Observations of the ozone and nitrogen dioxide profiles in the TROICA-4 experiment

To investigate the vast area of Russia, a mobile scientific facility based in a railway carriage was developed. It is capable to perform continues measurements being coupled in a passenger train traveling along railroads. It was first equipped with a spectrometer for remote sensing of ozone and nitrogen dioxide in the atmosphere for the transcontinental observations into the chemistry of the atmosphere-4 expedition performed from February 18 to March 5, 1998. A twilight DOAS method, which was applied for retrieval of the nitrogen dioxide profiles basing on spectral measurements at the visible wavelengths (434–451 nm), is described in the paper. Main features of a new algorithm for retrieval of the ozone profile and total content using the differential structure of the UV spectrum (310–335 nm) are presented. The ozone and nitrogen dioxide contents are obtained and shortly validated against available alternative data.     

Integrity of sulfur concrete subjected to simulated lunar temperature cycles

In view of potential application as a construction material on the lunar surface the mechanical integrity of sulfur concrete was evaluated after being subjected to simulated temperature cycles. Here, small cubes of sulfur concrete were repeatedly cycled between room (20 °C) and liquid nitrogen (−191 °C) temperatures after which they, and non-cycled cubes, were evaluated by compression testing. The compression strength of the non-cycled samples averaged ∼35 MPa (5076 psi) before failing whereas the cycled samples fractured at about 7 MPa (1015 psi). Microscopic examination of the fracture surfaces from the cycled samples showed clear de-bonding of the sulfur from the aggregate whereas it was seen adhering in those non-cycled. Based on a simple analysis it was concluded that the large strength discrepancy between cycled and non-cycled samples is due to differences between the coefficients of thermal expansion of the materials constituting the concrete.     

First results of ozone profiles between 35 and 65 km retrieved from SCIAMACHY limb spectra and observations of ozone depletion during the solar proton events in October/November 2003

Ozone density profiles between 35 and 65 km altitude are derived from scattered sunlight limb radiance spectra measured by the SCIAMACHY instrument on the Envisat satellite. The method is based on the inversion of normalized limb radiance profiles in the Hartley absorption bands of ozone at selected wavelengths between 250 and 310 nm. It employs a non-linear Newtonian iteration version of Optimal Estimation (OE) coupled with the radiative transfer model SCIARAYS. The limb scatter technique combined with a classical OE retrieval in the short-wave UV-B and long-wave UV-C delivers reliable results as shown by a first comparison with MIPAS V4.61 profiles yielding agreement within 10% between 38 and 55 km. An overview of the methodology and an initial error analysis are presented. Furthermore the effect of the solar proton storm between 28 October and 6 November 2003 on the ozone concentration profiles is shown. They indicate large depletion of ozone of about 60% at 50 km in the Northern hemisphere, a weaker depletion in the Southern hemisphere and a dependence of the depletion on the Earth’s magnetic field.     

Vertical wavenumber spectra of atmospheric ozone measured from ozonesonde observations

Vertical profiles of ozone have been measured at balloon altitudes. Our purpose is to examine the character of vertical wavenumber spectra of ozone fluctuations, to assess the possible roles of gravity wave field in ozone fluctuations, and to determine dominant vertical wavelengths of ozone spectra. Vertical wavenumber spectra of 12 ozone fluctuations obtained during June–August 2003 are presented. Results indicate that mean spectral slopes in the wavenumber range from 4.69 × 10⁻⁴ to 2.50 × 10⁻³ cyc/m are about −2.91 in the troposphere and −2.87 in the lower stratosphere, which is close to the slope of −3 predicted by current gravity wave saturation models. The consistency of the observed spectral slopes with the value of −3 predicted by current gravity wave saturation models suggests that the observed ozone fluctuations are due primarily to atmospheric gravity waves. At m = 1/(1000 m) the mean spectral amplitude is over 30 times larger in the lower stratosphere than in the troposphere. Mean vertical wavenumber spectra in area-preserving form reveal dominant vertical wavelengths of ∼2.6 km in the troposphere and ∼2.7 km in the lower stratosphere, which is consistent with the values varying between 1.5 and 3.0 km estimated from the velocity field and temperature field at these heights.     

