Deuterium Fractionation in Interstellar Clouds

This paper reviews the chemical processes responsible for fractionating deuterium in interstellar molecules. I show that this process is intrinsically a low temperature phenomenon and discuss how the degree of enhancement of the deuterium content of molecules is related to the physical conditions, particularly abundances, in molecular clouds. If significant amounts of abundant species, such as CO, are frozen out on to interstellar dust grains, the resulting enhancement in H₂D⁺ can result in its abundance being greater than that of H ₃ ⁺ at 10K. Transfer of the deuteron from H₂D⁺ can then lead to the efficient formation of multiply deuterated species, such as NHD₂ and ND₃. Fractionation can also occur in grain surface reactions and some simple models are discussed. This revised version was published online in August 2006 with corrections to the Cover Date.     

Recent progress in astrochemistry

Models of the four currently recognized regimes of astrochemistry are compared with observations. Ion-Molecule Gas Phase Chemistry is fundamental throughout all interstellar and circumstellar molecular clouds, and by itself explains fairly well the simpler molecular species in diffuse and cold quiescent dense interstellar clouds, as well as in the outer envelopes of circumstellar clouds. Dust-Grain Chemistry may modify ion-molecule chemistry noticeably in regions containing UV radiation, shocks, or other heating agents which can serve to promote surface reactions and to desorb molecules frozen on grains; it likely plays no role in cold quiescent clouds except to adsorb gas phase molecules. Shock Chemistry occurs in regions of star formation and appears important in explaining certain molecular species and in disrupting grains. Circumstellar envelopes combine several chemistries, including those of thermochemical equilibrium in the dense inner regions, and ion-molecule in the outer regions, with grain processes also likely. The limitations of all current models are lack of knowledge of reaction rates, of detailed physical conditions (interstellar clouds), and of the relative depletions (onto grains) of the chemical elements, as well as grain surface chemistry in general. In both interstellar and circumstellar objects, ion-molecule gas phase models are now quite successful in explaining, semi-quantitatively, observed species with up to 4 atoms, but difficulties remain for larger species, as well as the state of carbon, and the models are not yet very predictive.NRAO is operated by Associated Universities Inc. under contract with NSF.     

Dust Properties in the Local Interstellar Medium

Ulysses measurements yield reliable in-situdetection of large dust particles which stem from the interstellar medium (ISM) and which are not observed in interstellar extinction data. Both current models of large grains in the ISM: core-mantle grains as well as composite grains, are in agreement with dust properties implied by the Ulysses results. However, the size of particles detected by Ulysses still exceeds the size of the large grains that are predicted for the ISM. This revised version was published online in August 2006 with corrections to the Cover Date.     

The Ultra Heavy Elements in the Cosmic Radiation

The concept that nuclei of all of the elements in the periodic table were accelerated to relativistic energies in the primary cosmic rays was confirmed by the discovery of the presence of nuclei significantly heavier than iron. These “ultra heavy” nuclei must all have been synthesized in endothermic reactions, occurring predominately in the final stages of stellar evolution. Determination of the relative abundances of these nuclei should provide new insights into the nuclear processes in some of the most energetic events in the life cycle of stars. The very low abundances of these nuclei relative to those of the exothermic lighter nuclei have made progress difficult. In addition, the effects of apparent preferential acceleration mechanisms and of propagation through the interstellar medium have distorted the source abundances. The history of the original discovery of the presence of these nuclei will be followed by a summary of the present state of knowledge of the observed abundances. The effects of acceleration biases and of interstellar propagation will be discussed. Finally some of the possibilities for further advances will be outlined. A copy of the Power Point presentation for this talk is available on request.     

Filtration of Interstellar Atoms through the Heliospheric Interface

Interstellar atoms penetrate deep into the heliosphere after passing through the heliospheric interface—the region of the interaction of the solar wind with the interstellar medium. The heliospheric interface serves as a filter for the interstellar atoms of hydrogen and oxygen, and, to a lesser extent, nitrogen, due to their coupling with interstellar and heliospheric plasmas by charge exchange and electron impact ionization. The filtration has great importance for the determination of local interstellar abundances of these elements, which becomes now possible due to measurements of interstellar pickup by Ulysses and ACE, and anomalous cosmic rays by Voyagers, Ulysses, ACE, SAMPEX and Wind. The filtration of the different elements depends on the level of their coupling with the plasma in the interaction region. The recent studies of the filtration of the interstellar atoms in the heliospheric interface region is reviewed in this paper. The dependence of the filtration on the local interstellar proton and H atom number densities is discussed and the roles of the charge exchange and electron impact ionization on the filtration are evaluated. The influence of electron temperature in the inner heliosheath on the filtration process is discussed as well. Using the filtration coefficients obtained from the modeling and SWICS/Ulysses pickup ion measurements, the local interstellar abundances of the considered elements are determined.     

