XANES analysis of organic residues produced from the UV irradiation of astrophysical ice analogs

Organic residues formed in the laboratory from the ultraviolet (UV) photo-irradiation or ion bombardment of astrophysical ice analogs have been extensively studied for the last 15 years with a broad suite of techniques, including infrared (IR) and UV spectroscopies, as well as mass spectrometry. Analyses of these materials show that they consist of complex mixtures of organic compounds stable at room temperature, mostly soluble, that have not been fully characterized. However, the hydrolysis products of these residues have been partly identified using chromatography techniques, which indicate that they contain molecular precursors of prebiotic interest such as amino acids, nitrile-bearing compounds, and amphiphilic compounds. In this study, we present the first X-ray absorption near-edge structure (XANES) spectroscopy measurements of three organic residues made from the UV irradiation of ices having different starting compositions. XANES spectra confirm the presence of different chemical functions in these residues, and indicate that they are rich in nitrogen- and oxygen-bearing species. These data can be compared with XANES measurements of extraterrestrial materials. Finally, this study also shows how soft X rays can alter the chemical composition of samples.     

Primary mass discrimination of high energy cosmic rays using PNN and k-NN methods

Probabilistic neural network (PNN) and k-Nearest Neighbors (k-NN) methods are widely used data classification techniques. In this paper, these two methods have been used to classify the Extensive Air Shower (EAS) data sets which were simulated using the CORSIKA code for three primary cosmic rays. The primaries are proton, oxygen and iron nuclei at energies of 100?TeV–10?PeV. This study is performed in the following of the investigations into the primary cosmic ray mass sensitive observables. We propose a new approach for measuring the mass sensitive observables of EAS in order to improve the primary mass separation. In this work, the EAS observables measurement has performed locally instead of total measurements. Also the relationships between the included number of observables in the classification methods and the prediction accuracy have been investigated. We have shown that the local measurements and inclusion of more mass sensitive observables in the classification processes can improve the classifying quality and also we have shown that muons and electrons energy density can be considered as primary mass sensitive observables in primary mass classification. Also it must be noted that this study is performed for Tehran observation level without considering the details of any certain EAS detection array.     

The importance of charged aerosols in the polar mesosphere in connection with Noctilucent Clouds and Polar Mesosphere Summer Echoes

A number of campaigns have been conducted in order to study Polar Mesosphere Summer Echos (PMSE) and Noctilucent Clouds (NLC) in the period 1991–1994. Several sounding rockets have been launched through these layers with measurements being performed on upleg as well as downleg. These include measurements of positive ions and electrons in both ram and wake positions, as well as measurements of charged aerosols in ram on upleg. In this paper we will review these measurements and make a preliminary classification of the data based upon the presence of PMSE and/or NLC. One of the mechanisms responsible for PMSE is the presence of neutral air turbulence in combination with a high Schmidt number. We will briefly discuss this type of echo using in situ rocket data. Differences and similarities of PMSE and NLC as observed both in the Arctic and the Antarctic will be discussed. Observations show that especially PMSE are much more frequent in the Arctic. This may be due to a difference in the water vapour content or the temperature at mesopause heights. Lack of data in the Antarctic makes it difficult to decide which of these two factors are the most important. More measurements, especially co-ordinated in situ and ground-based lidar and radar measurements, are needed to discuss the Arctic and Antarctic similarities and differences in further detail.     

Time of flight measurements over a radio link from Uppsala to Bruntingthorpe and their application to testing predictions methods that approximate the ray tracing technique

Time of flight measurements (TOF) over the radio link between Uppsala (Tx: 59.9°N, 17.6°E) and Bruntingthorpe (Rx: 52.5°N, 1.1°W) have been performed every 2 min at six frequencies (4.637, 6.954, 8.008, 10.391, 11.118, and 14.364 MHz) during the period November 2006–January 2008. Such measurements have been compared with the TOF provided by three prediction methods that approximate the ray tracing technique: IRI-95, SIRM&BR_D, and ICEPAC. The root mean square deviation (rms) between TOF monthly median measurements and TOF monthly median predictions and the differences (DP) between the length of the median and predicted ray path have been calculated. The results, which are presented in terms of rms and DP for different seasons and different time periods, have indicated that the approximate methods are inadequate and that for more accurate predictions ray tracing techniques should be applied.     

