10Be in Ice Cores and 14C in Tree Rings: Separation of Production and Climate Effects

Cosmogenic radionuclides are more and more used in solar activity reconstructions. However, the cosmogenic radionuclide signal also contains a climate component. It is therefore crucial to eliminate the climate information to allow a better interpretation of the reconstructed solar activity indices. In this paper the method of principal components is applied to ¹⁰Be data from two ice cores from opposite hemispheres as well as to ¹⁴C data from tree rings. The analysis shows that these records are dominated by a common signal which explains about 80% of the variance on multi decadal to multi millennial time scales, reflecting their common production rate. The second and third components are significantly different for ¹⁴C and ¹⁰Be. They are interpreted as system effects introduced by the transport of ¹⁰Be and ¹⁴C from the atmosphere where they are produced to the respective natural archives where they are stored. Principal component analysis improves significantly extraction of the production signal from the cosmogenic isotope data series, which is more appropriate for astrophysical and terrestrial studies.     

Neutron Monitor Records in Broader Historical Context

Man-made neutron monitors have provided a continuous detailed record of the cosmic-ray flux over only about the last 5 decades. Fortunately, nature operates its own detectors and offers the opportunity to extend the cosmic-ray records over much longer time scales. Two different types of `natural detectors' can be distinguished. The first is based on long lived radionuclides that are produced by cosmic-ray interactions in the atmosphere and subsequently become stored in archives such as ice sheets or tree rings. The second type are rocks that are exposed to cosmic-rays at a certain time and from then on integrate the production of cosmogenic nuclides over the whole exposure time. The analysis of ¹⁰Be in polar ice cores and ¹⁴C in tree rings clearly reveals solar and geomagnetic modulation of the cosmic-ray flux on different time scales ranging from decades (11-year Schwabe cycle) to millennia. This revised version was published online in August 2006 with corrections to the Cover Date.     

Long-term indirect indices of solar variability

Continuous direct records of solar variability are limited to the telescopic era covering approximately the past four centuries. For longer records one has to rely on indirect indices such as cosmogenic radionuclides. Their production rate is modulated by magnetic properties of the solar wind. Using a parameterisation of the solar activity and a Monte Carlo simulation model describing the interaction of the cosmic rays with the atmosphere, the production rate for each cosmogenic nuclide of interest can be calculated as a function of solar activity. Analysis of appropriate well-dated natural archives such as ice cores or tree rings offers the possibility to reconstruct the solar activity over many millennia. However, the interpretation of the cosmogenic nuclide records from these archives is difficult. The measured concentrations contain not only information on solar activity but also on changes in the geomagnetic field intensity and the transport from the atmosphere into the archive where, under ideal conditions, no further processes take place. Comparison of different nuclides (e.g. ¹⁰Be and ¹⁴C) that are produced in a very similar way but exhibit a completely different geochemical behaviour, allows us to separate production effects from system effects.The presently available data show cyclic variability ranging from 11-year to millennial time scale periodicities with changing amplitudes, as well as irregularly distributed intervals of very low solar activity (so called minima, e.g. Maunder minimum) lasting typically 100 years.     

10Be Production in the Atmosphere by Galactic Cosmic Rays

Galactic cosmic ray nuclei and energetic protons produced in solar flares and accelerated by coronal mass ejections are the main sources of high-energy particles of extraterrestrial origin in near-Earth space and inside the Earth’s atmosphere. The intensity of galactic cosmic rays inside the heliosphere is strongly influenced by the modulation of the interstellar source particles on their way through interplanetary space. Among others, this modulation depends on the activity of the Sun, and the resulting intensity of the energetic particles in the atmosphere is an indicator of the solar activity. Therefore, rare isotopes found in historical archives and produced by spallation reactions of primary and secondary hadrons of cosmic origin in the atmosphere, so-called cosmogenic nuclides, can be used to reconstruct the solar activity in the past. The production rate of ¹⁰Be, one of the cosmogenic nuclides most adequate to study the solar activity, is presented showing its variations with geographic latitude and altitude and the dependence on different production cross-sections present in literature. In addition, estimates for altitude integrated production rates of ¹⁰Be at different locations since the early nineteen sixties are shown.     

