Reaction Networks for Interstellar Chemical Modelling: Improvements and Challenges

We survey the current situation regarding chemical modelling of the synthesis of molecules in the interstellar medium. The present state of knowledge concerning the rate coefficients and their uncertainties for the major gas-phase processes—ion-neutral reactions, neutral-neutral reactions, radiative association, and dissociative recombination—is reviewed. Emphasis is placed on those key reactions that have been identified, by sensitivity analyses, as ‘crucial’ in determining the predicted abundances of the species observed in the interstellar medium. These sensitivity analyses have been carried out for gas-phase models of three representative, molecule-rich, astronomical sources: the cold dense molecular clouds TMC-1 and L134N, and the expanding circumstellar envelope IRC +10216. Our review has led to the proposal of new values and uncertainties for the rate coefficients of many of the key reactions. The impact of these new data on the predicted abundances in TMC-1 and L134N is reported. Interstellar dust particles also influence the observed abundances of molecules in the interstellar medium. Their role is included in gas-grain, as distinct from gas-phase only, models. We review the methods for incorporating both accretion onto, and reactions on, the surfaces of grains in such models, as well as describing some recent experimental efforts to simulate and examine relevant processes in the laboratory. These efforts include experiments on the surface-catalyzed recombination of hydrogen atoms, on chemical processing on and in the ices that are known to exist on the surface of interstellar grains, and on desorption processes, which may enable species formed on grains to return to the gas-phase.     

Impact of Distance Determinations on Galactic Structure. I. Young and Intermediate-Age Tracers

Here we discuss impacts of distance determinations on the Galactic disk traced by relatively young objects. The Galactic disk, \(\sim40~\mbox{kpc}\) in diameter, is a cross-road of studies on the methods of measuring distances, interstellar extinction, evolution of galaxies, and other subjects of interest in astronomy. A proper treatment of interstellar extinction is, for example, crucial for estimating distances to stars in the disk outside the small range of the solar neighborhood. We’ll review the current status of relevant studies and discuss some new approaches to the extinction law. When the extinction law is reasonably constrained, distance indicators found in today and future surveys are telling us stellar distribution and more throughout the Galactic disk. Among several useful distance indicators, the focus of this review is Cepheids and open clusters (especially contact binaries in clusters). These tracers are particularly useful for addressing the metallicity gradient of the Galactic disk, an important feature for which comparison between observations and theoretical models can reveal the evolution of the disk.     

Recent progress in astrochemistry

Models of the four currently recognized regimes of astrochemistry are compared with observations. Ion-Molecule Gas Phase Chemistry is fundamental throughout all interstellar and circumstellar molecular clouds, and by itself explains fairly well the simpler molecular species in diffuse and cold quiescent dense interstellar clouds, as well as in the outer envelopes of circumstellar clouds. Dust-Grain Chemistry may modify ion-molecule chemistry noticeably in regions containing UV radiation, shocks, or other heating agents which can serve to promote surface reactions and to desorb molecules frozen on grains; it likely plays no role in cold quiescent clouds except to adsorb gas phase molecules. Shock Chemistry occurs in regions of star formation and appears important in explaining certain molecular species and in disrupting grains. Circumstellar envelopes combine several chemistries, including those of thermochemical equilibrium in the dense inner regions, and ion-molecule in the outer regions, with grain processes also likely. The limitations of all current models are lack of knowledge of reaction rates, of detailed physical conditions (interstellar clouds), and of the relative depletions (onto grains) of the chemical elements, as well as grain surface chemistry in general. In both interstellar and circumstellar objects, ion-molecule gas phase models are now quite successful in explaining, semi-quantitatively, observed species with up to 4 atoms, but difficulties remain for larger species, as well as the state of carbon, and the models are not yet very predictive.NRAO is operated by Associated Universities Inc. under contract with NSF.     