Long-term (50 years) measurements of cosmic ray fluxes in the atmosphere

Since the middle of 1957 till present time the group of researchers of P.N. Lebedev Physical Institute of the Russian Academy of Sciences has carried out the regular balloon borne measurements of charged particle fluxes in the atmosphere. The measurements are performed at polar (northern and southern) and middle latitudes and cover the interval of heights from the ground level up to 30–35 km. Standard detectors of particles (gas-discharged counters) have been used. More than 80,000 measurements of cosmic ray fluxes in the atmosphere have been performed to the present time. In the data analysis the geomagnetic field and the Earth’s atmosphere are used as cosmic ray spectrometers.     

Vertical density and temperature structure over Northern Europe

During the Energy Budget Campaign, several profiles of the density and temperature of the upper atmosphere were obtained. The measurements were made using rocket-borne instrumentation launched from ESRANGE, Sweden and Andoya Rocket Range, Norway during November and December, 1980. The techniques included meteorological temperature sondes, passive falling spheres, accelerometer instrumented falling spheres, density gauges, mass spectrometers and infrared emission experiments. The instruments provided data within the altitude range from 20 km to 150 km. The measurements were made during periods which have been grouped into three categories by level of geomagnetic activity. Analysis has been made to compare the results and to examine the oscillations and fluctuations in the vertical profiles for scales ranging between hundreds of meters and tens of kilometers. Most of the features observed fit qualitatively within the range expected for internal gravity waves. The geomagnetic storm conditions may be associated with enhanced wave activity and heating observed in the lower thermosphere.     

Development and coupling test of active spacecraft potential control – Next generation (ASPOC-NG)

The active spacecraft potential control (ASPOC) system developed in the 1990s emits positive ions to neutralise the spacecraft potential, such as used in several missions like Geotail, Equator-S, Cluster, Doublestar and MMS. With the experience gained, the next generation of the active spacecraft potential control (ASPOC-NG) instrument has been developed over the last three years. Thereby, three emission technologies were tested including Liquid Metal Ion Source (LMIS), Liquid Metal Electron Source (LMES) and Solid Metal Electron Source (SMES). The development of the emitter module by FOTEC and the corresponding electronics control unit by IWF is presented. Optimisations were carried out with the focus on the reduction of mass and power consumption to comply with the requirements of future scientific missions. Coupling tests of the modules and the electronics control unit were performed including range, accuracy and lifetime tests. Both ASPOC-NG instruments for positive and negative charge compensation and their performance values show excellent results.     

Validation of the stratospheric sounding unit

The Stratospheric Sounding Unit (SSU) is part of the TOVS (TIROS Operational Vertical Sounder) on NOAA operational meteorological satellites. SSU measurements can be validated by comparison with temperature measurements from colocated rocket sondes. Systematic differences are found which vary with rocket station and sonde and are a function of height. However, these measurements are not adequate to define the performance of individual SSUs to a precision which would allow the observations from different SSUs to be combined in the study of diurnal and semidiurnal tides and of long term trends in stratospheric temperature. Instead this is achieved by detailed radiometric and spectroscopic investigation of each individual SSU, both prior to launch and during its operational life. Using the techniques descirbed, it is demonstrated that measurements from different SSUs can be combined with a relative error of less than 0.2K in equivalent brightness temperature.     

微波和THz频段用于遥感标准的研发

美国国家标准和技术研究院(NIST)电磁部噪声规划提出了遥感应用例如卫星气象观测中的微波亮温度标准的研发。这个标准以现有波导系统电磁噪声基准为基础,与亮温度即辐射有关,借助一个特性很好的天线实现。热校准目标作为基准的补充,采用冗余测量的方式,用于检验或者减小不确定度。做过的26 GHz的初步测量表明所提出标准的可行性,同样太赫兹(THz)频率的研究也在进行中。对于THz噪声,用一个加热的目标作为噪声标准,虽然我们没有这么高频率的噪声基准。这个标准将与THz辐射计一起使用。辐射计基于一个接收机,该接收机采用了一个热电子测辐射热混频器,并被准光学适配器耦合到辐射中去。希望年底能够用这套系统进行THz噪声测量。     