Cosmogenic Radionuclides as an Extension of the Neutron Monitor Era into the Past: Potential and Limitations

The cosmogenic radionuclides, ¹⁰Be, ¹⁴C and others, provide a record of the paleo-cosmic radiation that extends >10,000 years into the past. They are the only quantitative means at our disposal to study the heliosphere prior to the commencement of routine sunspot observations in the 17th century. The cosmogenic radionuclides are primarily produced by secondary neutrons generated by the galactic cosmic radiation, and can be regarded, in a sense, as providing an extrapolation of the neutron monitor era into the past. However, their characteristics are quite different from the man-made neutron monitor in several important respects: (1) they are sensitive to somewhat lower cosmic ray energies; (2) their temporal resolution is ～1 to 2 years, being determined by the rapidity with which they are sequestered in ice, biological, or other archives; (3) the statistical precision for annual data is very poor (～19%); however it is quite adequate (～5% for 22-year averages) to study the large variations (±40%) that have occurred in the paleo-cosmic ray record in the past between grand solar minima and maxima. The data contains “noise” caused by local meteorological effects, and longer-term climate effects, and the use of principal component analysis to separate these “system” effects from production effects is outlined. The concentrations of ¹⁰Be decreased by a factor of two at the commencement of Holocene, the present-day “interglacial”, due to a 100% increase in the ice accumulation rates in polar regions. The use of the ¹⁰Be flux to study heliospheric properties during the last glacial is discussed briefly.     

Solar Variability and Climate Impact on Terrestrial Planets

Some possible factors of climate changes and of long term climate evolution are discussed with regard of the three terrestrial planets, Earth, Venus and Mars. Two positive feedback mechanisms involving liquid water, i.e., the albedo mechanism and the greenhouse effect of water vapour, are described. These feedback mechanisms respond to small external forcings, such as resulting from solar or astronomical constants variability, which might thus result in large influences on climatic changes on Earth. On Venus, reactions of the atmosphere with surface minerals play an important role in the climate system, but the involved time scales are much larger. On Mars, climate is changing through variations of the polar axis inclination over time scales of ～10⁵–10⁶ years. Growing evidence also exists that a major climatic change happened on Mars some 3.5 to 3.8 Gigayears ago, leading to the disappearance of liquid water on the planet surface by eliminating most of the CO₂ atmosphere greenhouse power. This change might be due to a large surge of the solar wind, or to atmospheric erosion by large bodies impacts. Indeed, except for their thermospheric temperature response, there is currently little evidence for an effect of long-term solar variability on the climate of Venus and Mars. This fact is possibly due to the absence of liquid water on these terrestrial planets.     

Cosmic Rays in the Heliosphere: Requirements for Future Observations

Since the publication of Cosmic Rays in the Heliosphere in 1998 there has been great progress in understanding how and why cosmic rays vary in space and time. This paper discusses measurements that are needed to continue advances in relating cosmic ray variations to changes in solar and interplanetary activity and variations in the local interstellar environment. Cosmic ray acceleration and transport is an important discipline in space physics and astrophysics, but it also plays a critical role in defining the radiation environment for humans and hardware in space, and is critical to efforts to unravel the history of solar activity. Cosmic rays are measured directly by balloon-borne and space instruments, and indirectly by ground-based neutron, muon and neutrino detectors, and by measurements of cosmogenic isotopes in ice cores, tree-rings, sediments, and meteorites. The topics covered here include: what we can learn from the deep 2008–2009 solar minimum, when cosmic rays reached the highest intensities of the space era; the implications of ¹⁰Be and ¹⁴C isotope archives for past and future solar activity; the effects of variations in the size of the heliosphere; opportunities provided by the Voyagers for discovering the origin of anomalous cosmic rays and measuring cosmic-ray spectra in interstellar space; and future space missions that can continue the exciting exploration of the heliosphere that has occurred over the past 50 years.     

Plasma-induced sputtering of an atmosphere

Magnetospheric ions, solar wind ions, and locally produced pick-up ions can impact the atmospheres of objects in the solar system, transferring energy by collisions with atmospheric atoms and molecules. This can result in an expansion of the atmospheric corona with a fraction of the energetic atoms or molecules being lost (sputtered) from the atmosphere. The expanded corona presents a larger target to the incident plasma, which in turn enhances pick-up ion formation and collisional ejection. In this manner a significant flux of atoms or molecules can be lost from an atmosphere, affecting its long-term evolution. This has been shown to be an important process for the dynamics and evolution of the atmosphere of lo, which is bombarded by the Jovian magnetospheric plasma, and for loss of atmosphere from Titan. Sputtering by pick-up ion bombardment has been shown to remove material from the atmosphere of Mars affecting the observed isotope ratios, and energetic O⁺ precipitation affects the Earth's thermosphere. The physics of ion bombardment of a gas which leads to atmospheric sputtering is described here. Analytic expressions derived from transport equations are shown to be useful for estimating the sputtering rate. These are compared to results from transport and Monte-Carlo calculations.     

