X-ray and extreme ultraviolet emissions from comets

There is significant progress in the observations, theory, and understanding of the x-ray and EUV emissions from comets since their discovery in 1996. That discovery was so puzzling because comets appear to be more efficient emitters of x-rays than the Moon by a factor of 80 000. The detected emissions are general properties of comets and have been currently detected and analyzed in thirteen comets from five orbiting observatories. The observational studies before 2000 were based on x-ray cameras and low resolution (E/δE ≈ 1.5-3) instruments and focused on the morphology of xrays, their correlations with gas and dust productions in comets and with the solar x-rays and the solar wind. Even those observations made it possible to choose uniquely charge exchange between the solar wind heavy ions and cometary neutrals as the main excitation process. The recently published spectra are of much better quality and result in the identification of the emissions of the multiply charged ions of O, C, Ne, Mg, and Si which are brought to comets by the solar wind. The observed spectra have been used to study the solar wind composition and its variations. Theoretical analyses of x-ray and EUV photon excitation in comets by charge exchange, scattering of the solar photons by attogram dust particles, energetic electron impact and bremsstrahlung, collisions between cometary and interplanetary dust, and solar x-ray scattering and fluorescence in comets have been made. These analyses confirm charge exchange as the main excitation mechanism, which is responsible for more than 90% of the observed emission, while each of the other processes is limited to a few percent or less. The theory of charge exchange and different methods of calculation for charge exchange are considered. Laboratory studies of charge exchange relevant to the conditions in comets are reviewed. Total and state-selective cross sections of charge exchange measured in the laboratory are tabulated. Simulations of synthetic spectra of charge exchange in comets are discussed. X-ray and EUV emissions from comets are related to different disciplines and fields such as cometary physics, fundamental physics, x-rays spectroscopy, and space physics.This revised version was published online in July 2005 with a corrected cover date.     

X-Ray and extreme ultraviolet emissions from comets

There is significant progress in the observations, theory, and understanding of the x-ray and EUV emissions from comets since their discovery in 1996. That discovery was so puzzling because comets appear to be more efficient emitters of x-rays than the Moon by a factor of 80000. The detected emissions are general properties of comets and have been currently detected and analyzed in thirteen comets from five orbiting observatories. The observational studies before 2000 were based on x-ray cameras and low resolution (E/E1.5–3) instruments and focused on the morphology of x-rays, their correlations with gas and dust productions in comets and with the solar x-rays and the solar wind. Even those observations made it possible to choose uniquely charge exchange between the solar wind heavy ions and cometary neutrals as the main excitation process. The recently published spectra are of much better quality and result in the identification of the emissions of the multiply charged ions of O, C, Ne, Mg, and Si which are brought to comets by the solar wind. The observed spectra have been used to study the solar wind composition and its variations. Theoretical analyses of x-ray and EUV photon excitation in comets by charge exchange, scattering of the solar photons by attogram dust particles, energetic electron impact and bremsstrahlung, collisions between cometary and interplanetary dust, and solar x-ray scattering and fluorescence in comets have been made. These analyses confirm charge exchange as the main excitation mechanism, which is responsible for more than 90% of the observed emission, while each of the other processes is limited to a few percent or less. The theory of charge exchange and different methods of calculation for charge exchange are considered. Laboratory studies of charge exchange relevant to the conditions in comets are reviewed. Total and state-selective cross sections of charge exchange measured in the laboratory are tabulated. Simulations of synthetic spectra of charge exchange in comets are discussed. X-ray and EUV emissions from comets are related to different disciplines and fields such as cometary physics, fundamental physics, x-rays spectroscopy, and space physics.     

X-Rays From Mars

X-rays from Mars were first detected in July 2001 with the satellite Chandra. The main source of this radiation was fluorescent scattering of solar X-rays in its upper atmosphere. In addition, the presence of an extended X-ray halo was indicated, probably resulting from charge exchange interactions between highly charged heavy ions in the solar wind and neutrals in the Martian exosphere. The statistical significance of the X-ray halo, however, was very low. In November 2003, Mars was observed again in X-rays, this time with the satellite XMM-Newton. This observation, characterized by a considerably higher sensitivity, confirmed the presence of the X-ray halo and proved that charge exchange is indeed the origin of the emission. This was the first definite detection of charge exchange induced X-ray emission from the exosphere of another planet. Previously, this kind of emission had been detected from comets (which are largely exospheres) and from the terrestrial exosphere. Because charge exchange interactions between atmospheric constituents and solar wind ions are considered as an important nonthermal escape mechanism, probably responsible for a significant loss of the Martian atmosphere, X-ray observations may lead to a better understanding of the present state of the Martian atmosphere and its evolution. X-ray images of the Martian exosphere in specific emission lines exhibited a highly anisotropic morphology, varying with individual ions and ionization states. With its capability to trace the X-ray emission out to at least 8 Mars radii, XMM-Newton can explore exospheric regions far beyond those that have been observationally explored to date. Thus, X-ray observations provide a novel method for studying processes in the Martian exosphere on a global scale.     