Magnetospheric Science Objectives of the <Emphasis Type="Italic">Juno</Emphasis> Mission

In July 2016, NASA’s Juno mission becomes the first spacecraft to enter polar orbit of Jupiter and venture deep into unexplored polar territories of the magnetosphere. Focusing on these polar regions, we review current understanding of the structure and dynamics of the magnetosphere and summarize the outstanding issues. The Juno mission profile involves (a) a several-week approach from the dawn side of Jupiter’s magnetosphere, with an orbit-insertion maneuver on July 6, 2016; (b) a 107-day capture orbit, also on the dawn flank; and (c) a series of thirty 11-day science orbits with the spacecraft flying over Jupiter’s poles and ducking under the radiation belts. We show how Juno’s view of the magnetosphere evolves over the year of science orbits. The Juno spacecraft carries a range of instruments that take particles and fields measurements, remote sensing observations of auroral emissions at UV, visible, IR and radio wavelengths, and detect microwave emission from Jupiter’s radiation belts. We summarize how these Juno measurements address issues of auroral processes, microphysical plasma physics, ionosphere-magnetosphere and satellite-magnetosphere coupling, sources and sinks of plasma, the radiation belts, and the dynamics of the outer magnetosphere. To reach Jupiter, the Juno spacecraft passed close to the Earth on October 9, 2013, gaining the necessary energy to get to Jupiter. The Earth flyby provided an opportunity to test Juno’s instrumentation as well as take scientific data in the terrestrial magnetosphere, in conjunction with ground-based and Earth-orbiting assets.     

Magnetic fields in the ionosphere of Venus

This review surveys the observations of the ionospheric magnetic fields of Venus as observed on the Pioneer Venus Orbiter and the models that have been developed to describe them over the last decade. The models for the large-scale ionospheric field have developed to the advanced stage of one-dimensional, self-consistent, multi-fluid MHD models which provide a detailed picture of the field in the subsolar region for specific upper boundary conditions. In contrast, the models for the small-scale fields and the nightside fields have only reached a rudimentary stage. Much challenging work remains to be done on the origin of the ionospheric flux ropes and nightside ionospheric hole fields. On the whole, the subject of the ionospheric fields would greatly benefit from 3-dimensional global MHD models with self-consistent treatments of the ionosphere.     

The OSIRIS-REx Thermal Emission Spectrometer (OTES) Instrument

The OSIRIS-REx Thermal Emission Spectrometer (OTES) will provide remote measurements of mineralogy and thermophysical properties of Bennu to map its surface, help select the OSIRIS-REx sampling site, and investigate the Yarkovsky effect. OTES is a Fourier Transform spectrometer covering the spectral range 5.71–100 μm (\(1750\mbox{--}100~\mbox{cm}^{-1}\)) with a spectral sample interval of \(8.66~\mbox{cm}^{-1}\) and a 6.5-mrad field of view. The OTES telescope is a 15.2-cm diameter Cassegrain telescope that feeds a flat-plate Michelson moving mirror mounted on a linear voice-coil motor assembly. A single uncooled deuterated l-alanine doped triglycine sulfate (DLATGS) pyroelectric detector is used to sample the interferogram every two seconds. Redundant ～0.855 μm laser diodes are used in a metrology interferometer to provide precise moving mirror control and IR sampling at 772 Hz. The beamsplitter is a 38-mm diameter, 1-mm thick chemical vapor deposited diamond with an antireflection microstructure to minimize surface reflection. An internal calibration cone blackbody target provides radiometric calibration. The radiometric precision in a single spectrum is \(\leq2.2 \times 10^{-8}~\mbox{W}\,\mbox{cm}^{-2}\,\mbox{sr} ^{-1}/\mbox{cm}^{-1}\) between 300 and \(1350~\mbox{cm}^{-1}\). The absolute integrated radiance error is \(<1\%\) for scene temperatures ranging from 150 to 380 K. The overall OTES envelope size is \(37.5 \times 28.9 \times 52.2~\mbox{cm}\), and the mass is 6.27 kg. The power consumption is 10.8 W average. OTES was developed by Arizona State University with Moog Broad Reach developing the electronics. OTES was integrated, tested, and radiometrically calibrated on the Arizona State University campus in Tempe, AZ.     