Isotopic Fractionation by Ion-Molecule Reactions

Isotopic fractionation in interstellar clouds can occur by ion-molecule reactions at low temperatures. The major effect is not kinetic but thermodynamic in origin in that it arises from the difference in rate coefficients between forward and backward directions in reactions which exchange isotopic atoms. In this article, we concentrate on deuterium fractionation in interstellar clouds; this effect enhances the relative abundances of deuterated isotopomers to their normal counterparts by up to four orders of magnitude as compared with the basic D/H elemental abundance ratio. We also discuss the fractionation of ¹⁵N and ¹³C. This revised version was published online in August 2006 with corrections to the Cover Date.     

From interstellar matter to comets: Elemental abundances in interstellar dust and in comet Halley

Analogies between interstellar and cometary matter can be found in their chemical compositions, both in the gaseous and solid phases, but also in the physical processes involved like evidence for ion-molecules reactions at low temperature and for ice irradiation processes. Such analogies can be observed from 3 types of measurements: interstellar spectra, cometary observations, and analyses of interplanetary dust particles, with the help of laboratory simulation experiments. Taking into account all the present available information, a compilation of the elemental abundances in interstellar matter and in comet Halley is derived, without any assumption about the dust to gas ratio. It is found that there is a significant apparent depletion of nitrogen, presently unexplained, in both interstellar and cometary materials.     

Cosmic-Ray Energy Spectra and Time Variations in the Local Interstellar Medium: Constraints and Uncertainties

The spectra of galactic cosmic rays that are observed inside the heliosphere result from the interaction of the spectra present in the local interstellar medium with the structured but turbulent magnetic field carried by the solar wind. Observational tests of solar modulation theory depend on comparisons between spectra inside and outside the heliosphere. Our knowledge of the local interstellar spectra are indirect, using extrapolations of interplanetary spectra measured at high energies where solar modulation effects are minimal and modeling of the physical processes that occur during particle acceleration and transport in the interstellar medium. The resulting estimates of the interstellar spectra can also be checked against observations of the effects that cosmic rays have on the chemistry of the interstellar medium and on the production of the diffuse galactic gamma-ray background. I review the present understanding of the local galactic cosmic-ray spectra, emphasizing the constraints set by observations and the uncertainties that remain.     

The Composition of Interstellar Molecular Clouds

We consider four aspects of interstellar chemistry for comparison with comets: molecular abundances in general, relative abundances of isomers (specifically, HCN and HNC), ortho/para ratios for molecules, and isotopic fractionation, particularly for the ratio hydrogen/deuterium. Since the environment in which the solar system formed is not well constrained, we consider both isolated dark clouds where low mass stars may form and the "hot cores" that are the sites of high mass star formation. Attention is concentrated on the gas phase, since the grains are considered elsewhere in this volume. This revised version was published online in June 2006 with corrections to the Cover Date.     

D/H and Nearby Interstellar Cloud Structures

Analysis of UV spectra obtained with the HST, FUSE and other satellites provides a new understanding of the deuterium abundance in the local region of the galactic disk. The wide range of gas-phase D/H measurements obtained outside of the Local Bubble can now be explained as due to different amounts of deuterium depletion on carbonaceous grains. The total D/H ratio including deuterium in the gas and dust phases is at least 23 parts per million of hydrogen, which is providing a challenge to models of galactic chemical evolution. Analysis of HST and ground-based spectra of many lines of sight to stars within the Local Bubble have identified interstellar velocity components that are consistent with more than 15 velocity vectors. We have identified the structures of 15 nearby warm interstellar clouds on the basis of these velocity vectors and common temperatures and depletions. We estimate the distances and masses of these clouds and compare their locations with cold interstellar clouds.     