Quasi-biennial oscillation (QBO) of tropical total ozone under alternative QBO scenarios of equatorial stratospheric wind

Equatorial total column ozone variations with quasi-biennial periodicity are described by paying attention to their coupling with the quasi-biennial oscillation (QBO) of zonal wind in equatorial stratosphere. Analysis is made for the 35-year time interval from 1978 to 2013 using the zonal mean total ozone (TOZ) data in latitude band from 5° S to 5° N derived from satellite measurements by means of Total Ozone Mapping Spectrometer (TOMS) and Ozone Monitoring Instrument (OMI). The study was performed using strong seasonal regularities of the wind QBO and the discrete variation of the QBO-period revealed earlier. The forecast of the wind QBO evolution made in Gabis (2012) is fully justified. The comparison between predicted and actually observed changes of the height wind structure shows the prominent accordance, which confirms the forecast validity. It is shown that variations of deseasonalized TOZ are in strong coupling with changes of equatorial wind QBO that coincides with the numerous previous researches. However our results contradict the assumption about quite complicated ozone response in the equatorial region due to continuously varying with time relationship between annual and quasi-biennial cycles and irregularly variable wind QBO-period. The total ozone changes actually observed clearly corresponds to the mean ozone variations calculated for different QBO scenarios and aligned according to the sequence of QBO scenarios already occurred in fact. This close association indicates the possibility of forecasting the equatorial total ozone QBO based on the predicted wind QBO.     

Physiologic and metabolic responses of wheat seedlings to elevated and super-elevated carbon dioxide

The metabolic consequence of suboptimal (400 μmol mol⁻¹ or ppm), near-optimal (1500 ppm) and supra-optimal (10,000 ppm) atmospheric carbon dioxide concentrations [CO₂] was investigated in an attempt to reveal plausible underlying mechanisms for the differential physiological and developmental responses to increasing [CO₂]. Both non-targeted and targeted metabolite profiling by GC–MS and LC–MS were employed to examine primary and secondary metabolites in wheat (Triticum aestivum, cv Yocoro rojo) continuously exposed to these [CO₂] levels for 14, 21 and 28 days. Metabolite profile was altered by both [CO₂] and physiological age. In general, plants grown under high [CO₂] exhibited a metabolite profile characteristic of older plants under ambient CO₂. Elevated [CO₂] resulted in higher levels of phosphorylated sugar intermediates, though no clear trend in the content of reducing sugars was observed. Transient starch content was enhanced by increasing [CO₂] to a much greater extent at 10,000 ppm CO₂ than at 1500 ppm CO₂. The percentage increase of starch content resulting from CO₂ enrichment declined as plants develope. In contrast, elevated [CO₂] promoted the accumulation of secondary metabolites (flavonoids) progressively to a greater extent as plants became mature. Elevated [CO₂] to 1500 ppm induced a higher initial growth rate, while super-elevated [CO₂] appeared to negate such initial growth promotion. However, after 4 weeks, there was no difference in vegetative growth between 1500 and 10,000 ppm CO₂-grown plants, both elevated CO₂ levels resulted in an overall 25% increase in biomass over the control plants. More interestingly, elevated atmospheric [CO₂] reduced evapotranspiration rate (ET), but further increase to the supra-optimal level resulted in increased ET (a reversed trend), i.e. ET at 1500 ppm < ET at 10,000 ppm < ET at 400 ppm. The differential effect of elevated and super-elevated CO₂ on plants was further reflected in the nitrogen dynamics. These results provide the potential metabolic basis for the differential productivity and stomatal function of plants grown under elevated and super-elevated CO₂ levels.     

Study on extraction of crop information using time-series MODIS data in the Chao Phraya Basin of Thailand

In order to acquire the crop-related information in Chao Phraya Basin, time-series MODIS data were used in this paper. Although the spatial resolution of MODIS data is not very high, it is still useful for detecting very large-scale phenomenon, such as changes in seasonal vegetation patterns. After the data processing a general crop-related LULC (land use and land cover) map, cropping intensity map and cropping patterns map were produced. Analysis of these maps showed that the main land use type in the study area was farmland, most of which was dominated by rice. Rice fields mostly concentrated in the flood plains and double or triple rice-cropping system was commonly employed in this area. Maize, cassava, sugarcane and other upland crops were mainly distributed in the high alluvial terraces. Because these area often have water shortage problem particularly in the dry season which can support only one crop in a year, the cropping intensity was very low. However, some upland areas can be cultivated twice a year with crops which have short growing seasons. The crop information extracted from MODIS data sets were assessed by CBERS data, statistic data and so on. It was shown that MODIS derived crop information coincided well with the statistic data at the provincial level. At the same time, crop information extracted by MODIS data sets and CBERS were compared with each other which also showed similar spatial patterns.     

