electrons/cm²-tube. 75 per cent of the electron flux values obtained from the time variation of N_T are lower than 6×10⁸ el cm^?2s^?1, while in some cases the fluxes reach a value as high as 3×10⁹ el cm^?2s^?1. Between 17 and 04 LT the dominant flux direction is toward the ionosphere. The data also indicate that the day to day filling of the plasmasphere after magnetic disturbances continues through several days without exhibiting saturation, with higher filling rates for lower values of average K_p.