Radiolysis and Photolysis of Icy Satellite Surfaces: Experiments and Theory

The transport and exchange of material between bodies in the outer solar system is often facilitated by their exposure to ionizing radiation. With this in mind we review the effects of energetic ions, electrons and UV photons on materials present in the outer solar system. We consider radiolysis, photolysis, and sputtering of low temperature solids. Radiolysis and photolysis are the chemistry that follows the bond breaking and ionization produced by incident radiation, producing, e.g., O₂ and H₂ from irradiated H₂O ice. Sputtering is the ejection of molecules by incident radiation. Both processes are particularly effective on ices in the outer solar system. Materials reviewed include H₂O ice, sulfur-containing compounds (such as SO₂ and S₈), carbon-containing compounds (such as CH₄), nitrogen-containing compounds (such as NH₃ and N₂), and mixtures of those compounds. We also review the effects of ionizing radiation on a mixture of N₂ and CH₄ gases, as appropriate to Titan’s upper atmosphere, where radiolysis and photolysis produce complex organic compounds (tholins).     

Characteristics of Icy Surfaces

The surfaces of the Solar System’s icy satellites show an extraordinary variety of morphological features, which bear witness to exchange processes between the surface and subsurface. In this paper we review the characteristics of surface features on the moons of Jupiter, Saturn, Uranus and Neptune. Using data from spacecraft missions, we discuss the detailed morphology, size, and topography of cryovolcanic, tectonic, aeolian, fluvial, and impact features of both large moons and smaller satellites.     

Subsurface Water Oceans on Icy Satellites: Chemical Composition and Exchange Processes

The state of knowledge about the structure and composition of icy satellite interiors has been significantly extended by combining direct measurements from spacecraft, laboratory experiments, and theoretical modeling. The existence of potentially habitable liquid water reservoirs on icy satellites is dependent on the radiogenic heating of the rock component, additional contributions such as the dissipation of tidal energy, the efficiency of heat transfer to the surface, and the presence of substances that deplete the freezing point of liquid water. This review summarizes the chemical evolution of subsurface liquid water oceans, taking into account a number of chemical processes occuring in aqueous environments and partly related to material exchange with the deep interior. Of interest are processes occuring at the transitions from the liquid water layer to the ice layers above and below, involving the possible formation of clathrate hydrates and high-pressure ices on large icy satellites. In contrast, water-rock exchange is important for the chemical evolution of the liquid water layer if the latter is in contact with ocean floor rock on small satellites. The composition of oceanic floor deposits depends on ambient physical conditions and ocean chemistry, and their evolutions through time. In turn, physical properties of the ocean floor affect the circulation of oceanic water and related thermal effects due to tidally-induced porous flow and aqueous alteration of ocean floor rock.     

Thermal Properties of Icy Surfaces in the Outer Solar System

The thermal properties of airless icy surfaces are providing a wealth of information on their regolith structure after eons of space weathering. Numerous observations of the thermal cycles of Jupiter and Saturn icy satellites or Centaurs and TNOs have been acquired in the latest decades thanks to the Galileo and Cassini missions and to the Spitzer and Herschel telescopes. These observations and the latest developments on thermophysical modeling which have been achieved to link the thermal inertia to the regolith structure are reviewed here. Measured thermal inertias of these surfaces covered with water ice are very low, roughly between about 1 and 100 J/m²/K/s^1/2. Often interpreted as due to unconsolidated or highly porous regoliths, these low values may result from a composition of amorphous ice or from the roughness of grains defacing contacts in a regolith of normal compaction. Taken together, thermal inertias appear to increase with probed depth and to decrease with heliocentric distance. This latter effect can be easily reproduced if heat transfer is dominated by radiation in pores, despite low temperatures, because the conduction through grains is limited, either due to the presence of amorphous ice or because of the roughness of grains.     