Particle Acceleration Mechanisms

In this paper we review the possible mechanisms for production of non-thermal electrons which are responsible for the observed non-thermal radiation in clusters of galaxies. Our primary focus is on non-thermal Bremsstrahlung and inverse Compton scattering, that produce hard X-ray emission. We first give a brief review of acceleration mechanisms and point out that in most astrophysical situations, and in particular for the intracluster medium, shocks, turbulence and plasma waves play a crucial role. We also outline how the effects of the turbulence can be accounted for. Using a generic model for turbulence and acceleration, we then consider two scenarios for production of non-thermal radiation. The first is motivated by the possibility that hard X-ray emission is due to non-thermal Bremsstrahlung by nonrelativistic particles and attempts to produce non-thermal tails by accelerating the electrons from the background plasma with an initial Maxwellian distribution. For acceleration rates smaller than the Coulomb energy loss rate, the effect of energising the plasma is to primarily heat the plasma with little sign of a distinct non-thermal tail. Such tails are discernible only for acceleration rates comparable or larger than the Coulomb loss rate. However, these tails are accompanied by significant heating and they are present for a short time of <10⁶ years, which is also the time that the tail will be thermalised. A longer period of acceleration at such rates will result in a runaway situation with most particles being accelerated to very high energies. These more exact treatments confirm the difficulty with this model, first pointed out by Petrosian (Astrophys. J. 557:560, 2001). Such non-thermal tails, even if possible, can only explain the hard X-ray but not the radio emission which needs GeV or higher energy electrons. For these and for production of hard X-rays by the inverse Compton model, we need the second scenario where there is injection and subsequent acceleration of relativistic electrons. It is shown that a steady state situation, for example arising from secondary electrons produced from cosmic ray proton scattering by background protons, will most likely lead to flatter than required electron spectra or it requires a short escape time of the electrons from the cluster. An episodic injection of relativistic electrons, presumably from galaxies or AGN, and/or episodic generation of turbulence and shocks by mergers can result in an electron spectrum consistent with observations but for only a short period of less than one billion years.     

Imaging Plasma Density Structures in the Soft X-Rays Generated by Solar Wind Charge Exchange with Neutrals

