Studies on urine treatment by biological purification using Azolla and UV photocatalytic oxidation

The amount of water consumed in space station operations is very large. In order to reduce the amount of water which must be resupplied from Earth, the space station needs to resolve the problems of water supply. For this reason, the recovery, regeneration and utilization of urine of astronauts are of key importance. Many investigations on this subject have been reported. Our research is based on biological absorption and, purification using UV photocatalytic oxidation techniques to achieve comprehensive treatment for urine. In the treatment apparatus we created, the urine solution is used as part of the nutrient solution for the biological components in our bioregenerative life support system. After being absorbed, the nutrients from the urine were then decomposed, metabolized and purified which creates a favorable condition for the follow-up oxidation treatment by UV photocatalytic oxidation. After these two processes, the treated urine solution reached Chinese national standards for drinking water quality (GB5749-1985).     

Status and progress in on-line spectrometric monitoring and control of plant nutrient solutions.

Biotronics has been involved, under NASA sponsorship, in a wide ranging research and development program for instrumentation used in the monitoring and control of controlled environment agriculture. This program has embraced both chemical monitoring of plant nutrient solutions as well as microbiological monitoring of bacteria and fungi in these same solutions. This paper emphasizes the microbiological monitoring aspects of this program. In contrast to traditional methods of microbiological analysis based on culturing, staining and microscopic observation, the development described here is based on spectroscopic measurements, more specifically spectral fluorometry. The rationale, objectives, analytical methods and new instrumentation employed in the development of an on-line microbiological analyzer (MBA) are presented in some detail. Finally, the signal processing/pattern recognition methods used to evaluate the spectral data and produce estimates of microbial populations are described along with experimental test results to conclude the paper.     

Integration of waste processing and biomass production systems as part of the KSC Breadboard project.

After initial emphasis on large-scale baseline crop tests, the Kennedy Space Center (KSC) Breadboard project has begun to evaluate long-term operation of the biomass production system with increasing material closure. Our goal is to define the minimum biological processing necessary to make waste streams compatible with plant growth in hydroponic systems, thereby recycling nutrients into plant biomass and recovering water via atmospheric condensate. Initial small and intermediate-scale studies focused on the recycling of nutrients contained in inedible plant biomass. Studies conducted between 1989-1992 indicated that the majority of nutrients could be rapidly solubilized in water, but the direct use of this crop "leachate" was deleterious to plant growth due to the presence of soluble organic compounds. Subsequent studies at both the intermediate scale and in the large-scale Biomass Production Chamber (BPC) have indicated that aerobic microbiological processing of crop residue prior to incorporation into recirculating hydroponic solutions eliminated any phytotoxic effect, even when the majority of the plant nutrient demand was provided from recycled biomass during long term studies (i.e. up to 418 days). Current and future studies are focused on optimizing biological processing of both plant and human waste streams.     

Density and composition of microorganisms during long-term (418 day) growth of potato using biologically reclaimed nutrients from inedible plant biomass.

A study evaluating alternative methods for long term operation of biomass production systems was recently completed at the Kennedy Space Center (KSC). The 418-day study evaluated repeated batch versus mixed-aged production of potato grown on either standard 1/2-strength Hoagland's nutrient solution or solutions including nutrients recycled from inedible plant material. The long term effects of closure and recycling on microbial dynamics were evaluated by monitoring the microbial communities associated with various habitats within the plant growth system (i.e., plant roots, nutrient solution, biofilms within the hydroponic systems, atmosphere, and atmospheric condensate). Plate count methods were used to enumerate and characterize microorganisms. Microscopic staining methods were used to estunate total cell densities. The primary finding was that the density and composition of microbial communities associated with controlled environmental plant growth systems are stable during long term operation. Continuous production resulted in slightly greater stability. Nutrient recycling, despite the addition of soluble organic material from the waste processing system, did not significantly increase microbial density in any of the habitats.     

Absorption and vibrational spectra of methylamine and its ions using quantum chemical methods

We present vibrational spectra of methylamine and its ions using the MP2 method and absorption spectra using time dependent density functional method. On the basis of these calculations electronic transitions of methylamine were successfully determined. We also have derived electron affinity and ionization potential for methylamine. The ionization potential 8.98 eV from this work is in excellent agreement with the experimental value of 9.04 eV. We found that like neutral methylamine, its cation also displays strong σ → σ∗ electronic transitions in the vacuum UV region whereas its anion shows strong electronic transitions in both the vacuum and far UV regions. The detection of methylamine in astronomical objects may benefit greatly from the accurate new data on its far-UV and near-IR lines.     