Cassini-Huygens Investigations of Satellite Surfaces and Interiors

The Saturnian system contains 18 known satellites ranging from 10 km to 2575 km in radius. In bulk properties and surface appearance these objects show less regularity than the sparser Jupiter system. The Galilean-sized moon Titan sports a dense atmosphere of nitrogen and methane which renders surface observations difficult, but also makes this moon intriguing from the standpoints of climate change and exobiology. The Cassini-Huygens mission will make extensive observations of the satellites over a range of wavelengths, as well as using in-situ sampling of satellite environments (and in the case of Titan, sampling of atmosphere and surface). The goals of these extensive investigations are to understand the bulk properties of the satellites, their surface compositions and evolution through time, as well as interactions with the magnetosphere and rings of Saturn. This knowledge in turn should provide a deeper understanding of the origin of the Saturnian system as a whole and underlying causes for the distinctive differences from the Jovian satellite system. This revised version was published online in August 2006 with corrections to the Cover Date.     

The Solar Chemical Composition

We present our current knowledge of the solar chemical composition based on the recent significant downward revision of the solar photospheric abundances of the most abundant metals. These new solar abundances result from the use of a 3D hydrodynamic model of the solar atmosphere instead of the classical 1D hydrostatic models, accounting for departures from LTE, and improved atomic and molecular data. With these abundances, the new solar metallicity, Z, decreases to Z=0.012, almost a factor of two lower than earlier widely used values. We compare our values with data from other sources and analyse a number of impacts of these new photospheric abundances. While resolving a number of longstanding problems, the new 3D-based solar photospheric composition also poses serious challenges for the standard solar model as judged by helioseismology.     

Comets and Chemical Composition

It is commonly believed that comets are made of primordial material. As a consequence, they can reveal more information about the origin of our solar system. To interpret the coma composition measurements of comet Churyumov–Gerasimenko that will be collected by the Rosetta mission, models of the coma chemistry have to be constructed. However, programming the chemistry of a cometary coma is extremely complex due to the large number of species and reactions involved. Moreover, such a program needs to be very flexible as one may want to extend, change, or update the set of species, reactions, and reaction rates. Therefore, we developed software to manage a database of species and reactions and to generate code automatically to compute source/loss balances. This database includes the data from the UMIST database and the ion–molecule reactions collected by V.G. Anicich. To use all these databases together, a lot of practical problems need to be solved, but the result is an enormous source of information about chemical reactions that can be used in chemical models, not only for comets but also for other applications.     

Evolution of Icy Satellites

Evolutionary scenarios for the major satellites of Jupiter, Saturn, Neptune, and Pluto-Charon are discussed. In the Jovian system the challenge is to understand how the present Laplace resonance of Io, Europa, and Ganymede was established and to determine whether the heat being radiated by Io is in balance with the present tidal dissipation in the moon. In the Saturnian system, Enceladus and Titan are the centers of attention. Tidal heating is the likely source of activity at the south pole of Enceladus, although the details of how the heating occurs are not understood. An evolutionary scenario based on accretion and internal differentiation is presented for Titan, whose present substantial orbital eccentricity is not associated with any dynamical resonance. The source and maintenance of methane in Titan’s present atmosphere remain uncertain. Though most attention on the Saturnian moons focuses on Titan and Enceladus, the mid-size satellites Iapetus, Rhea, Tethys, and the irregular satellite Phoebe also draw our interest. An evolutionary scenario for Iapetus is presented in which spin down from an early rapidly rotating state is called upon to explain the satellite’s present oblate shape. The prominent equatorial ridge on Iapetus is unexplained by the spin down scenario. A buckling instability provides another possible explanation for the oblateness and equatorial ridge of Iapetus. Rhea is the only medium-size Saturnian satellite for which there are gravity data at present. The interpretation of these data are uncertain, however, since it is not known if Rhea is in hydrostatic equilibrium. Pluto and Charon are representative of the icy dwarf planets of the Kuiper belt. Did they differentiate as they evolved, and do either of them have a subsurface liquid water ocean? New Horizons might provide some answers when it arrives at these bodies.     