Physics of interplanetary and interstellar dust

Observations of dust in the solar system and in the diffuse interstellar medium are summarized. New measurements of interstellar dust in the heliosphere extend our knowledge about micron-sized and bigger particles in the local interstellar medium. Interplanetary grains extend from submicron- to meter-sized meteoroids. The main destructive effect in the solar system are mutual collisions which provide an effective source for smaller particles. In the diffuse interstellar medium sputtering is believed to be the dominant destructive effect on submicron-sized grains. However, an effective supply mechanism for these grains is presently unknown. The dominant transport mechanisms in the solar system is the Poynting-Robertson effect which sweeps meteoroids bigger than about one micron in size towards the sun. Smaller particles are driven out of the solar system by radiation pressure and electromagnetic interaction with the interplanetary magnetic field. In the diffuse interstellar medium coupling of charged interstellar grains to large-scale magnetic fields seem to dominate frictional coupling of dust to the interstellar gas.     

Grain Surface Models and Data for Astrochemistry

The cross-disciplinary field of astrochemistry exists to understand the formation, destruction, and survival of molecules in astrophysical environments. Molecules in space are synthesized via a large variety of gas-phase reactions, and reactions on dust-grain surfaces, where the surface acts as a catalyst. A broad consensus has been reached in the astrochemistry community on how to suitably treat gas-phase processes in models, and also on how to present the necessary reaction data in databases; however, no such consensus has yet been reached for grain-surface processes. A team of \({\sim}25\) experts covering observational, laboratory and theoretical (astro)chemistry met in summer of 2014 at the Lorentz Center in Leiden with the aim to provide solutions for this problem and to review the current state-of-the-art of grain surface models, both in terms of technical implementation into models as well as the most up-to-date information available from experiments and chemical computations. This review builds on the results of this workshop and gives an outlook for future directions.     

Deuterium in Molecules of the Interstellar Medium

Deuterated molecules are detected both in interstellar translucent clouds and in cold dark clouds, as well as in star forming regions. We review the recent observational studies of deuterated molecules ranging from the VUV to the millimeter wavelength range. We outline some sources of uncertainties on the deuterium fractionation and on the subsequent derivation of the elemental deuterium to hydrogen ratio. Steady state versus time dependent models are discussed and the role of initial conditions is emphasized. This revised version was published online in August 2006 with corrections to the Cover Date.     

The Composition of Cosmic Rays and the Mixing of the Interstellar Medium

The differences between the composition of Galactic cosmic rays and that of the interstellar medium are manifold, and they contain a wealth of information about the varying processes that created them. These differences reveal much about the initial mixing of freshly synthesized matter, the chemistry and differentiation of the interstellar medium, and the mechanisms and environment of ion injection and acceleration. Here we briefly explore these processes and show how they combine to create the peculiar, but potentially universal, composition of the cosmic rays and how measurements of the composition can provide a unique measure of the mixing ratio of the fresh supernova ejecta and the old interstellar medium in this initial phase of interstellar mixing. In particular, we show that the major abundance differences between the cosmic rays and the average interstellar medium can all result from cosmic ray ion injection by sputtering and scattering from fast refractory oxide grains in a mix of fresh supernova ejecta and old interstellar material. Since the bulk of the Galactic supernovae occur in the cores of superbubbles, the bulk of the cosmic rays are accelerated there out of such a mix. We show that the major abundance differences all imply a mixing ratio of the total masses of fresh supernova ejecta and old interstellar material in such cores is roughly 1 to 4. That means that the metallicity of ∼3 times solar, since the ejecta has a metallicity of ∼8 times that of the present interstellar medium.     

Oxygen and carbon abundances for the WO stars

We present relative carbon and oxygen abundances derived via an optically thin recombination line analysis for five WO stars, and compare the derived abundances to recent evolutionary models. New recombination coefficients for O⁴⁺, O⁵⁺ and O⁶⁺ ions have allowed total oxygen abundances to be derived. The final C/He values range between 0.4 and 0.8 by number, consistent with C/He ratios previously derived for WC stars. O/He values range between 0.1–0.4, with C/O ratios between 2.1–4.8.A comparison of the derived abundances with the evolutionary models of Maeder (1990) and Schaller et al. (1992) shows promising agreement. We find reasonably tight agreement between the abundances derived for the WO stars. The degree of enhancement for the oxygen abundances in regions of low metallicity predicted by Maeder (1990) is not corroborated by our results.Additionally we present a revised, quantified classification scheme for WO subtypes. We extend the class to lower excitation, WO5, and place MS 4 (=WR 30a) in this class. Equivalent widths of the strongest lines of MS 4 are also presented. Finally, we present new observations of DR 1, a WO3 star located in the dwarf irregular galaxy IC 1613.     