Both heliophysics and planetary physics seek to understand the complex nature of the solar wind’s interaction with solar system obstacles like Earth’s magnetosphere, the ionospheres of Venus and Mars, and comets. Studies with this objective are frequently conducted with the help of single or multipoint in situ electromagnetic field and particle observations, guided by the predictions of both local and global numerical simulations, and placed in context by observations from far and extreme ultraviolet (FUV, EUV), hard X-ray, and energetic neutral atom imagers (ENA). Each proposed interaction mechanism (e.g., steady or transient magnetic reconnection, local or global magnetic reconnection, ion pick-up, or the Kelvin-Helmholtz instability) generates diagnostic plasma density structures. The significance of each mechanism to the overall interaction (as measured in terms of atmospheric/ionospheric loss at comets, Venus, and Mars or global magnetospheric/ionospheric convection at Earth) remains to be determined but can be evaluated on the basis of how often the density signatures that it generates are observed as a function of solar wind conditions. This paper reviews efforts to image the diagnostic plasma density structures in the soft (low energy, 0.1–2.0 keV) X-rays produced when high charge state solar wind ions exchange electrons with the exospheric neutrals surrounding solar system obstacles.The introduction notes that theory, local, and global simulations predict the characteristics of plasma boundaries such the bow shock and magnetopause (including location, density gradient, and motion) and regions such as the magnetosheath (including density and width) as a function of location, solar wind conditions, and the particular mechanism operating. In situ measurements confirm the existence of time- and spatial-dependent plasma density structures like the bow shock, magnetosheath, and magnetopause/ionopause at Venus, Mars, comets, and the Earth. However, in situ measurements rarely suffice to determine the global extent of these density structures or their global variation as a function of solar wind conditions, except in the form of empirical studies based on observations from many different times and solar wind conditions. Remote sensing observations provide global information about auroral ovals (FUV and hard X-ray), the terrestrial plasmasphere (EUV), and the terrestrial ring current (ENA). ENA instruments with low energy thresholds (\(\sim1~\mbox{keV}\)) have recently been used to obtain important information concerning the magnetosheaths of Venus, Mars, and the Earth. Recent technological developments make these magnetosheaths valuable potential targets for high-cadence wide-field-of-view soft X-ray imagers.Section 2 describes proposed dayside interaction mechanisms, including reconnection, the Kelvin-Helmholtz instability, and other processes in greater detail with an emphasis on the plasma density structures that they generate. It focuses upon the questions that remain as yet unanswered, such as the significance of each proposed interaction mode, which can be determined from its occurrence pattern as a function of location and solar wind conditions. Section 3 outlines the physics underlying the charge exchange generation of soft X-rays. Section 4 lists the background sources (helium focusing cone, planetary, and cosmic) of soft X-rays from which the charge exchange emissions generated by solar wind exchange must be distinguished. With the help of simulations employing state-of-the-art magnetohydrodynamic models for the solar wind-magnetosphere interaction, models for Earth’s exosphere, and knowledge concerning these background emissions, Sect. 5 demonstrates that boundaries and regions such as the bow shock, magnetosheath, magnetopause, and cusps can readily be identified in images of charge exchange emissions. Section 6 reviews observations by (generally narrow) field of view (FOV) astrophysical telescopes that confirm the presence of these emissions at the intensities predicted by the simulations. Section 7 describes the design of a notional wide FOV “lobster-eye” telescope capable of imaging the global interactions and shows how it might be used to extract information concerning the global interaction of the solar wind with solar system obstacles. The conclusion outlines prospects for missions employing such wide FOV imagers.     

Review of energetic (> 20 ke V) bremsstrahlung X-ray measurements from satellites

Worldwide maps of electron precipitation into the atmosphere can be obtained remotely with a unique separation of spatial and temporal variations by sensing from a satellite the bremsstrahlung X-rays produced in the atmosphere by the incident electrons. From X-ray measurements electron fluxes and energy spectra can be derived over a broad range of energies under both daytime and nighttime conditions. The technique was first demonstrated in 1972 and has now been used sucessfully in several programs. The most continuous and widespread coverage can clearly be achieved from high altitudes, but even at only a few hundred kilometers it has been possible to obtain mappings over a wide area since bremsstrahlung X-ray fluxes are often rather steady in time during the few minute duration of a low altitude satellite pass over the polar region. The satellite bremsstrahlung data already acquired have provided information on the long term morphology of the total fluxes and energy spectra of bremsstrahlung X-rays emitted from a large area and have shown that pronounced longitude structure commonly occurs in the X-ray emissions. The data have tended to be complementary in nature to that obtained by the more well established technique of measuring bremsstrahlung X-rays from balloons, whereby time variations can be studied in detail with more limited geographic coverage. From balloons it is known that the X-rays show a variety of time variations, but many of the faster microburst type phenomena have yet to be observed from satellites. The present status of satellite bremsstrahlung X-ray measurements is reviewed here, some of the key results summarized and suggestions made for future improvements in instrumentation. The review is limited to X-rays > 20 ke V and therefore to the associated precipitation of only the more energetic electrons.     

The origin of cosmic rays in spiral galaxies

The problem of the origin and distribution of cosmic rays in the Galaxy is introduced by summarizing the literature on the radio and -ray studies of the Galaxy, discussing the propagation of cosmic rays in the interstellar medium, and listing the observed properties of cosmic rays. The localization of cosmic-ray electrons to their parent galaxies is an indicator that processes leading to cosmic-ray production may be common to galaxies like our own. The studies of external galaxies are therefore relevant to our own and have the advantage of better perspective.Studies of cosmic rays in exsternal galaxies are limited to the electron component which radiates synchrotron emission at radio frequencies. Multi-colour photometry of galaxies allows the separation of stellar populations that harbour particular classes of cosmic-ray sources. Statistical studies aimed at correlating integrated radio and optical properties of galaxies have reached conflicting conclusions. Although a correlation of cosmic rays with the older stellar population is proposed by some authors, others argue that the young stellar population harbours cosmic ray sources.Morphological studies of resolved galaxies provide information on the distributions of cosmic-ray electrons in galaxies. Studies in which the resolution of the radio images is much lower than in the optical are limited and have also produced contradictory results. Radio imaging at optical resolution is required for a direct comparison of cosmic-ray distributions with stellar distributions. Such studies are reviewed and the constraints they impose on cosmic-ray propagation and distribution of cosmic-ray sources is discussed.Theoretical cosmic-ray acceleration mechanisms are surveyed and an attempt is made to determine likely contributors. Mechanisms associated with shock waves in a variety of astrophysical settings are reviewed. Acceleration mechanisms not involving shocks, are also discussed. Finally, the status of the field is summarized along with some speculation on the future directions the field may take.     