Nucleosynthesis in Supernovae

We present the status and open problems of nucleosynthesis in supernova explosions of both types, responsible for the production of the intermediate mass, Fe-group and heavier elements (with the exception of the main s-process). Constraints from observations can be provided through individual supernovae (SNe) or their remnants (e.g. via spectra and gamma-rays of decaying unstable isotopes) and through surface abundances of stars which witness the composition of the interstellar gas at their formation. With a changing fraction of elements heavier than He in these stars (known as metallicity) the evolution of the nucleosynthesis in galaxies over time can be determined. A complementary way, related to gamma-rays from radioactive decays, is the observation of positrons released in \(\beta^{+}\)-decays, as e.g. from \(^{26}\mbox{Al}\), \(^{44}\mbox{Ti}\), \(^{56,57}\mbox{Ni}\) and possibly further isotopes of their decay chains (in competition with the production of \(e^{+}e^{-}\) pairs in acceleration shocks from SN remnants, pulsars, magnetars or even of particle physics origin). We discuss (a) the role of the core-collapse supernova explosion mechanism for the composition of intermediate mass, Fe-group (and heavier?) ejecta, (b) the transition from neutron stars to black holes as the final result of the collapse of massive stars, and the relation of the latter to supernovae, faint supernovae, and gamma-ray bursts/hypernovae, (c) Type Ia supernovae and their nucleosynthesis (e.g. addressing the \(^{55}\mbox{Mn}\) puzzle), plus (d) further constraints from galactic evolution, \(\gamma\)-ray and positron observations. This is complemented by the role of rare magneto-rotational supernovae (related to magnetars) in comparison with the nucleosynthesis of compact binary mergers, especially with respect to forming the heaviest r-process elements in galactic evolution.     

An Investigation of the Mechanical Properties of Some Martian Regolith Simulants with Respect to the Surface Properties at the InSight Mission Landing Site

In support of the InSight mission in which two instruments (the SEIS seismometer and the \(\mbox{HP}^{3}\) heat flow probe) will interact directly with the regolith on the surface of Mars, a series of mechanical tests were conducted on three different regolith simulants to better understand the observations of the physical and mechanical parameters that will be derived from InSight. The mechanical data obtained were also compared to data on terrestrial sands. The density of the regolith strongly influences its mechanical properties, as determined from the data on terrestrial sands. The elastoplastic compression volume changes were investigated through oedometer tests that also provided estimates of possible changes in density with depth. The results of direct shear tests provided values of friction angles that were compared with that of a terrestrial sand, and an extrapolation to lower density provided a friction angle compatible with that estimated from previous observations on the surface of Mars. The importance of the contracting/dilating shear volume changes of sands on the dynamic penetration of the mole was determined, with penetration facilitated by the \(\sim1.3~\mbox{Mg/m}^{3}\) density estimated at the landing site. Seismic velocities, measured by means of piezoelectric bender elements in triaxial specimens submitted to various isotropic confining stresses, show the importance of the confining stress, with lesser influence of density changes under compression. A power law relation of velocity as a function of confining stress with an exponent of 0.3 was identified from the tests, allowing an estimate of the surface seismic velocity of 150 m/s. The effect on the seismic velocity of a 10% proportion of rock in the regolith was also studied. These data will be compared with in situ data measured by InSight after landing.     

Chemical Composition of Icy Satellite Surfaces

Much of our knowledge of planetary surface composition is derived from remote sensing over the ultraviolet through infrared wavelength ranges. Telescopic observations and, in the past few decades, spacecraft mission observations have led to the discovery of many surface materials, from rock-forming minerals to water ice to exotic volatiles and organic compounds. Identifying surface materials and mapping their distributions allows us to constrain interior processes such as cryovolcanism and aqueous geochemistry. The recent progress in understanding of icy satellite surface composition has been aided by the evolving capabilities of spacecraft missions, advances in detector technology, and laboratory studies of candidate surface compounds. Pioneers 10 and 11, Voyagers I and II, Galileo, Cassini and the New Horizons mission have all made significant contributions. Dalton (Space Sci. Rev., 2010, this issue) summarizes the major constituents found or inferred to exist on the surfaces of the icy satellites (cf. Table 1 from Dalton, Space Sci. Rev., 2010, this issue), and the spectral coverage and resolution of many of the spacecraft instruments that have revolutionized our understanding (cf. Table 2 from Dalton, Space Sci. Rev., 2010, this issue). While much has been gained from these missions, telescopic observations also continue to provide important constraints on surface compositions, especially for those bodies that have not yet been visited by spacecraft, such as Kuiper Belt Objects (KBOs), trans-Neptunian Objects (TNOs), Centaurs, the classical planet Pluto and its moon, Charon. In this chapter, we will discuss the major satellites of the outer solar system, the materials believed to make up their surfaces, and the history of some of these discoveries. Formation scenarios and subsequent evolution will be described, with particular attention to the processes that drive surface chemistry and exchange with interiors. Major similarities and differences between the satellites are discussed, with an eye toward elucidating processes operating throughout the outer solar system. Finally we discuss the outermost satellites and other bodies, and summarize knowledge of their composition. Much of this review is likely to change in the near future with ongoing and planned outer planet missions, adding to the sense of excitement and discovery associated with our exploration of our planetary neighborhood.     

