Development of a long cycle life sealed nickel-zinc battery forhigh energy-density applications

Nickel-zinc battery technology is being developed for commercial applications requiring high energy density and high power capability. Development cells have demonstrated the ability to deliver over 60 Watt-hours per kilogram at the one hour rate. Cycle life has been improved to more than 600 cycles at 80% depth of discharge by using a patented, reduced solubility zinc electrode and an improved sealed cell design. More than 8000 charge/discharge cycles at 10% depth-of-discharge have been completed. Large quantities of sealed prismatic cells have been manufactured, including a 140 cell, 220 V battery for a hybrid electric vehicle (HEV)     

Advanced developments in NiH2 Dependent Pressure Vessel(DPV) cell and battery technology

The Dependent Pressure Vessel (DPV) Nickel-Hydrogen (NiH₂ ) design is being developed by Eagle-Picher Industries, Inc. (EPI) as an advanced battery for military and commercial, aerospace and terrestrial applications. The DPV cell design offers high specific energy and energy density as well as reduced cost, while retaining the established Individual Pressure Vessel (IPV) technology flight heritage and database. This advanced DPV design also offers a more efficient mechanical, electrical and thermal cell and battery configuration and a reduced parts count. The DPV battery design promotes compact, minimum volume packaging and weight efficiency, and delivers cost and weight savings with minimal design risks     

A nickel/hydrogen battery for PV systems

The nickel-hydrogen battery, developed in the early nineteen-seventies as an energy-storage subsystem for commercial communication satellites, is discussed. The advantages offered by nickel-hydrogen batteries, including long life, low maintenance and high reliability, make it very attractive for terrestrial applications such as stand-alone photovoltaic systems. The major drawback to the wider use of the nickel-hydrogen battery is its high initial cost. A 7-kWh battery has been on test since January 1988 using a flat-plate photovoltaic array for charging. The cell, battery design and test methods are briefly described, and the results of cycling and solar tests are presented. It is concluded that the battery is well suited for remote solar applications     

The Hy-StorTM battery

The Hy-Stor^TM Battery is a rechargeable battery being developed for electric vehicles and other large battery applications. The battery combines the high energy storage capability of metal hydride alloys with the high cycle life and discharge rate capabilities of nickel-hydrogen cells. It is a hybrid battery concept that offers potential performance, economic and safety advantages over other large battery technologies. Very recent developments indicate that much smaller batteries can also be produced to meet the needs of the portable computer and other portable electronic device markets. Initial tests demonstrated the ability of a metal hydride storage system to achieve high cycle life when absorbing hydrogen that was saturated with battery electrolyte solution and then passed through a purifier. Based on positive test results, a patent for the Hy-Stor battery was applied for and granted     

Prediction of electric-powered fixed-wing UAV endurance

To overcome the problems encountered in predicting the endurance of electricpowered fixed-wing unmanned aerial vehicles (UAVs),which were stemmed from the dynamic changes in electric power system efficiency and battery discharge characteristics under different operating conditions,the required battery power model and battery discharge model were studied.The required battery power model was determined using an approximate model of electric power system efficiency based on wind tunnel testing and the self-adaptive penalty function.Furthermore,current correction and ambient temperature correction terms were proposed for the trained Kriging model representing the discharge characteristics under standard operation,and then the discharged capacity-terminal voltage model was established.Through numerical integration of this model with the required battery power model,the electric-powered fixed-wing UAV endurance prediction model was obtained.Laboratory tests indicated that the proposed endurance model could precisely calculate the battery discharge time and accurately describe the battery discharge process.The similarity of the theoretical and flight test results reflected the accuracy of the proposed endurance model as well as the importance of considering dynamic changes in power system efficiency in endurance calculations.The proposed endurance model meeting precision requirements can be used in practical engineering applications.     