The Challenges of Plasma Modeling: Current Status and Future Plans

Successfully modeling X-ray emission from astrophysical plasmas requires a wide range of atomic data to be rapidly accessible by modeling codes, enabling calculation of synthetic spectra for fitting with observations. Over many years the astrophysical databases have roughly kept pace with the advances in detector and spectrometer technology. We outline here the basic atomic processes contributing to the emission from different types of plasmas and briefly touch on the difference between the methods used to calculate this data. We then discuss in more detail the different issues addressed by atomic databases in regards to what data to store and how to make it accessible. Finally, the question of the effect of uncertainties in atomic data is explored, as a reminder to observers that atomic data is not known to infinite precision, and should not be treated as such.     

Plasma-maser effects in plasma astrophysics

The role of a new mode coupling effect (plasma-maser) in space plasma physics is reviewed. The new maser effect, the idea that the resonant electrons with the low-frequency mode can amplify the high-frequency mode, does not require population inversion of electrons. The generation mechanisms of ULF modulated ELF emissions, auroral kilometric radiation, chorus related electrostatic bursts, whistler mode in the solar wind, and type III solar radio bursts are studied based on plasma-maser effect. The forced plasma-maser interaction model reduces to a conservative Lotka-Volterra system. A chaotic behavior of the forced Lotka-Volterra system is obtained. The new mode coupling process has potential importance in attempting to interpret numerous astrophysical radio phenomena.     

X-rays from quasars and active galaxies

We review some of the most important theoretical ideas and observations for quasars and the nuclei of active galaxies, and suggest areas of future research. Emphasis is on the nature of the power source, the radiation processes, and the mechanism for formation and collimation of jets. Phenomena that produce X-rays are of particular concern. Particular topics discussed are the observed and expected time variability, the gas supply mechanisms and luminosity evolution, thermal and nonthermal radiation processes, observed and theoretical spectra, criteria for thermalization of electrons and ions, effects of electron-positron pairs on relativistic plasmas, hydrodynamic, electrodynamic and inertial methods for producing and confining jets. We conclude with a list of needed observations.Based on a lecture given at the Goddard Workshop on X-ray Astronomy (October 1981).     

Microphysics in Astrophysical Plasmas

Although macroscale features dominate astrophysical images and energetics, the physics is controlled through microscale transport processes (conduction, diffusion) that mediate the flow of mass, momentum, energy, and charge. These microphysical processes manifest themselves in key (all) boundary layers and also operate within the body of the plasma. Crucially, most plasmas of interest are rarefied to the extent that classical particle collision length- and time-scales are long. Collective plasma kinetic phenomena then serve to scatter or otherwise modify the particle distribution functions and in so-doing govern the transport at the microscale level. Thus collisionless plasmas are capable of supporting thin shocks, current sheets which may be prone to magnetic reconnection, and the dissipation of turbulence cascades at kinetic scales. This paper lays the foundation for the accompanying collection that explores the current state of knowledge in this subject. The richness of plasma kinetic phenomena brings with it a rich diversity of microphysics that does not always, if ever, simply mimic classical collision-dominated transport. This can couple the macro- and microscale physics in profound ways, and in ways which thus depend on the astrophysical context.     

The interaction between a magnetized plasma flow and a magnetized celestial body: A review of magnetospheric studies

Through an intensive study of the magnetospheres of the Earth, Mercury, and Jupiter, we have begun to understand how a magnetized celestial body interacts with a magnetized plasma flow. Some of the important findings are:Some of these findings may have significant implications in interpreting a variety of astrophysical processes associated with the magnetosphere of magnetic stars, pulsars and head-tail galaxies and also with transient processes, such as solar flares and flarings of particular types of variable stars, etc.     