Kinetic temperature and carbon dioxide from broadband infrared limb emission measurements taken from the TIMED/SABER instrument

The Sounding of the Atmosphere using Broadband Emission Radiometry (SABER) experiment is one of four instruments on NASA’s Thermosphere–Ionosphere–Energetics and Dynamics (TIMED) satellite. SABER measures broadband infrared limb emission and derives vertical profiles of kinetic temperature (Tk) from the lower stratosphere to approximately 120 km, and vertical profiles of carbon dioxide (CO₂) volume mixing ratio (vmr) from approximately 70 km to 120 km. In this paper we report on SABER Tk/CO₂ data in the mesosphere and lower thermosphere (MLT) region from the version 1.06 dataset. The continuous SABER measurements provide an excellent dataset to understand the evolution and mechanisms responsible for the global two-level structure of the mesopause altitude. SABER MLT Tk comparisons with ground-based sodium lidar and rocket falling sphere Tk measurements are generally in good agreement. However, SABER CO₂ data differs significantly from TIME-GCM model simulations. Indirect CO₂ validation through SABER-lidar MLT Tk comparisons and SABER-radiation transfer comparisons of nighttime 4.3 μm limb emission suggest the SABER-derived CO₂ data is a better representation of the true atmospheric MLT CO₂ abundance compared to model simulations of CO₂ vmr.     

Effects of different carbon dioxide and LED lighting levels on the anti-oxidative capabilities of Gynura bicolor DC

Gynura bicolor DC is not only an edible plant but also a kind of traditional Chinese herbal medicine. G. bicolor DC grown in controlled environmental chambers under 3 CO₂ concentrations [450 (ambient), 1500 (elevated), 8000 (super-elevated) μmol mol⁻¹] and 3 LED lighting conditions [white (WL), 85% red + 15% blue (RB15), 70% red + 30% blue (RB30) ] were investigated to reveal plausible antioxidant anabolic responses to CO₂ enrichment and LED light quality. Under ambient and elevated CO₂ levels, blue light increasing from 15% to 30% was conducive to the accumulation of anthocyanins and total flavonoids, and the antioxidant activity of extract was also increased, but plant biomass was decreased. These results demonstrated that the reinforcement of blue light could induce more antioxidant of secondary metabolites, but depress the effective growth of G. bicolor DC under ambient and elevated CO₂ levels. In addition, compared with the ambient and elevated CO₂ levels, the increased anthocyanins, total flavonoids contents and antioxidant enzyme activities of G. bicolor DC under super-elevated CO₂ level could serve as important components of antioxidative defense mechanism against CO₂ stress. Hence, G. bicolor DC might have higher tolerance to CO₂ stress.     

Carbon dioxide dynamics of combined crops of wheat,cowpea, pinto beans in the Laboratory Biosphere closed ecological system

A mixed crop consisting of cowpeas, pinto beans and Apogee ultra-dwarf wheat was grown in the Laboratory Biosphere, a 40 m³ closed life system equipped with 12,000 W of high pressure sodium lamps over planting beds with 5.37 m² of soil. Similar to earlier reported experiments, the concentration of carbon dioxide initially increased to 7860 ppm at 10 days after planting due to soil respiration plus CO₂ contributed from researchers breathing while in the chamber for brief periods before plant growth became substantial. Carbon dioxide concentrations then fell rapidly as plant growth increased up to 29 days after planting and subsequently was maintained mostly in the range of about 200–3000 ppm (with a few excursions) by CO₂ injections to feed plant growth. Numerous analyses of rate of change of CO₂ concentration at many different concentrations and at many different days after planting reveal a strong dependence of fixation rates on CO₂ concentration. In the middle period of growth (days 31–61), fixation rates doubled for CO₂ at 450 ppm compared to 270 ppm, doubled again at 1000 ppm and increased a further 50% at 2000 ppm. High productivity from these crops and the increase of fixation rates with elevated CO₂ concentration supports the concept that enhanced CO₂ can be a useful strategy for remote life support systems. The data suggests avenues of investigation to understand the response of plant communities to increasing CO₂ concentrations in the Earth’s atmosphere. Carbon balance accounting and evapotranspiration rates are included.     

Determination of surface global radiation using METEOSAT images and ground based visibility measurements

Our purpose is the forecast of the global radiation. As a first step we try to determine the global radiation as function of other predictable parameters. First the daily average values of the relative global radiation was considered as parabolic function of the cloud coverage obtained from METEOSAT images, an empirical formula was determined for calculation of the relative global radiation from the cloud amount. The correct this formula the cloud coverage and ground based visibility data were used. The value of the multiple correlation coefficient presenting the accuracy of the new formula was 0.96 for Budapest, and 0.93 for region of Hungary. This fact indicates that we have a sufficiently correct formula for calculation of the global radiation.     