光学原位法探针测量超低减排烟气

随着燃煤电厂超低减排的开展,烟气监测技术的要求也越来越严格。研制了应用差分光学吸收光谱(DOAS)和多波长消光的实时在线烟气监测探针,可同时对SO_2、烟尘等浓度进行监测。并在实验室进行了标定,SO_2浓度及烟尘反演误差均小于10%,不同浓度SO_2反演浓度曲线线性度好,线性相关系数为0.999 64。利用该系统对某燃煤电厂烟气中的SO_2和液滴颗粒物进行了现场监测。结果表明:该系统对SO_2、液滴颗粒的监测结果与锅炉运行工况、实际运行状况吻合。     

一种用于CPT原子频标的高性能解调电路

介绍了同步积分器和相敏检波器级联的解调电路及该电路在相干布居囚禁（CPT）原子频标中的应用。通过理论计算和先进设计系统软件进行的仿真表明,该解调电路具有很高的Q值和很好的抑制噪声能力,是一种可应用于CPT原子频标的解调电路。对电路的测试结果证实,该电路能够从光检测信号中解调出高性能的用于激光频率稳频的多普勒吸收谱线的微分曲线和用于微波频率稳频的CPT谱线的微分曲线。     

Use of biologically reclaimed minerals for continuous hydroponic potato production in a CELSS.

Plant-derived nutrients were successfully recycled in a Controlled Ecological Life Support System (CELSS) using biological methods. The majority of the essential nutrients were recovered by microbiologically treating the plant biomass in an aerobic bioreactor. Liquid effluent containing the nutrients was then returned to the biomass production component via a recirculating hydroponic system. Potato (Solanum tuberosum L.) cv. Norland plants were grown on those nutrients in either a batch production mode (same age plants on a nutrient solution) or a staggered production mode (4 different ages of plants on a nutrient solution). The study continued over a period of 418 days, within NASA Breadboard Project's Biomass Production Chamber at the Kennedy Space Center. During this period, four consecutive batch cycles (104-day harvests) and 13 consecutive staggered cycles (26-day harvests) were completed using reclaimed minerals and compared to plants grown with standard nutrient solutions. All nutrient solutions were continually recirculated during the entire 418 day study. In general, tuber yields with reclaimed minerals were within 10% of control solutions. Contaminants, such as sodium and recalcitrant organics tended to increase over time in solutions containing reclaimed minerals, however tuber composition was comparable to tubers grown in the control solutions.     

A review of recent results on cosmic gamma-ray bursts

The results obtained on cosmic gamma-ray bursts over the last several years are reviewed and compared with the older “historical” results. Fine time resolution measurements of burster light curves continue to reveal structure at the millisecond and sub-millisecond level, suggesting a compact object origin. Similarly, the evolution of the low energy X-ray spectra of bursts towards shapes consistent with 1–2 keV blackbodies may be interpreted in terms of a neutron star origin, as can the continuing detection of absorption and emission features. The statistical evidence, however, argues strongly for an isotropic distribution which has been completely sampled. To reconcile this with galactic neutron stars requires the assumption that they are Population II objects. Counterpart searches have evolved to the point where they may be carried out within days of an event, and a soft X-ray source has now been detected in the error box of one recent burst.     

New problems to be solved for establishing closed life support system.

New test bed facilities such as Bioplex and CEEF have been constructed to test the new advanced technologies for solving the various problems as follows, (1) how to develop air content stabilization technologies with gas balance between the generation and the absorption by living organisms, (2) how to solve the mismatching between the assimilation rate of autotrophic organisms and the respiration rate of heterotrophic organisms, (3) how to balance the speed of the waste decomposition with the absorption speed of nutrient components in the sequential plant cultivation, (4) how to develop new nutrient adjusting subsystems for each plant species, (5) how to compensate the denitrification during the waste decomposition and anaerobic microbes in the nutrient solution.     

基于TDLAS的气体检测技术研究

TDLAS技术由于其非接触性、高灵敏度、在线响应速度快等优点,而成为当前气体浓度在线检测技术的重要发展方向之一。确定分子吸收线型函数是应用该技术的前提条件,但是目前尚没有有效的方法在线测量分子吸收线型函数,以至严重影响了TDLAS技术的测量精度,限制了其应用范围。因此,通过吸收光谱理论和波长调制理论研究TDLAS技术中谐波特征参数与分子吸收线型函数的关系,推导出蕴含分子吸收信息的谐波通项表达式,利用谐波信号间的关系特征来消除背景信号、激光强度、调制系数等因素的影响,建立了一种基于谐波信号的绝对吸收强度测量算法。以CO₂分子和H₂O分子在6982cm^-1附近的谱线为例进行数值分析和实验研究,仿真和实验结果表明,根据算法测得的分子吸收光谐波信号谱与理论吸收光谱之间的相对误差不超过5%,进一步提高了TDLAS技术的测量精度,拓宽了其应用范围。     