Cometary dynamics

The modern theory of cometary dynamics is based on Oort's hypothesis that the solar system is surrounded by a spherically symmetric cloud of 10¹¹ to 10¹² comets extending out to interstellar distances. Dynamical modeling and analysis of cometary motion have confirmed the ability of the Oort hypothesis to explain the observed distribution of energies for the long-period comet orbits. The motion of comets in the Oort cloud is controlled by perturbations from random passing stars, interstellar clouds, and the galactic gravitational field. Additionally, comets which enter the planetary region are perturbed by the major planets and by nongravitational forces resulting from jetting of volatiles on the surfaces of the cometary nuclei. The current Oort cloud is estimated to have a radius of 6 to 8 × 10⁴ AU, and to contain some 2 × 10¹² comets with a total mass of 7 to 8 Earth masses. Evidence has begun to accumulate for the existence of a massive inner Oort cloud extending from just beyond the orbit of Neptune to 10⁴ AU or more, with a population up to 100 times that of the outer Oort cloud. This inner cloud may serve as a reservoir to replenish the outer cloud as comets are stripped away by the various perturbers, and may also provide a more efficient source for the short-period comets. Recent suggestions of an unseen solar companion star or a tenth planet orbiting in the inner cloud and causing periodic comet showers on the Earth are likely unfounded. The formation site of the comets in the Oort cloud was likely the extended nebula accretion disc reaching from about 15 to 500 AU from the forming protosun. Comets which escape from the Oort cloud contribute to the flux of interstellar comets, though capture of interstellar comets by the solar system is extremely unlikely. The existence of Oort clouds around other main sequence stars has been suggested by the detection by the IRAS spacecraft of cool dust shells around about 10% of nearby stars.     

Electron-Ion Temperature Equilibration in Collisionless Shocks: The Supernova Remnant-Solar Wind Connection

Collisionless shocks are loosely defined as shocks where the transition between pre-and post-shock states happens on a length scale much shorter than the collisional mean free path. In the absence of collision to enforce thermal equilibrium post-shock, electrons and ions need not have the same temperatures. While the acceleration of electrons for injection into shock acceleration processes to produce cosmic rays has received considerable attention, the related problem of the shock heating of quasi-thermal electrons has been relatively neglected. In this paper we review the state of our knowledge of electron heating in astrophysical shocks, mainly associated with supernova remnants (SNRs), shocks in the solar wind associated with the terrestrial and Saturnian bowshocks, and galaxy cluster shocks. The solar wind and SNR samples indicate that the ratio of electron temperature, (T _e ) to ion temperature (T _p ) declining with increasing shock speed or Alfvén Mach number. We discuss the extent to which such behavior can be understood on the basis of waves generated by cosmic rays in a shock precursor, which then subsequently damp by heating electrons, and speculate that a similar explanation may work for both solar wind and SNR shocks.     

Implications of X-ray Observations for Electron Acceleration and Propagation in Solar Flares

High-energy X-rays and ??-rays from solar flares were discovered just over fifty years ago. Since that time, the standard for the interpretation of spatially integrated flare X-ray spectra at energies above several tens of keV has been the collisional thick-target model. After the launch of the Reuven Ramaty High Energy Solar Spectroscopic Imager (RHESSI) in early 2002, X-ray spectra and images have been of sufficient quality to allow a greater focus on the energetic electrons responsible for the X-ray emission, including their origin and their interactions with the flare plasma and magnetic field. The result has been new insights into the flaring process, as well as more quantitative models for both electron acceleration and propagation, and for the flare environment with which the electrons interact. In this article we review our current understanding of electron acceleration, energy loss, and propagation in flares. Implications of these new results for the collisional thick-target model, for general flare models, and for future flare studies are discussed.     