Solar Variability Over the Past Several Millennia

The Sun is the most important energy source for the Earth. Since the incoming solar radiation is not equally distributed and peaks at low latitudes the climate system is continuously transporting energy towards the polar regions. Any variability in the Sun-Earth system may ultimately cause a climate change. There are two main variability components that are related to the Sun. The first is due to changes in the orbital parameters of the Earth induced by the other planets. Their gravitational perturbations induce changes with characteristic time scales in the eccentricity (～100,000 years), the obliquity (angle between the equator and the orbital plane) (～40,000 years) and the precession of the Earth’s axis (～20,000 years). The second component is due to variability within the Sun. A variety of observational proxies reflecting different aspects of solar activity show similar features regarding periodic variability, trends and periods of very low solar activity (so-called grand minima) which seem to be positively correlated with the total and the spectral solar irradiance. The length of these records ranges from 25 years (solar irradiance) to 400 years (sunspots). In order to establish a quantitative relationship between solar variability and solar forcing it is necessary to extend the records of solar variability much further back in time and to identify the physical processes linking solar activity and total and spectral solar irradiance. The first step, the extension of solar variability, can be achieved by using cosmogenic radionuclides such as ¹⁰Be in ice cores. After removing the effect of the changing geomagnetic field, a 9000-year long record of solar modulation was obtained. Comparison with paleoclimatic data provides strong evidence for a causal relationship between solar variability and climate change. It will be the subject of the next step to investigate the underlying physical processes that link solar variability with the total and spectral solar irradiance.     

Influence of Solar Wind on the Global Electric Circuit,and Inferred Effects on Cloud Microphysics,Temperature, and Dynamics in the Troposphere

There are at least three independent ways in which the solar wind modulates the flow of current density (Jz) in the global electric circuit. These are (A) changes in the galactic cosmic ray energy spectrum, (B) changes in the precipitation of relativistic electrons from the magnetosphere, and (C) changes in the ionospheric potential distribution in the polar caps due to magnetosphere-ionosphere coupling. The current density J _z flows between the ionosphere and the surface, and as it passes through conductivity gradients it generates space charge concentrations dependent on J _z and the conductivity gradient. The gradients are large at the surfaces of clouds and space charge concentrations of order 1000 to 10,000 elementary charges per cm³ can be generated at cloud tops. The charge transfers to droplets, many of which are evaporating at the cloud-clear air interface. The charge remains on the residual evaporation nuclei with a lifetime against leakage of order 1000 sec, and for a longer period the nuclei also retain coatings of sulfate and organic compounds adsorbed by the droplet while in the cloud.The charged evaporation nuclei become well mixed with more droplets in many types of clouds with penetrative mixing. The processes of entrainment and evaporation are also efficient for these clouds. The collection of such nuclei by nearby droplets is greatly increased by the electrical attraction between the charge on the particle and the image charge that it creates on the droplet. This process is called electroscavenging. Because the charge on the evaporation nuclei is derived from the original space charge, it depends on J _z, giving a rate of electroscavenging responsive to the solar wind inputs.There may be a number of ways in which the electroscavenging has consequences for weather and climate. One possibility is enhanced production of ice. The charged evaporation nuclei have been found to be good ice forming nuclei because of their coatings, and so in supercooled clouds droplet freezing can occur by contact ice nucleation, as the evaporation nuclei are electroscavenged. Although quantitative models for the all the cloud microphysical processes that may be involved have not yet been produced, we show that for many clouds, especially those with broad droplet size distributions, relatively high droplet concentrations, and cloud top temperatures just below freezing, this process is likely to dominate over other primary ice nucleation processes. In these cases there are likely to be effects on cloud albedo and rates of sedimentation of ice, and these will depend on J _z.For an increase in ice production in thin clouds such as altocumulus or stratocumulus the main effect is a decrease in albedo to incoming solar radiation, and in opacity to outgoing longwave radiation. At low latitudes the surface and troposphere heat, and at high latitudes in winter they cool. The change in meridional temperature gradient affects the rate of cyclogenesis, and the amplitude of planetary waves. For storm clouds, as in winter cyclones, the effect of increased ice formation is mainly to increase the rate of glaciation of lower level clouds by the seeder-feeder process. The increase in precipitation efficiency increases the rate of transfer of latent heat between the air mass and the surface. In most cyclones this is likely to result in intensification, producing changes in the vorticity area index as observed. Cyclone intensification also increases the amplitude of planetary waves, and shifts storm tracks, as observed.In this paper we first describe the production of space charge and the way in which it may influence the rate of ice nucleation. Then we review theory and observations of the solar wind modulation of J _z, and the correlated changes in atmospheric temperature and dynamics in the troposphere. The correlations are present for each input, (A, B, and C), and the detailed patterns of responses provide support for the inferred electrical effects on the physics of clouds, affecting precipitation, temperature and dynamics.     