Aerosols on the Giant Planets and Titan

On the giant planets and Titan, like on the terrestrial planets, aerosols play an important part in the physico-chemistry of the upper atmosphere (P ≤ 0.5 bar). Above all, aerosols significantly affect radiative transfer processes, mainly through light scattering, thus influencing the atmospheric energy budget and dynamics. Because there is usually significant coupling between atmospheric circulation and haze production, aerosols may constitute useful tracers of atmospheric dynamics.More generally, since their production is directly linked to some kind of energy deposition, their study may also provide clues to external sources of energy as well as their variability. Finally, aerosols indirectly influence other processes such as cloud formation and disequilibrium chemistry, by acting either as condensation nuclei or as reaction sites for surface chemistry. Here, I present a review of observational and modeling results based on remote sensing data, and also some insights derived from laboratory simulations. Despite our knowledge of the effects of aerosols in outer planetary atmospheres, however, relatively little is understood about the pathways which produce them, either endogenously (as end-products of gas-phase photochemical or shock reactions) or exogenously (as residues of meteroid ablation).     

Quantitative models of the magnetospheric magnetic field: Methods and results

The paper reviews various approaches to the problem of evaluation and numerical representation of the magnetic field distributions produced within the magnetosphere by the main electric current systems including internal Earth's sources, the magnetopause surface current, the tail plasma sheet, the large-scale systems of Birkeland current, the currents due to radiation belt particles, and the partial ring current circuit. Some basic physical principles as well as mathematical background for development of magnetospheric magnetic field models are discussed.A special emphasis is placed on empirical modeling based on datasets created from large bodies of spacecraft measurements. A review of model results on the average magnetospheric configurations and their dependence on the geomagnetic disturbance level and the state of interplanetary medium is given. Possibilities and perspectives for elaborating the instantaneous models capable of evaluating a current distribution of magnetic field and force line configuration based on a synoptic monitoring the intensity of the main magnetospheric electric current systems are also discussed. Some areas of practical use of magnetospheric models are reviewed in short. Magnetospheric plasma and energetic particle measurements are considered in the context of their use as an independent tool for testing and correcting the magnetic field models.     

Electric Fields and Magnetic Fields in the Plasmasphere: A Perspective From CLUSTER and IMAGE

The electric field and magnetic field are basic quantities in the plasmasphere measured since the 1960s. In this review, we first recall conventional wisdom and remaining problems from ground-based whistler measurements. Then we show scientific results from Cluster and Image, which are specifically made possible by newly introduced features on these spacecraft, as follows. 1. In situ electric field measurements using artificial electron beams are successfully used to identify electric fields originating from various sources. 2. Global electric fields are derived from sequences of plasmaspheric images, revealing how the inner magnetospheric electric field responds to the southward interplanetary magnetic fields and storms/substorms. 3. Understanding of sub-auroral polarization stream (SAPS) or sub-auroral ion drifts (SAID) are advanced through analysis of a combination of magnetospheric and ionospheric measurements from Cluster, Image, and DMSP. 4. Data from multiple spacecraft have been used to estimate magnetic gradients for the first time.     