An ISO View on Interstellar and Cometary Ice Chemistry

The ISO-SWS instrument offering a large wavelength coverage and a resolution well adapted to the solid phase has changed our knowledge of the physical-chemical properties of ices in space. The discovery of many new ice features was reported and the comparison with dedicated laboratory experiments allowed the determination of more accurate abundances of major ice components. The presence of CO₂ ice has recently been confirmed with the SWS (Short Wavelength Spectrometer) as a dominant ice component of interstellar grain mantles. The bending mode of CO₂ ice shows a particular triple-peak structure which provides first evidence for extensive ice segregation in the line-of-sight toward massive protostars. A comparison of interstellar and cometary ices using recent ISO data and ground-based measurements has revealed important similarities but also indicated that comets contain, beside pristine interstellar material, admixtures of processed material. The investigation of molecules in interstellar clouds is essential to reveal the link between dust in the interstellar medium and in the Solar System. This revised version was published online in June 2006 with corrections to the Cover Date.     

Modelling the heliosphere

An overview of our present efforts at the Bartol Research Institute in modelling the largescale interaction of the solar wind with the local interstellar medium is presented. Particular stress is placed on the self-consistent inclusion of neutral hydrogen in the models and both 2D and 3D structure is discussed. Observational implications are noted.     

Velocity Distribution of Interstellar H Atoms in the Heliospheric Interface

In this paper we present first results of a numerical computation of the velocity distribution function of interstellar H atoms in the heliospheric interface, the region of the solar and interstellar wind interaction. The velocity distribution is a key tool to evaluate uncertainties introduced by various simplified models of the interface. We numerically solve the kinetic equation for gas of H-atoms self-consistently with the hydrodynamic equations for plasma. Neutral and plasma components are efficiently coupled by charge exchange. The interaction disturbs the atom velocity distribution, which is assumed to be Maxwellian in the circumsolar local interstellar medium. It is shown that besides ‘original’ interstellar atoms, there are three other important atom populations originating in the heliospheric interface. Velocity distribution functions of these populations at the heliopause are presented and discussed. This revised version was published online in August 2006 with corrections to the Cover Date.     

Interstellar Matter and the Boundary Conditions of the Heliosphere

The interstellar cloud surrounding the solar system regulates the galactic environment of the Sun, and determines the boundary conditions of the heliosphere. Both the Sun and interstellar clouds move through space, so these boundary conditions change with time. Data and theoretical models now support densities in the cloud surrounding the solar system of n(H0)=0.22±0.06 cm−3, and n(e−)∼0.1 cm−3, with larger values allowed for n(H0) by radiative transfer considerations. Ulysses and Extreme Ultraviolet Explorer satellite He0 data yield a cloud temperature of 6400 K. Nearby interstellar gas appears to be structured and inhomogeneous. The interstellar gas in the Local Fluff cloud complex exhibits elemental abundance patterns in which refractory elements are enhanced over the depleted abundances found in cold disk gas. Within a few parsecs of the Sun, inconclusive evidence for factors of 2–5 variation in Mg+ and Fe+ gas phase abundances is found, providing evidence for variable grain destruction. In principle, photoionization calculations for the surrounding cloud can be compared with elemental abundances found in the pickup ion and anomalous cosmic-ray populations to model cloud properties, including ionization, reference abundances, and radiation field. Observations of the hydrogen pile up at the nose of the heliosphere are consistent with a barely subsonic motion of the heliosphere with respect to the surrounding interstellar cloud. Uncertainties on the velocity vector of the cloud that surrounds the solar system indicate that it is uncertain as to whether the Sun and α Cen are or are not immersed in the same interstellar cloud. This revised version was published online in June 2006 with corrections to the Cover Date.