On the Isotopic Composition of Primordial Xenon in Terrestrial Planet Atmospheres

Xenon plays a crucial role in models of atmospheric evolution in which noble gases are fractionated from their initial compositions to isotopically heavier distributions by early hydrodynamic escape of primordial planetary atmospheres. With the assumption that nonradiogenic Xe isotope ratios in present-day atmospheres were generated in this way, backward modeling from these ratios through the fractionating process can in principle identify likely parental Xe compositions and thus the probable sources of noble gases in pre-escape atmospheres. Applied to Earth, this approach simultaneously establishes the presence of an atmospheric Xe component due principally to fission of extinct ²⁴⁴Pu and identifies a composition called U-Xe as primordial Xe. Pu-Xe comprises 4.65±0.30% of atmospheric ¹³⁶Xe, and 6.8±0.5% of the present abundance of ¹²⁹Xe derives from decay of extinct ¹²⁹I. U-Xe is identical to the measured composition of solar-wind Xe except for deficits of the two heaviest isotopes – an unexpected difference since the modeling otherwise points to solar wind compositions for the lighter noble gases in the primordial terrestrial atmosphere. Evidence for the presence of U-Xe is not restricted to the early Earth; modeling based on a purely meteoritic data set defines a parental component in chondrites and achondrites with the same isotopic distribution. Results of experimental efforts to measure this composition directly in meteorites are promising but not yet conclusive. U-Xe also appears as a possible base component in interstellar silicon carbide, here with superimposed excesses of ¹³⁴Xe and ¹³⁶Xe six-fold larger than those in the solar wind. These compositional differences imply mixing of U-Xe with a nucleogenetic heavy-isotope component whose relative abundance in the solar accretion disk and in pre-solar environments varied both spatially and temporally. In contrast to Earth, the U-Xe signature on Mars was apparently overwhelmed by local accretion of materials rich in either chondritic Xe or solar-wind Xe. Data currently in hand from SNC meteorites on the composition of the present atmosphere are insufficiently precise to constrain a modeling choice between these two candidates for primordial martian Xe. They likewise do not permit definitive resolution of a ²⁴⁴Pu component in the atmosphere although its presence is allowed within current measurement uncertainties. This revised version was published online in June 2006 with corrections to the Cover Date.     

A Comparative Study of the Influence of the Active Young Sun on the Early Atmospheres of Earth, Venus, and Mars

Because the solar radiation and particle environment plays a major role in all atmospheric processes such as ionization, dissociation, heating of the upper atmospheres, and thermal and non-thermal atmospheric loss processes, the long-time evolution of planetary atmospheres and their water inventories can only be understood within the context of the evolving Sun. We compare the effect of solar induced X-ray and EUV (XUV) heating on the upper atmospheres of Earth, Venus and Mars since the time when the Sun arrived at the Zero-Age-Main-Sequence (ZAMS) about 4.6 Gyr ago. We apply a diffusive-gravitational equilibrium and thermal balance model for studying heating of the early thermospheres by photodissociation and ionization processes, due to exothermic chemical reactions and cooling by IR-radiating molecules like CO₂, NO, OH, etc. Our model simulations result in extended thermospheres for early Earth, Venus and Mars. The exospheric temperatures obtained for all the three planets during this time period lead to diffusion-limited hydrodynamic escape of atomic hydrogen and high Jeans’ escape rates for heavier species like H₂, He, C, N, O, etc. The duration of this blow-off phase for atomic hydrogen depends essentially on the mixing ratios of CO₂, N₂ and H₂O in the atmospheres and could last from ∼100 to several hundred million years. Furthermore, we study the efficiency of various non-thermal atmospheric loss processes on Venus and Mars and investigate the possible protecting effect of the early martian magnetosphere against solar wind induced ion pick up erosion. We find that the early martian magnetic field could decrease the ion-related non-thermal escape rates by a great amount. It is possible that non-magnetized early Mars could have lost its whole atmosphere due to the combined effect of its extended upper atmosphere and a dense solar wind plasma flow of the young Sun during about 200 Myr after the Sun arrived at the ZAMS. Depending on the solar wind parameters, our model simulations for early Venus show that ion pick up by strong solar wind from a non-magnetized planet could erode up to an equivalent amount of ∼250 bar of O⁺ ions during the first several hundred million years. This accumulated loss corresponds to an equivalent mass of ∼1 terrestrial ocean (TO (1 TO ∼1.39×10²⁴ g or expressed as partial pressure, about 265 bar, which corresponds to ∼2900 m average depth)). Finally, we discuss and compare our findings with the results of preceding studies.     