Magnetic Reconnection in Extreme Astrophysical Environments

Magnetic reconnection is a fundamental plasma physics process in which ideal-MHD??s frozen-in constraints are broken and the magnetic field topology is dramatically re-arranged, which often leads to a violent release of the free magnetic energy. Most of the magnetic reconnection research done to date has been motivated by the applications to systems such as the solar corona, Earth??s magnetosphere, and magnetic confinement devices for thermonuclear fusion. These environments have relatively low energy densities and the plasma is adequately described as a mixture of equal numbers of electrons and ions and where the dissipated magnetic energy always stays with the plasma. In contrast, in this paper I would like to introduce a different, new direction of research??reconnection in high energy density radiative plasmas, in which photons play as important a role as electrons and ions; in particular, in which radiation pressure and radiative cooling become dominant factors in the pressure and energy balance. This research is motivated in part by rapid theoretical and experimental advances in High Energy Density Physics, and in part by several important problems in modern high-energy astrophysics. I first discuss some astrophysical examples of high-energy-density reconnection and then identify the key physical processes that distinguish them from traditional reconnection. Among the most important of these processes are: special-relativistic effects; radiative effects (radiative cooling, radiation pressure, and radiative resistivity); and, at the most extreme end??QED effects, including pair creation. The most notable among the astrophysical applications are situations involving magnetar-strength fields (10¹⁴?C10¹⁵ G, exceeding the quantum critical field B _??4×10¹³ G). The most important examples are giant flares in soft gamma repeaters (SGRs) and magnetic models of the central engines and relativistic jets of Gamma Ray Bursts (GRBs). The magnetic energy density in these environments is so high that, when it is suddenly released, the plasma is heated to ultra-relativistic temperatures. As a result, electron-positron pairs are created in copious quantities, dressing the reconnection layer in an optically thick pair coat, thereby trapping the photons. The plasma pressure inside the layer is then dominated by the combined radiation and pair pressure. At the same time, the timescale for radiation diffusion across the layer may, under some conditions, still be shorter than the global (along the layer) Alfvén transit time, and hence radiative cooling starts to dominate the thermodynamics of the problem. The reconnection problem then becomes essentially a radiative transfer problem. In addition, the high pair density makes the reconnection layer highly collisional, independent of the upstream plasma density, and hence radiative resistive MHD applies. The presence of all these processes calls for a substantial revision of our traditional physical picture of reconnection when applied to these environments and thus opens a new frontier in reconnection research.     

Synchrotron Radiation from Galactic Sources: What We Can Learn About Particle Acceleration

I review the observations of galactic synchrotron sources, focusing on shell supernova remnants (SNRs), with particular attention to attributes that constrain the properties of electron acceleration. Radio observations provide information on source fluxes, spectral index, morphology, and polarization. Recent observations give us strong reason to believe that several young SNRs show synchrotron X-ray emission. Even if X-rays are thermal, however, limits can be set on the maximum energy to which electrons can be accelerated without a spectral break, since no galactic SNR is observed to have X-ray emission (due to any source) as bright as the extrapolation from radio frequencies of radio synchrotron emission. If synchrotron X-rays are detected or inferred, their morphology and spectrum provide important information on mechanisms governing acceleration to the highest energies. I describe models of synchrotron emission from SNRs and their comparison with observations. Finally, I describe the tasks ahead for both observers and theoreticians, to make better use of what SNR synchrotron emission tells us about particle acceleration.     

Temporal and Spatial Variations of Heliospheric x-ray Emissions Associated with Charge Transfer of the Solar Wind with Interstellar Neutrals

A simple model has been developed that demonstrates that heliospheric X-ray emission can account for about 25%–50% of observed soft X-ray background intensities. Similar to cometary soft X-ray emission, these X-rays are thought to be produced in the heliosphere due to charge transfer collisions between heavy solar wind ions and interstellar neutrals. A more complex model has now been developed to take into account temporal and spatial variations of the solar wind and interstellar neutrals. Measured time histories of the solar wind proton flux are used in the model and the results are compared with the ‘long-term enhancements’ in the soft X-ray background measured by ROSAT for the same time period. This revised version was published online in August 2006 with corrections to the Cover Date.     

X-Ray Spectroscopy of Galaxy Clusters: Beyond the CIE Modeling

X-ray spectra of galaxy clusters are dominated by the thermal emission from the hot intracluster medium. In some cases, besides the thermal component, spectral models require additional components associated, e.g., with resonant scattering and charge exchange. The latter produces mostly underluminous fine spectral features. Detection of the extra components therefore requires high spectral resolution. The upcoming X-ray missions will provide such high resolution, and will allow spectroscopic diagnostics of clusters beyond the current simple thermal modeling. A representative science case is resonant scattering, which produces spectral distortions of the emission lines from the dominant thermal component. Accounting for the resonant scattering is essential for accurate abundance and gas motion measurements of the ICM. The high resolution spectroscopy might also reveal/corroborate a number of new spectral components, including the excitation by non-thermal electrons, the deviation from ionization equilibrium, and charge exchange from surface of cold gas clouds in clusters. Apart from detecting new features, future high resolution spectroscopy will also enable a much better measurement of the thermal component. Accurate atomic database and appropriate modeling of the thermal spectrum are therefore needed for interpreting the data.