基于TDLAS的气体检测技术研究

TDLAS技术由于其非接触性、高灵敏度、在线响应速度快等优点,而成为当前气体浓度在线检测技术的重要发展方向之一。确定分子吸收线型函数是应用该技术的前提条件,但是目前尚没有有效的方法在线测量分子吸收线型函数,以至严重影响了TDLAS技术的测量精度,限制了其应用范围。因此,通过吸收光谱理论和波长调制理论研究TDLAS技术中谐波特征参数与分子吸收线型函数的关系,推导出蕴含分子吸收信息的谐波通项表达式,利用谐波信号间的关系特征来消除背景信号、激光强度、调制系数等因素的影响,建立了一种基于谐波信号的绝对吸收强度测量算法。以CO2分子和H2O分子在6982cm-1附近的谱线为例进行数值分析和实验研究,仿真和实验结果表明,根据算法测得的分子吸收光谐波信号谱与理论吸收光谱之间的相对误差不超过5%,进一步提高了TDLAS技术的测量精度,拓宽了其应用范围。     

XANES analysis of organic residues produced from the UV irradiation of astrophysical ice analogs

Organic residues formed in the laboratory from the ultraviolet (UV) photo-irradiation or ion bombardment of astrophysical ice analogs have been extensively studied for the last 15 years with a broad suite of techniques, including infrared (IR) and UV spectroscopies, as well as mass spectrometry. Analyses of these materials show that they consist of complex mixtures of organic compounds stable at room temperature, mostly soluble, that have not been fully characterized. However, the hydrolysis products of these residues have been partly identified using chromatography techniques, which indicate that they contain molecular precursors of prebiotic interest such as amino acids, nitrile-bearing compounds, and amphiphilic compounds. In this study, we present the first X-ray absorption near-edge structure (XANES) spectroscopy measurements of three organic residues made from the UV irradiation of ices having different starting compositions. XANES spectra confirm the presence of different chemical functions in these residues, and indicate that they are rich in nitrogen- and oxygen-bearing species. These data can be compared with XANES measurements of extraterrestrial materials. Finally, this study also shows how soft X rays can alter the chemical composition of samples.     

The role of stars in the energetics of LINERs

Imaging studies have shown that ∼ 25% of LINER galaxies display a compact nuclear UV source. I compare the HST ultraviolet (1150–3200 Å) spectra that are now available for seven such “UV-bright” LINERs. The spectra of NGC 404, NGC 4569, and NGC 5055 show clear absorption-line signatures of massive stars, indicating a stellar origin for the UV continuum. Similar features are probably present in NGC 6500. The same stellar signatures may be present but undetectable in NGC 4594, due to the low signal-to-noise ratio of the spectrum, and in M81 and NGC 4579, due to superposed strong, broad emission lines. The compact central UV continuum source that is observed in these galaxies is a nuclear star cluster rather than a low-luminosity active galactic nucleus (AGN), at least in some cases. At least four of the LINERs suffer from an ionizing photon deficit, in the sense that the ionizing photon flux inferred from the observed far-UV continuum is insufficient to drive the optical H I recombination lines. Examination of the nuclear X-ray flux of each galaxy shows a high X-ray UV ratio in the four “UV-photon starved” LINERs. In these four objects, a separate component, emitting predominantly in the extreme-UV, is the likely ionizing agent, and is perhaps unrelated to the observed nuclear UV emission. Future observations can determine whether the UV continuum in LINERs is always dominated by a starburst or, alternatively, that there are two types of UV-bright LINERs: starburst-dominated and AGN-dominated. Interestingly, recent results show that starbursts dominate the nuclear energetics in many Seyfert 2s as well.     

ROSAT PSPC spectra of six Seyfert 1 galaxies

We present six ROSAT PSPC observations of Seyfert 1 galaxies chosen to have low Galactic line-of-sight absorption (N_H 10²⁰ cm⁻²). As expected, it is found that all of these sources possess significantly steeper spectra below 1 keV, than that observed at higher X-ray energies. In addition we find evidence for soft X-ray spectral features, which are best parameterized as line emission at 0.63 keV in NGC7469 and 0.75 keV in ESO198-G24. We examine these results in the light of the accuracy of the PSPC spectral calibration.     

Novel sensor technology for monitoring and control of critical plant nutrient parameters.