Cloud Formation and the Possible Significance of Charge for Atmospheric Condensation and Ice Nuclei

Cloud formation in the atmosphere is related to the presence of water vapour, cloud condensation nuclei (CCN) and ice nuclei (IN). Ionisation in the atmosphere is caused by a variety of sources, but the contribution from cosmic rays is always present and is modulated by the solar cycle. Methods of investigating the variability in ionisation are described. The mechanisms proposed by which (1) ionisation could influence cloud formation, and (2) by which changes to the CCN and IN could occur are discussed. Direct formation of sulphate CN is conceivable in atmospheric air by radioactivity, and charging of molecular clusters leads to greater collisions rates than for neutral clusters. Modification of the ice nucleation efficiency of aerosol could also have atmospheric effects through latent heat release. However in both cases definitive atmospheric experimental work is lacking and therefore any link between solar variability and clouds remains unproven.     

Theoretical models of ionospheric storms

Summary Precipitations of soft particles at the polar region will enhance the electron density in the oval shaped region surrounding the pole and their effects are marked at winter night.Reduction in the electron density in the sunlit polar region and at the trough may be caused by polar atmospheric heating through two processes; one is the increased chemical reaction coefficients controlling the loss rate of electron density and the other is the decrease in atmospheric density ratio O/N₂ near the turbopause caused by enhanced mixing by atmospheric gravity waves or by convective motion of the upper atmosphere.Positive disturbances of the ionosphere appearing in the evening or around noon at mid-latitudes on the storm developing stage, may be caused by equatorward meridional wind arising from a pressure gradient in the upper atmosphere, though the effects of electric fields cannot be ruled out.The Dst part of ionospheric storms persisting over several days may be caused by changes in atmospheric composition arising from global convective motion of the upper atmosphere.Equatorial ionospheric storms are probably caused by changes in east-west electric fields in the equatorial ionosphere arising probably from disturbance electric currents flowing at the polar region.     

Isotopic Composition of H,HE and NE in the Protosolar Cloud

Observations and measurements in the solar wind, the Jovian atmosphere and the gases trapped in lunar surface material provide the main evidence from which the isotopic composition of H, He and Ne in the Protosolar Cloud (PSC) is derived. These measurements and observations are reviewed and the corrections are discussed that are needed for obtaining from them the PSC isotopic ratios. The D/H, ³He/⁴He (D+³He)/H, ²⁰Ne/²²Ne and ²¹Ne/²²Ne ratios adopted for the PSC are presented. Protosolar abundances provide the basis for the interpretation of isotopic ratios measured in the various solar system objects. In this article we discuss constraints derived from the PSC abundances on solar mixing, the origin of atmospheric neon, and the nature of the “SEP” component of neon trapped at the lunar surface. We also discuss constraints on the galactic evolution provided by the isotopic abundances of H and He in the PSC. This revised version was published online in August 2006 with corrections to the Cover Date.     