Seasonal and diurnal behavior of NO2 column density in Antarctica as observed by Mark IV,Brewer Ozone Spectrophotometer Number 153

The Meteorology Department of India has been measuring vertical column density of NO₂ at Maitri (70.7°S, 11.7°E), Antarctica since July 1999 using a Mark IV, Brewer Ozone Spectrophotometer. Maitri is situated at the south of the Antarctic circle. An analysis of 6 years of data shows that NO₂ column has seasonal variation with a maximum value during summer. It is also found that during the period when sun does not set, the NO₂ column exhibits a diurnal variation, with a peak around noon and lower values in the morning and afternoon hours. Using a simple steady-state chemical reaction scheme, an attempt has been made to explain these features.     

Determination of land surface temperature using precipitable water based Split-Window and Artificial Neural Network in Turkey

Land surface temperature (LST) calculation utilizing satellite thermal images is very difficult due to the great temporal variance of atmospheric water vapor in the atmosphere which strongly affects the thermal radiance incoming to satellite sensors. In this study, Split-Window (SW) and Radial Basis Function (RBF) methods were utilized for prediction of LST using precipitable water for Turkey. Coll 94 Split-Window algorithm was modified using regional precipitable water values estimated from upper-air Radiosond observations for the years 1990–2007 and Local Split-Window (LSW) algorithms were generated for the study area. Using local algorithms and Advanced Very High Resolution Radiometer (AVHRR) data, monthly mean daily sum LST values were calculated. In RBF method latitude, longitude, altitude, surface emissivity, sun shine duration and precipitable water values were used as input variables of the structure. Correlation coefficients between estimated and measured LST values were obtained as 99.23% (for RBF) and 94.48% (for LSW) at 00:00 UTC and 92.77% (for RBF) and 89.98% (for LSW) at 12:00 UTC. These meaningful statistical results suggest that RBF and LSW methods could be used for LST calculation.     

Re-entry trajectory tracking of reusable launch vehicle using artificial delay based robust guidance law

A Reusable Launch Vehicle (RLV), during the re-entry phase of its flight, experiences uncertain environment and extreme turbulence. This calls for an effective control strategy to guide the vehicle efficiently on a trajectory that allows safer landing conditions while providing robustness against external disturbances and system uncertainties. In this regard, a Time-Delayed Control (TDC) strategy has been proposed to track the space vehicle on a predetermined trajectory in the presence of these uncertainties. In the proposed approach, the system vector and the uncertainties are lumped into a single function which is estimated using the input and output data from the previous instant. Theoretical analysis of the control strategy executed using Lyapunov’s method, proves Uniformly Ultimately Bounded (UUB) stability of the closed loop system. The efficacy of the proposed approach has been verified through simulation studies which affirm robust tracking of the optimal trajectory generated through Pseudo-Spectral method (PSM), in the presence of time-varying uncertainties.     

Detection and mapping vegetation cover based on the Spectral Angle Mapper algorithm using NOAA AVHRR data

Satellite data, taken from the National Oceanic and Atmospheric Administration (NOAA) have been proposed and used for the detection and the cartography of vegetation cover in North Africa. The data used were acquired at the Analysis and Application of Radiation Laboratory (LAAR) from the Advanced Very High Resolution Radiometer (AVHRR) sensor of 1 km spatial resolution. The Spectral Angle Mapper Algorithm (SAM) is used for the classification of many studies using high resolution satellite data. In the present paper, we propose to apply the SAM algorithm to the moderate resolution of the NOAA AVHRR sensor data for classifying the vegetation cover. This study allows also exploiting other classification methods for the low resolution. First, the normalized difference vegetation index (NDVI) is extracted from two channels 1 and 2 of the AVHRR sensor. In order to obtain an initial density representation of vegetal formation distribution, a methodology, based on the combination between the threshold method and the decision tree, is used. This combination is carried out due to the lack of accurate data related to the thresholds that delimit each class. In a second time, and based on spectral behavior, a vegetation cover map is developed using SAM algorithm. Finally, with the use of low resolution satellite images (NOAA AVHRR) and with only two channels, it is possible to identify the most dominant species in North Africa such as: forests of the Liege oaks, other forests, cereal’s cultivation, steppes and bar soil.     