Bipolar nickel-metal hydride battery for hybrid vehicles

Hybrid electric vehicles are receiving increased interest as an approach to decrease vehicle pollution, dependence, and consumption of liquid petroleum and meet forthcoming Government vehicle emission standards. A number of schemes are under consideration (heat engine battery, fuel cell battery, peaking battery, inner-city battery, etc.). The success of any of the approaches will be dependent on battery capabilities, i.e., power, density, life, and cost. The nickel-metal hydride system appears to be the most promising of the candidate battery chemistries. Preliminary designs and analysis have been prepared and are presented for various configurations. Initial performance characterization tests are presented. It is concluded that a bipolar package arrangement for the Ni-MH chemistry appears most suited for the hybrid vehicle application considered     

Demonstration of a zinc bromine battery in an electric vehicle

The zinc bromine battery is a high energy density battery that utilizes low cost materials. The battery is of unique construction utilizing plastic storage tanks for the zinc bromide electrolyte and plastic bipolar electrode stacks. This paper briefly describes the zinc bromine battery technology and the experience gained in installing and operating an electric vehicle with this advanced system. The described electric vehicle (The “T-Star”) was tested in March 1993 on the Chrysler Proving Grounds in Phoenix, Arizona and it participated in the May 1993 American Tour de Sol capturing second place over all and first place in the student division     

富锂锰基正极材料研究进展

随着社会发展,电动汽车、消费类(3C)电子产品、储能装置等对锂离子电池的能量密度提出了更高要求。富锂锰基正极材料具有高比容量(≈250 mAh/g)、高工作电压(≈3.6 V)及低成本等优势,有望成为下一代商用高比能电池正极材料。首次库仑效率低、倍率性能差、电压/容量衰减快等问题限制了富锂锰基正极材料的工程化应用。本文综述了富锂锰基正极材料的最新研究进展,重点从材料结构、电化学反应机理、失效机制和改性方法等几方面进行了阐述。研究表明,采用离子掺杂、表面包覆、晶体结构调控等技术,可显著改善富锂锰基正极材料的电化学性能。最后,对富锂锰基正极材料的发展方向进行了展望。     

Safety testing of lithium ion batteries for navy devices

Lithium ion battery technology is being introduced into power supplies used by our armed forces for a variety of applications. In many cases, the same cells and design parameters that support commercial battery packs are being used in military battery packs. This approach is expected to result in a major decrease in the total life cycle cost of the equipment these batteries support. On June 13, 1991, NAVSEA issued INST9310.1B1, which states that all lithium battery powered equipment must undergo safety evaluation and approval prior to fleet use. This safety program governs a process whereby approvals are issued for lithium batteries to be used in specific equipment on ground facilities, surface combatants, air combatants, and/or submarines. The Naval Ordnance Safety and Security Activity (NOSSA) manages the program. The chief technical advisors are Code 644 at NSWC Carderock Division and Code 609A at NSWC Crane Division. This paper describes three battery designs that incorporate lithium ion technology, and the results of battery safety tests conducted in accordance with navy requirements.     

Performance characteristics of lithium-ion cells for NASA's Mars2001 Lander application

NASA requires lightweight rechargeable batteries for future missions to Mars and the outer planets that are capable of operating over a wide range of temperatures, with high specific energy and energy densities. Due to the attractive performance characteristics, lithium-ion batteries have been identified as the battery chemistry of choice for a number of future applications, including Mars rovers and landers. The Mars 2001 Lander (Mars Surveyor Program MSP 01) will be one of the first missions which will utilize lithium-ion technology. This application will require two lithium-ion batteries, each being 28 V (eight cells), 25 Ah and 8 kg. In addition to the requirement of being able to supply at least 200 cycles and 90 days of operation on the surface of Mars, the battery must be capable of operation (both charge and discharge) at temperatures as low as -20°C. To assess the viability of lithium-ion cells for these applications, a number of performance characterization tests have been performed, including: assessing the room temperature cycle life, low temperature cycle life (-20°C), rate capability as a function of temperature, pulse capability, self-discharge and storage characteristics, as well as mission profile capability. This paper describes the Mars 2001 Lander mission battery requirements and contains results of the cell testing conducted to-date in support of the mission,     