Sodium lidar measurements of mesopause region temperatures at 23° S

A sodium lidar, capable of measuring temperature in the 80–100 km region, has been in operation at São José dos Campos (23° S, 46 W) since March 2007. Good quality data have been obtained for late autumn, winter and spring, but weather conditions make it extremely difficult to make measurements from mid-November to mid- February. We find the temperature structure to be strongly modulated by tides and gravity waves, but average profiles typically show a primary mesopause height close to 100 km with temperatures around 180 K, and a tendency for a secondary minimum of about 185 K to occur close to 90 km. Vertical temperature gradients greater than 50 K/km are sometimes seen even on profiles averaged over several hours. The strongest gradients are always positive and are frequently associated with strong gradients in sodium concentration. On the other hand, we frequently see rapid changes in the temperature profile, suggesting that models and non-local temperature measurements, as made by satellite radiometers, for example, are of little use in applications such as the analysis of gravity wave propagation seen in airglow images.     

国产皮秒级商用MTIM测量仪比测

介绍国产皮秒级商用多通道时间间隔测量仪（MTIM）随同北斗导航系统建设的发展历程，通过在工程应用中比较分析国产MTIM测量仪与外国知名厂商MTIM测量仪比对测量数据，结果表明，国产MTIM测量仪的测量分辨力优于10ps，测量噪声小于15ps，测量不确定度小于20ps，通道固定时延随温度变化的温度系数小于1ps/℃；单批次、数十台、数以百计的高性能MTIM测量通道被用户合格验收。这表明小批量产的国产皮秒级商用MTIM测量仪足以比肩于国外同类知名产品。     

Remote sensing of the atmospheric from scientific stations “Salyut”

A review of the four-channel teleradiometer “Micron” calibration and data processing techniques has been presented. The sensor validation of the space-borne teleradiometer “Micron” was based on the following: the preflight absolute calibration with the state certificated standard, the secondary onboard standard (miniature filament lamp), the inflight measurements of the Moon's brightness. The procedure of the extinction coefficient determination from the daytime horizon profiles has been developed. The validity of the used techniques was estimated by carring out model calculations. An optimal measuring procedure has been recommended. The proposed simple techniques are used for processing the space measured horizon brightness data. The results have been compared with the earlier published ones.     

Meteorological variations in the middle clouds of Venus from VEGA balloon in situ measurements

Instruments aboard the gondolas of the two VEGA balloons obtained in situ measurements of pressure, temperature, vertical velocity relative to the balloon, cloud particle backscatter, lightning and the ambient light level. Atmospheric motions at the balloon float altitudes were also determined from Earth-based tracking results. To illustrate the history of the balloon flights and to facilitate comparisons between some of the different observed quantities, measurements of pressure, temperature and backscatter are presented as time series for the entire lifetime of each balloon. Both long and short period variations have been detected. In addition, the environmental entropy encountered by each balloon will be discussed.     

A facility for simulating Titan’s environment

As a result of measurements acquired by the Cassini–Huygens mission of Titan’s near surface atmospheric composition and temperature, Titan conditions can now be simulated in the laboratory and samples can subsequently be subjected to those conditions. Titan demonstrates an active hydrological-like cycle with its thick atmosphere, dynamic clouds, polar lakes of methane and ethane, moist regolith, and extensive fluvial erosive features. Unlike Earth, Titan’s hydrological-like cycle likely involves several constituents, primarily methane and ethane. Here the properties of a new Titan simulation facility are presented, including conceptual methodology, design, implementation, and performance results. The chamber maintains Titan’s surface temperature and pressure, and the sample cryogenic liquids undergoing experimentation are condensed within the chamber itself. During the experiments, the evaporation rates of the sample liquids are directly determined by continually measuring mass. Constituents are analyzed utilizing a Fourier Transform Infrared Spectroscopy (FTIR), and vapor concentrations are determined using a gas chromatograph fitted with a Flame Ionization Detector (FID). All pertinent data is logged via computer. Under laboratory conditions, the direct measurements of the evaporation rates of methane, ethane, and mixtures thereof can be achieved. Among the processes to be studied are the effects of regolith on transport from the subsurface to the atmosphere, the freezing point depression effects of dissolved nitrogen, and the solubility of various relevant organic compounds.     