Imaging Plasma Density Structures in the Soft X-Rays Generated by Solar Wind Charge Exchange with Neutrals

Both heliophysics and planetary physics seek to understand the complex nature of the solar wind’s interaction with solar system obstacles like Earth’s magnetosphere, the ionospheres of Venus and Mars, and comets. Studies with this objective are frequently conducted with the help of single or multipoint in situ electromagnetic field and particle observations, guided by the predictions of both local and global numerical simulations, and placed in context by observations from far and extreme ultraviolet (FUV, EUV), hard X-ray, and energetic neutral atom imagers (ENA). Each proposed interaction mechanism (e.g., steady or transient magnetic reconnection, local or global magnetic reconnection, ion pick-up, or the Kelvin-Helmholtz instability) generates diagnostic plasma density structures. The significance of each mechanism to the overall interaction (as measured in terms of atmospheric/ionospheric loss at comets, Venus, and Mars or global magnetospheric/ionospheric convection at Earth) remains to be determined but can be evaluated on the basis of how often the density signatures that it generates are observed as a function of solar wind conditions. This paper reviews efforts to image the diagnostic plasma density structures in the soft (low energy, 0.1–2.0 keV) X-rays produced when high charge state solar wind ions exchange electrons with the exospheric neutrals surrounding solar system obstacles.The introduction notes that theory, local, and global simulations predict the characteristics of plasma boundaries such the bow shock and magnetopause (including location, density gradient, and motion) and regions such as the magnetosheath (including density and width) as a function of location, solar wind conditions, and the particular mechanism operating. In situ measurements confirm the existence of time- and spatial-dependent plasma density structures like the bow shock, magnetosheath, and magnetopause/ionopause at Venus, Mars, comets, and the Earth. However, in situ measurements rarely suffice to determine the global extent of these density structures or their global variation as a function of solar wind conditions, except in the form of empirical studies based on observations from many different times and solar wind conditions. Remote sensing observations provide global information about auroral ovals (FUV and hard X-ray), the terrestrial plasmasphere (EUV), and the terrestrial ring current (ENA). ENA instruments with low energy thresholds (\(\sim1~\mbox{keV}\)) have recently been used to obtain important information concerning the magnetosheaths of Venus, Mars, and the Earth. Recent technological developments make these magnetosheaths valuable potential targets for high-cadence wide-field-of-view soft X-ray imagers.Section 2 describes proposed dayside interaction mechanisms, including reconnection, the Kelvin-Helmholtz instability, and other processes in greater detail with an emphasis on the plasma density structures that they generate. It focuses upon the questions that remain as yet unanswered, such as the significance of each proposed interaction mode, which can be determined from its occurrence pattern as a function of location and solar wind conditions. Section 3 outlines the physics underlying the charge exchange generation of soft X-rays. Section 4 lists the background sources (helium focusing cone, planetary, and cosmic) of soft X-rays from which the charge exchange emissions generated by solar wind exchange must be distinguished. With the help of simulations employing state-of-the-art magnetohydrodynamic models for the solar wind-magnetosphere interaction, models for Earth’s exosphere, and knowledge concerning these background emissions, Sect. 5 demonstrates that boundaries and regions such as the bow shock, magnetosheath, magnetopause, and cusps can readily be identified in images of charge exchange emissions. Section 6 reviews observations by (generally narrow) field of view (FOV) astrophysical telescopes that confirm the presence of these emissions at the intensities predicted by the simulations. Section 7 describes the design of a notional wide FOV “lobster-eye” telescope capable of imaging the global interactions and shows how it might be used to extract information concerning the global interaction of the solar wind with solar system obstacles. The conclusion outlines prospects for missions employing such wide FOV imagers.     