Bipolar nickel-metal hydride batteries for aerospace applications

Electro Energy Inc. (EEI) is developing high power, long life, bipolar nickel-metal hydride batteries for aerospace applications. Bipolar nickel-metal hydride designs allow for high energy and high power designs with a 25 percent reduction in both weight and volume as compared to prismatic and/or cylindrical Ni-MH designs. Utilizing a sealed wafer cell design EEI has demonstrated a 1.2 kW/kg power capability. Prototype designs have achieved 70 Wh/kg. Designs studies show 80 Wh/kg are achievable with EEI's state-of-the-art technology. The sealed wafer cell is the building block for EEI's high power and high voltage bipolar batteries making the assembly easy and significantly lower in cost. Satellite and aircraft batteries are being developed which provide high power and long life. Sealed cells now show excellent rate capability and life. Cells tested in a low earth orbit (LEO) cycle have reached 9000 cycles and continue on test. High power, bipolar battery designs are ideal in applications where using conventional aerospace battery technology would require excessive capacity; weight and volume, thereby reducing usable payload on the vehicle     

Five-year update: nickel hydrogen industry survey

A 1984 survey of the nickel hydrogen (NiH₂) battery industry is updated. Late 1980s and early 1990s issues are identified, and usage and testing results of the survey are summarized. NiH₂ is the system of choice for new geosynchronous-earth-orbit (GEO) satellites and is being seriously considered for low-earth-orbit (LEO) applications. In five years, the annual cell production rate has doubled from approximately 1000 to 2000 cells. A number of cells under test have exceeded 20000 cycles at 40% DOD in LEO regimes, while other cells have achieved over 35 seasons in accelerated GEO regimes. The LEO database clearly indicates that NiH₂ performance is at least as good as the best conventional nickel-cadmium performance demonstrated under test     

Making batteries last longer [for electric vehicles]

The early 1900's era of electric cars ended because the batteries didn't last long enough, and a new gasoline-engine-powered car cost less than a replacement battery. Long-life batteries are the key to achieving a low life-cycle cost for the electric vehicles that will help solve the air-pollution problem in our cities. New ways of making batteries last longer are discussed     

Battery package design optimization for small electric aircraft

The increasing gross weight of electric Unmanned Aerial Vehicle (UAV) poses a challenge in practical applications. The range and endurance of the electric UAV are limited by the fixed mass of the battery package. In this work, a design optimization method for the battery package topology of small electric UAV is proposed to enhance the performance. To improve the accuracy of the method, the dynamic battery model and simplified electric component models are presented. These models are utilized by the trajectory optimization method, which takes the dynamic characteristic into consideration to calculate the aircraft performance. The direct optimal control method is used for solving the trajectory optimization problem, and this method is tested on a small blended-wing-body electric aircraft. The test result shows that the range and energy-consumption are mainly influenced by the parallel topology of the battery package, while the flight time in climb phase is more sensitive to the series topology. It is deduced that the range- and energy-optimal design points can be considered concurrently in design optimization. The work proves the feasibility of integrating the trajectory optimization and battery package design.     

新能源电动飞机发展与挑战

发展绿色航空是人类社会形成的基本共识,新能源电动飞机为实现彻底的绿色航空提供了一条光明的技术途径。简述了航空对环境的影响、电在飞机上的应用及电动飞机的发展历程,对新能源电动飞机的能源分类、电推进系统及其总体效率进行了研究,重点针对载人轻型运动飞机,分析了电动飞机的发展现状、特征以及能源需求,通过对电池作为能源的载人电动飞机的航程和极限航程研究,提出了电池能量密度提升和性能改进、高升阻比空气动力设计、低成本轻质高效复合材料结构设计与制造、高效率电推进系统设计与集成等电动飞机发展面临的挑战,给出了应大力发展电动飞机的建议和本领域未来的研究方向。     