A novel dielectric sensor technology has been developed for monitoring and control of plant nutrient delivery systems as part of NASA's Controlled Ecological Life Support System (CELSS) program. A unique measurement phenomenon was discovered in which the electrostatic field is shunted to a third terminal of the sensor, resulting in a much greater sensitivity to changes in the complex dielectric properties of the nutrient solution. Based on this phenomenon, a small, flexible, thin-film shunting dielectric sensor (SDS) was designed to provide low-frequency, non-invasive measurement of both the thickness and nutrient concentration of the layer of solution on a plant growth surface. Test results indicate a sensitivity of +/- 0.05mm in layer thickness while characterization of the ability to measure nutrient concentration continues. The development plan for this sensor is presented and other applications are discussed.     

Recycling of inorganic nutrients for hydroponic crop production following incineration of inedible biomass.

The goal of resource recovery in a regenerative life support system is maintenance of product quality to sure support of reliable and predictable levels of life support function performance by the crop plant component. Further, these systems must be maintained over extended periods of time, requiring maintenance of nutrient solutions to avoid toxicity and deficiencies. The focus of this study was to determine the suitability of the ash product following incineration of inedible biomass as a source of inorganic nutrients for hydroponic crop production. Inedible wheat biomass was incinerated and ash quality characterized. The incinerator ash was dissolved in adequate nitric acid to establish a consistent nitrogen concentration is all nutrient solution treatments. Four experimental nutrient treatments were included: control, ash only, ash supplemented to match the control treatment, and ash only quality formulated with reagent grade chemicals. When nutrient solutions were formulated using only ash following incineration of inedible biomass, a balance in solution is established representing elemental retention following incineration and nutrient proportions present in the original biomass. The resulting solution is not identical to the control. This imbalance resulted in a suppression of crop growth. When the ash is supplemented with reagent grade chemicals to establish the same balance as in the control--growth is identical to the control. The ash appears to carry no phytotoxic materials. Growth in solution formulated with reagent grade chemicals but matching the quality of the ash only treatment resulted in similar growth to that of the ash only treatment. The ash product resulting from incineration of inedible biomass appears to be a suitable form for recycle of inorganic nutrients to crop production.     

Einstein observations of hot stars

Surveys with instruments on the $\text{Einstein Observatory}$ have shown that essentially all 0 and B main sequence stars are X-ray sources as are many, if not all, 0B supergiants and Wolf-Rayet stars. The X-ray luminosities are sufficient to explain broad lines from the superionization stages seen in the UV spectra of the stars. High energy resolution spectra from the Solid State Spectrometer are shown to place severe constraints on various models for the location of the X-ray sources in the outer atmospheres of the stars. Coronal and embedded shock models for the X-ray emission are discussed and each is found to have some problems in explaining the X-ray emission of 0B stars. X-ray line emission of Si XIII and S XV in ? Ori is discussed and interpreted as arising from magnetically confined loops.     

Optical chemical sensors for environmental control and system management.

Several fiber optic based chemical sensors have been developed for use in plant growth systems and enclosed life support systems. Optical chemical sensors offer several distinct advantages in terms of sensitivity, calibration stability, immunity to biofouling and electrical interference, and ease of multiplexing sensors for multipoint/multiparameter analysis. Also, the ability to locate fiber optic sensors in close proximity to plant roots or leaves should improve the measurement reliability by obviating the need for handling and transport which can compromise sample integrity. Polestar Technologies and GEO-CENTERS have developed and tested many types of optical chemical sensors which utilize novel glass and polymeric materials as the sensor substrate. Analytes are detected using immobilized colorimetric indication systems or molecular recognition elements. Typically transduction is via wavelength specific absorption changes with multiwavelength detection for drift compensation. Sensors have been developed for solution pH, NH3, ethylene, CO2, and dissolved metal ions. In addition, unique PC-compatible optoelectronic interfaces, as well as distributed measurement systems, so that integrated detection systems are now available. In this paper recent efforts to develop sensors for critical nutrient ions are presented.     

The manifestation of seismic activity in 557.7 nm emission variations of the earth's upper atmosphere

For the Baikal seismic zone (East Siberia region, 52°N, 103°E) the Earth's upper atmosphere radiation parameters were analysed for 557.7 nm emission line of atomic oxygen [OI] (de-excitation heights 85–115 km) during earthquakes. The analysis revealed an increase in mean night-time 557.7 nm emission intensities prior to earthquakes, with a decrease in intensities during post-earthquake days. Preliminary results of a spectral analysis suggest possible changes in spectra (from a few to tens of minutes) of 557.7 nm emission prior to and after earthquakes. The results are compared with those obtained for the earthquakes in the Central Asian region.