Solar Models with Non-Standard Chemical Composition

The OPAL monochromatic opacity tables are used to evaluate the impact of a non-standard chemical composition on solar models. A calibrated solar model with consistent diffusion including the effect of radiative forces and ionization on drift velocities is presented. It is shown that surface abundances are predicted to change slightly more than in traditional solar models where these refinements are not included. All elements included in the model settle at similar rates which is reflected in the relative variation in surface abundances ranging from 7.5% for calcium to 8.8% for argon. The structural difference between the consistent model and the traditional model is small, with a maximum effect of 0.3% for the isothermal sound speed at the base of the convection zone. The settling of CNO is only marginally affected. Opacity profiles have also been calculated with varying abundances for volatile elements, for which the abundances are poorly known, and other selected elements. It is shown that if one allows a 10% variation of these elements individually one can expect a peak Rosseland mean opacity variation of 3% for oxygen, a little less 2% for Si and Ne, and around 1% for Mg and S in the radiative zone. Other light metals and volatile elements have no significant impact on the opacity. This revised version was published online in June 2006 with corrections to the Cover Date.     

冬日这冷雪

正在某个寒冷的夜晚,雪就这样与我们不期而遇了。不计其数的雪花从上方黑夜急速飘落,仿佛每一朵都是天空派来的小战士,身负使命,不问结局。从路灯底下看雪花犹为壮丽,因为其他的事物都消失在黑夜里了,剩下的只有光晕和飘落的雪。从天空坠地的那一刻,这些白色小精灵就无声地化作一只小水珠,再温柔地浸入土地。正像是世间来去众生,从呱呱坠地,到老终了,渺小、脆弱,但又顽强、绚丽。     

Spectroscopy of Icy Moon Surface Materials

Remote sensing of icy objects in the outer solar system relies upon availability of appropriate laboratory measurements. Surface deposits of specific substances often provide our most direct route to understanding interior composition, thereby informing theories of endogenic surface modification, exogenic surface processing and processes involving exchange of material with the interiors. Visible to near-infrared reflectance spectra of properly prepared compounds are required to enable retrieval of surface abundances through linear and nonlinear mixture analysis applied to spacecraft observations of icy bodies. This chapter describes the techniques, conditions and approaches necessary to provide reference spectra of use to theoretical models of icy satellite surface compositions, and summarizes the current state of knowledge represented in the published literature.     

Atmospheric/Exospheric Characteristics of Icy Satellites

The atmospheres/exospheres of icy satellites greatly vary from one to the next in terms of density, composition, structure or steadiness. Titan is the only icy satellite with a dense atmosphere comparable in many ways to that of the Earth’s atmosphere. Titan’s atmosphere prevents the surface from direct interaction with the plasma environment, but gives rise to Earth-like exchanges of energy, matter and momentum. The atmospheres of other satellites are tenuous. Enceladus’ atmosphere manifests itself in a large water vapor plume emanating from surface cracks near the south pole. Io’s SO₂ atmosphere originates from volcanoes. Europa’s tenuous O₂ atmosphere is produced by intense radiation bombardment. This chapter reviews the characteristics of the atmospheres of Titan, Enceladus, Io and Europa based on observations.     

Rheological and Thermal Properties of Icy Materials

Laboratory measurements of physical properties of planetary ices generate information for dynamical models of tectonically active icy bodies in the outer solar system. We review the methods for measuring both flow properties and thermal properties of icy planetary materials in the laboratory, and describe physical theories that are essential for intelligent extrapolation of data from laboratory to planetary conditions. This review is structured with a separate and independent section for each of the two sets of physical properties, rheological and thermal. The rheological behaviors of planetary ices are as diverse as the icy moons themselves. High-pressure water ice phases show respective viscosities that vary over four orders of magnitude. Ices of CO₂, NH₃, as well as clathrate hydrates of CH₄ and other gases vary in viscosity by nearly ten orders of magnitude. Heat capacity and thermal conductivity of detected/inferred compositions in outer solar system bodies have been revised. Some low-temperature phases of minerals and condensates have a deviant thermal behavior related to paramount water ice. Hydrated salts have low values of thermal conductivity and an inverse dependence of conductivity on temperature, similar to clathrate hydrates or glassy solids. This striking behavior may suit the dynamics of icy satellites.     