天翼1无人机电动化改造可行性分析

电动飞机正在国内外通用航空领域蓬勃发展,并影响着未来航空的发展方向。利用电推进技术对无人机进行电动化改造,能大大提高无人机的安全性、可靠性和维修性,降低使用成本。以天翼1无人机为电动化改造对象,提出了电动化改造方案,详细计算分析了电推进系统中电动机和锂电池组的主要参数,并从无人机的重量重心、性能以及电推进系统的安装方式等方面分析了改造的可行性。分析结果表明,天翼1无人机电动化改造基本可行;并提出了后续改造实施中需注意的问题。     

Advanced materials for next generation NiMH portable, HEV and EVbatteries

While Ovonic NiMH batteries are already in high volume commercial production for portable applications, advances in materials technology have enabled performance improvements in specific energy (100 Wh/kg), specific power (600-1000 W/kg), high temperature operation, charge retention, and voltage stability. Concurrent with technology advances, Ovonic NiMH batteries have established performance and commercial milestones in electric vehicles, hybrid electric vehicles, as well as scooter, motorcycle and bicycle applications. As important as these advances, significant manufacturing cost reductions have also occurred which allow continued growth of NiMH technology. In this paper, advances in performance, applications and cost reduction are discussed with particular emphasis on the improved proprietary metal hydride and nickel hydroxide materials that make such advances possible     

FEL system for energy transmission

The use of a free electron laser (FEL) as the power source for transmission from Earth stations to space assets is discussed. Considerations of requirements including net power transmitted, system reliability, system availability, cost, and technical maturity are addressed to determine a reasonable development path to an optimal system. Various applications of transmitted power are examined such as supplementary power to communications satellites, orbit raising through the use of electric and thermal thrusters, supplementary power to manned orbiters and space stations. It is seen that each of these applications leads to different stages of infrastructure development, and that a program following a near optimal development path can lead to a system that has justifiable investments for the services delivered at each stage past the initial technology demonstration     

Heating and cooling battery electric vehicles-the final barrier

Battery electric vehicles (EVs) present a particular challenge to the development of more efficient and effective heating and cooling systems for automotive applications. Because heating-ventilating-air-conditioning (HVAC) systems are electrically powered, vehicle range is reduced when the HVAC system is operating. The alternative solutions to HVAC battery electric vehicles are identified and evaluated. These include a basis for determining HVAC boundary design assumptions and showing mathematical methods for estimating the HVAC load and energy requirements, and evaluation of the new European and Japanese approaches to wintertime heating, such as NaS battery, motor and component waste heat recovery, electric seat warmer, radiant foot warmer, electric windshield and backlight defrost, molten salt latent heat storage, metal hydride hydrogen storage and catalytic heater, and liquid fueled heater     

Electric-vehicle batteries

Electric vehicles that can't reach trolley wires need batteries. In the early 1900's electric cars disappeared when owners found that replacing the car's worn-out lead-acid battery costs more than a new gasoline-powered car. Most of today's electric cars are still propelled by lead-acid batteries. General Motors in their prototype Impact, for example, used starting-lighting-ignition batteries, which deliver lots of power for demonstrations, but have a life of less than 100 deep discharges. Now promising alternative technology has challenged the world-wide lead miners, refiners, and battery makers into forming a consortium that sponsors research into making better lead-acid batteries. Horizon's new bipolar battery delivered 50 watt-hours per kg (Wh/kg), compared with 20 for ordinary transport-vehicle batteries. The alternatives are delivering from 80 Wh/kg (nickel-metal hydride) up to 200 Wh/kg (zinc-bromine). A Fiat Panda traveled 260 km on a single charge of its zinc-bromine battery. A German 3.5-ton postal truck traveled 300 km with a single charge in its 650-kg (146 Wh/kg) zinc-air battery. Its top speed was 110 km per hour