Validation of aerosol measurements by the satellite sensors SAM II and SAGE

The satellite sensors SAM II and SAGE have been developing a global data base on stratospheric aerosols since they were launched in October 1978 and February 1979, respectively. The validity of this data base has been tested by numerous comparisons with other measurements made by lidars, balloon-borne particle counters, and aircraft-borne impactors and filters. Because the satellite sensors measure extinction and the correlative sensors measure other properties (e.g., backscatter, number, mass), special techniques are required to convert each measured property to other properties and to quantify conversion uncertainties and measurement uncertainties. Use of these techniques in two major comparative experiments shows that the SAM II and SAGE extinction measurements agree with each other and with values derived from dustsonde, lidar, and filter measurements. In addition, the comparative experiments have highlighted the uncertainties of each type of sensor and stimulated further efforts to reduce these uncertainties.     

The search for extra-solar planetary systems.

I review the observational evidence for planetary systems around nearby stars and, using our own solar system as a guide, assess the stringent requirements that new searches need to meet in order to unambiguously establish the presence of another planetary system. Basically, these requirements are: 1 milliarcsecond or better positional accuracy for astrometric techniques, 9 orders of magnitude or better star to planet luminosity ratio discrimination at 0.5 to 1" separation in the optical for direct imaging techniques, 10 meters sec-1 or better radial velocity accuracy for reflex motion techniques and +/-1% or better brightness fluctuation accuracy for planet/star occultation measurements. The astrometric accuracy is in reach of HST, direct imaging will require much larger telescopes and/or a 50 times smoother mirror than HST while the reflex motion and occultation techniques best performed on the ground are just becoming viable and promise exciting new discoveries. On the other band, new indirect evidence on the existence of other planetary systems also comes from the observation of large dusty disks around nearby main sequence stars not too dissimilar from our sun. In one particular case, that of Beta Pictoris, a flattened disk seen nearly edge-on has been imaged in the optical and near IR down to almost 70 AU of the star. It probably represents a young planetary system in its clearing out phase as planetesimals collide, erode and are swept out of the inner system by radiation pressure. The hypothesized Kuiper belt around our solar system may be the analogous structure in a later evolutionary stage. Features of this type have been detected in the far IR and sub-millimeter wavelength regions around 50-100 nearby main sequence and pre-main sequence stars. I discuss a battery of new accurate observations planned in the near future of these objects some of which may actually harbour planets or planetesimals that will certainly dramatically improve our knowledge of planetary system formation processes and our peculiar position in this scheme.     

Connection between winter mesopause region temperatures and diurnal LF reflection height variations measured at Collm

Scale height, H, estimates are calculated from the decrease/increase of ionospheric virtual reflection heights of low-frequency (LF) radio waves at oblique incidence in suitably defined morning intervals around sunrise during winter months. The day-to-day variations of H qualitatively agree with daily mean temperature variations around 90 km from meteor radar measurements. Since mesospheric long-period temperature variations are generally accepted to be the signature of atmospheric planetary waves, this shows that LF reflection height measurements can be used for monitoring the dynamics of the upper middle atmosphere. The long-term variations of monthly mean H estimates have also been analysed. There is no significant trend, which is in agreement with other measurements of mesopause region temperature trends.     

Past,present and future measurements of the solar diameter

The solar diameter, and its possible variation, have been the subject of careful measurements for over 350 years, with ever increasing accuracy. The importance of the knowledge of the diameter, and its variation, for solar physics, and climatology are pointed out. Different techniques have been used, and the instrumentation has evolved in time. This is why the long-term evolution of the Sun is still a controversial subject. Even for the short term of the 11-year solar cycle, the results are inconsistent even with the most advanced instruments presently in use. These discrepancies probably have several origins: the Earth’s atmosphere, the spectral domain of observation, the stability of the instruments, and the data filtering techniques used. The absence of either internal angular calibration for most of them, or intercomparisons prior to the operational phase either from ground or space, make understanding the origin of the discrepancies difficult. Not all instruments suffer from all the above defects, but all instruments are affected by at least one of them. Furthermore, the lack of precise definition of what is measured is another source of confusion. We review the available results, and attempt to understand the origin of the discrepancies. Finally, a proposal for future measurements is made.     

Pulsar studies with GRO-COMPTEL

Pulsar measurements performed by the experiment COMPTEL, aboard the Compton Gamma Ray Observatory, are described. The main results refer to the Crab and Vela pulsars whose pulse shape characteristics are given in some detail and light curves are compared with those above 50 MeV, as observed by the COS-B satellite. No other gamma-ray pulsars have been detected to date by COMPTEL, the upper limit on the pulsed signal from Geminga being compatible with indications by other experiments.