On the Detectability and Use of Normal Modes for Determining Interior Structure of Mars

The InSight mission to Mars is well underway and will be the first mission to acquire seismic data from a planet other than Earth. In order to maximise the science return of the InSight data, a multifaceted approach will be needed that seeks to investigate the seismic data from a series of different frequency windows, including body waves, surface waves, and normal modes. Here, we present a methodology based on globally-averaged models that employs the long-period information encoded in the seismic data by looking for fundamental-mode spheroidal oscillations. From a preliminary analysis of the expected signal-to-noise ratio, we find that normal modes should be detectable during nighttime in the frequency range 5–15 mHz. For improved picking of (fundamental) normal modes, we show first that those are equally spaced between 5–15 mHz and then show how this spectral spacing, obtained through autocorrelation of the Fourier-transformed time series can be further employed to select normal mode peaks more consistently. Based on this set of normal-mode spectral frequencies, we proceed to show how this data set can be inverted for globally-averaged models of interior structure (to a depth of \(\sim 250~\mbox{km}\)), while simultaneously using the resultant synthetically-approximated normal mode peaks to verify the initial peak selection. This procedure can be applied iteratively to produce a “cleaned-up” set of spectral peaks that are ultimately inverted for a “final” interior-structure model. To investigate the effect of three-dimensional (3D) structure on normal mode spectra, we constructed a 3D model of Mars that includes variations in surface and Moho topography and lateral variations in mantle structure and employed this model to compute full 3D waveforms. The resultant time series are converted to spectra and the inter-station variation hereof is compared to the variation in spectra computed using different 1D models. The comparison shows that 3D effects are less significant than the variation incurred by the difference in radial models, which suggests that our 1D approach represents an adequate approximation of the global average structure of Mars.     

Extended Pile Driving Model to Predict the Penetration of the Insight/HP<Superscript>3</Superscript> Mole into the Martian Soil

The NASA InSight mission will provide an opportunity for soil investigations using the penetration data of the heat flow probe built by the German Aerospace Center DLR. The Heat flow and Physical Properties Probe (HP³) will penetrate 3 to 5 meter into the Martian subsurface to investigate the planetary heat flow. The measurement of the penetration rate during the insertion of the HP³ will be used to determine the physical properties of the soil at the landing site. For this purpose, numerical simulations of the penetration process were performed to get a better understanding of the soil properties influencing the penetration performance of HP³. A pile driving model has been developed considering all masses of the hammering mechanism of HP³. By cumulative application of individual stroke cycles it is now able to describe the penetration of the Mole into the Martian soil as a function of time, assuming that the soil parameters of the material through which it penetrates are known. We are using calibrated materials similar to those expected to be encountered by the InSight/HP³ Mole when it will be operated on the surface of Mars after the landing of the InSight spacecraft. We consider various possible scenarios, among them a more or less homogeneous material down to a depth of 3–5 m as well as a layered ground, consisting of layers with different soil parameters. Finally we describe some experimental tests performed with the latest prototype of the InSight Mole at DLR Bremen and compare the measured penetration performance in sand with our modeling results. Furthermore, results from a 3D DEM simulation are presented to get a better understanding of the soil response.     

The roles of direct input of energy from the solar wind and unloading of stored magnetotail energy in driving magnetospheric substorms

This paper presents the consensus arrived at by the authors with respect to the contributions to the substorm expansive phase of direct energy input from the solar wind and from energy stored in the magnetotail which is released in a sometimes unpredictable manner. Two physical processes, neither of which can be ignored, are considered to be of importance in the dispensation of the energy input from the solar wind. One of these is the driven process in which energy, supplied from the solar wind, is directly dissipated in the ionosphere with the only clearly definable delay being due to the inductance of the magnetosphere-ionosphere system. The other is the loading-unloading process in which energy from the solar wind is first stored in the magnetotail and then is suddenly released to be deposited in the ionosphere as a consequence of external changes in the interplanetary medium or internal triggering processes. Although the driven process appears to be more dominant on a statistical basis in terms of solar wind-geomagnetic activity relationships, one or the other of the two above processes may dominate for any individual cases. Moreover, the two processes may operate simultaneously during a given phase of the substorm, e.g., the magnetotail may experience loading as the driven system increases in strength. Thus, in our approach, substorms are described in terms of physical processes which we infer to be operative in the magnetosphere and the terminology of the past (e.g., phases) is related to those inferred physical processes. The pattern of substorm development in response to changes in the interplanetary medium is presented for a canonical isolated substorm.Now at Max-Planck-Institut für Physik und Astrophysik, Institut für Extraterrestrische Physik, D-8046 Garching, F.R.G.