Effects of the External Environment on Icy Satellites

In order to understand the evolution of planetary satellite surfaces and atmospheres it is important to understand their external environments. In this paper we look at the interactions between plasma in planetary magnetospheres and satellite atmospheres responsible for the production and loss of atmospheric mass. We focus on the processes which take place in the tenuous atmospheres of the Galilean satellites and in the Enceladus water plume. We also review the impact histories of satellites in the outer solar system, and compare the record of impacts in the inner and outer solar system.     

Morphological Structure and Chemical Composition of Cometary Nuclei and Dust

The chemical composition of comet nuclei derived from current data on interstellar dust ingredients and comet dust and coma molecules are shown to be substantially consistent with each other in both refractory and volatile components. When limited by relative cosmic abundances the water in comet nuclei is constrained to be close to 30% by mass and the refractory to volatile ratio is close to 1:1. The morphological structure of comet nuclei, as deduced from comet dust infrared continuum and spectral emission properties, is described by a fluffy (porous) aggregate of tenth micron silicate core-organic refractory mantle particle on which outer mantles of predominantly H₂O ices contain embedded carbonaceous and polycyclic aromatic hydrocarbon (PAH) type particles of size in the of 1 - 10nm range. This revised version was published online in June 2006 with corrections to the Cover Date.     

The Chemical Composition of Interstellar Matter at the Solar Location

The Local Interstellar Cloud (LIC) surrounds the Solar System and sets the boundary conditions for the heliosphere. Using both in situ and absorption line data towards ε CMa we are able to constrain both the ionization and the gas phase abundances of the LIC gas at the Solar Location. We find that the abundances are consistent with all of the carbonaceous dust grains having been destroyed, and in fact with a supersolar abundance of C. The constituents of silicate grains, Si, Mg, and Fe, appear to be sub-solar, indicating that silicate dust is present in the LIC. N, O and S are close to the solar values.     

Water and the Interior Structure of Terrestrial Planets and Icy Bodies

Water content and the internal evolution of terrestrial planets and icy bodies are closely linked. The distribution of water in planetary systems is controlled by the temperature structure in the protoplanetary disk and dynamics and migration of planetesimals and planetary embryos. This results in the formation of planetesimals and planetary embryos with a great variety of compositions, water contents and degrees of oxidation. The internal evolution and especially the formation time of planetesimals relative to the timescale of radiogenic heating by short-lived ²⁶Al decay may govern the amount of hydrous silicates and leftover rock–ice mixtures available in the late stages of their evolution. In turn, water content may affect the early internal evolution of the planetesimals and in particular metal-silicate separation processes. Moreover, water content may contribute to an increase of oxygen fugacity and thus affect the concentrations of siderophile elements within the silicate reservoirs of Solar System objects. Finally, the water content strongly influences the differentiation rate of the icy moons, controls their internal evolution and governs the alteration processes occurring in their deep interiors.     

卫星双向法与卫星测距

卫星双向时间比对是目前远距离台站时间比对精度最高的时间同步技术,时间比对精度达几百皮秒,比GPS共视技术的时间比对精度几乎高一个数量级。中科院国家授时中心根据多台站卫星时间比对经验,提出利用卫星双向比对技术进行卫星测距(称转发器定轨)。实验证明:利用卫星双向技术(卫星需要转发器)进行卫星测距,可得到高精度卫星轨道(内符精度为几厘米)和卫星预报轨道。