GPS scintillation and TEC depletion near the northern crest of equatorial anomaly over South China

This study presents a statistical analysis of GPS L-band scintillation with data observed from July 2008 to March 2012 at the northern crest of equatorial anomaly stations in Guangzhou and Shenzhen of South China. The variations of the scintillation with local time, season, solar activity and duration of scintillation patches were investigated. The relationship between the scintillation and TEC depletion was also reported. Our results revealed that GPS scintillation occurred from 19:30 LT (pre-midnight) to 03:00 LT (post-midnight). During quiet solar activity years, the scintillation was only observed in pre-midnight hours of equinox months and patches durations were mostly less than 60 min. During high solar activity years, more scintillation occurred in the pre-midnight hours of equinox and winter months; and GPS scintillation started to occur in the post-midnight hours of summer and winter. The duration of scintillation patches extended to 180 min in high solar activity years. Solar activity had a larger effect to strong scintillations (S₄ > 0.6) than to weak scintillations (0.6 ? S₄ > 0.2). Strong scintillations were accompanied by TEC depletion especially in equinox months. We also discussed the relationship between TEC depletion and plasma bubble.     

Rainfall estimation over a Mediterranean region using a method based on various spectral parameters of SEVIRI-MSG

The ultimate objective of this paper is the estimation of rainfall over an area in Algeria using data from the SEVIRI radiometer (Spinning Enhanced Visible and Infrared Imager). To achieve this aim, we use a new Convective/Stratiform Rain Area Delineation Technique (CS-RADT). The satellite rainfall retrieval technique is based on various spectral parameters of SEVIRI that express microphysical and optical cloud properties. It uses a multispectral thresholding technique to distinguish between stratiform and convective clouds. This technique (CS-RADT) is applied to the complex situation of the Mediterranean climate of this region. The tests have been conducted during the rainy seasons of 2006/2007 and 2010/2011 where stratiform and convective precipitation is recorded. The developed scheme (CS-RADT) is calibrated by instantaneous meteorological radar data to determine thresholds, and then rain rates are assigned to each cloud type by using radar and rain gauge data. These calibration data are collocated with SEVIRI data in time and space.     

基于单片机AT89S52热导检测器及其信号仿真研究

随着石油、化工、冶金、生物等领域的飞速发展,对物质成份进行定性和定量分析的要求更加严格.在气相色谱仪中采用热导检测器(TCD)检测物质成份的浓度变化,具有构造简单、测定范围广、稳定性好、线性范围宽等优点.针对基于单片机AT89S52热导检测器的各单元进行了分析与设计,并采用ISIS软件对由铼钨丝构成的惠斯顿电桥信号进行了仿真.最后,对影响热导检测器灵敏度的原因和热导检测器常见故障进行了分析.     

Study of the ionosphere during a magnetospheric storm using data on the ground and in space

For the magnetospheric storm of May 14–16, 1997 geophysical data of satellites DMSP and IMP-8 are compared with data of radio propagation on the high-latitude HF radio path of Heiss Island – St. Petersburg and data from European ionosondes. Peculiarities of variations of the operational frequencies range MOF–LOF (maximum and lowest observed frequencies) on the path were considered. The range has been determined by the method of oblique ionospheric sounding (OIS). The latter is more informative for observations during a magnetic storm compared to the vertical sounding method. Nevertheless, an analysis of variations of the critical frequency of the ionospheric F2 layer from the chain of European ionosondes was carried out. For interpretation of results, data of magnetospheric parameters, AE-indexes and riometer data were used. The variations of both frequency range on the path and critical frequencies of the F2 layer through the ionosondes chain during the disturbed period had certain regularities of behaviour. These regularities are being explained from the physical point of view. The analysis of the satellite DMSP data has showed that a magnetospheric disturbance causes displacement equatorward of precipitation and some growth of its width and energy.     

First observation of upper mesospheric semi annual oscillations using ground based airglow measurements from Indian low latitudes

We summarize two years of Mesosphere Lower Thermosphere Photometer (MLTP) operation of mesospheric OH and O₂ emission monitoring. The deduced mesospheric OH and O₂ temperatures show large variability. Nightly temperature variations over Gadanki (13.5°N, 79.2°E) are dominated by the short period wave features, while tidal amplitudes are relatively small. Our measurements are the first to report a long period seasonal variation at two upper mesospheric altitudes simultaneously over the Indian sector. Our observations reveal the presence of a dominant semi-annual oscillation (∼6 months periodicity) together with a shorter period (∼2.5  months periodicity) oscillation in both OH and O₂ data.