Solar Forcing of Climate. 2: Evidence from the Past

The nature of the climatic response to solar forcing and its geographical coherence is reviewed. This information is of direct relevance for evaluating solar forcing mechanisms and validating climate models. Interpretation of Sun-climate relationships is hampered by difficulties in (1) translating proxy records into quantitative climate parameters (2) obtaining accurate age assessments (3) elucidating spatial patterns and relationships (4) separating solar forcing from other forcing mechanisms (5) lacking physical understanding of the solar forcing mechanisms. This often limits assessment of past solar forcing of climate to identification of correlations between environmental change and solar variability. The noisy character and often insufficient temporal resolution of proxy records often exclude the detection of high frequency decadal and bi-decadal cycles. However, on multi-decadal and longer time scales, notably the ∼90 years Gleisberg, and ∼200 years Suess cycles in the ¹⁰Be and ¹⁴C proxy records of solar activity are also well presented in the environmental proxy records. The additional ∼1500 years Bond cycle may result from interference between centennial-band solar cycles. Proxy evidence for Sun-climate relations is hardly present for Africa, South America and the marine realm; probably more due to a lack of information than a lack of response to solar forcing. At low latitudes, equatorward movement of the ITCZ (upward component of the Hadley cell) occurs upon a decrease in solar activity, explaining humidity changes for (1) Mesoamerica and adjacent North and South American regions and (2) East Africa and the Indian and Chinese Monsoon systems. At middle latitudes equatorward movement of the zonal circulation during solar minima probably (co-)induces wet and cool episodes in Western Europe, and Terra del Fuego as well as humidity changes in Southern Africa, Australia, New Zealand and the Mediterranean. The polar regions seem to expand during solar minima which, at least for the northern hemisphere is evident in southward extension of the Atlantic ice cover. The forcing-induced migration of climate regimes implies that solar forcing induces a non linear response at a given location. This complicates the assessment of Sun-climate relations and calls for nonlinear analysis of multiple long and high resolution records at regional scale. Unfortunately nonlinear Sun-climate analysis is still a largely barren field, despite the fact that major global climate configurations (e.g. the ENSO and AO) follow nonlinear dynamics. The strength of solar forcing relative to other forcings (e.g. volcanism, ocean circulation patterns, tides, and geomagnetism) is another source of dynamic responses. Notably the climatic effects of tides and geomagnetism are hitherto largely enigmatic. Few but well-dated studies suggest almost instantaneous, climatic deteriorations in response to rapid decreases in solar activity. Such early responses put severe limits to the solar forcing mechanisms and the extent of this phenomenon should be a key issue for future Sun-climate studies.     

Helium in the terrestrial atmosphere

After a brief historical review of the discovery of helium in the terrestrial atmosphere, the production mechanisms of the isotopes He⁴ and He³ are discussed. Although the radioactive production of He⁴ in the Earth is well understood, some uncertainty still exists for the degassing process leading to an atmospheric influx of (2.5 ±1.5) × 10⁶ atoms cm^–2 s^–1. Different production mechanisms are possible for He³ leading to an influx of (7.5±2.5) atoms cm^–2 s^–1. Observations of helium in the thermosphere show a great variability of this constituent. The different mechanisms proposed to explain the presence of the winter helium bulge are discussed. Since helium ions are present in the topside ionosphere and in the magnetosphere, ionization mechanisms are analyzed. Owing to possible variations and uncertainties in the solar UV flux, the photoionization coefficient is (8±4) × 10^–8 s^–1. Finally, the helium balance between production in the earth and loss into the interplanetary space is discussed with respect to the different processes which can play an effective role.     

The Middle Atmospheric Ozone Response to the 11-Year Solar Cycle

Because of its chemical and radiative properties, atmospheric ozone constitutes a key element of the Earth’s climate system. Absorption of sunlight by ozone in the ultraviolet wavelength range is responsible for stratospheric heating, and determines the temperature structure of the middle atmosphere. Changes in middle atmospheric ozone concentrations result in an altered radiative input to the troposphere and to the Earth’s surface, with implications on the energy balance and the chemical composition of the lower atmosphere. Although a wide range of ground- and satellite-based measurements of its integrated content and of its vertical distribution have been performed since several decades, a number of uncertainties still remain as to the response of middle atmospheric ozone to changes in solar irradiance over decadal time scales. This paper presents an overview of achieved findings, including a discussion of commonly applied data analysis methods and of their implication for the obtained results. We suggest that because it does not imply least-squares fitting of prescribed periodic or proxy data functions into the considered times series, time-domain analysis provides a more reliable method than multiple regression analysis for extracting decadal-scale signals from observational ozone datasets. Applied to decadal ground-based observations, time-domain analysis indicates an average middle atmospheric ozone increase of the order of 2% from solar minimum to solar maximum, which is in reasonable agreement with model results.     

The Changing Face of Titan’s Haze: Is it all Dynamics?

Titan’ atmosphere shows some similarities with that of the Earth, in terms of composition and surface pressure. Also, its seasonal cycle is similar, as Titan’ obliquity is about 27^°(23^°,5 for the Earth), although it is about 30 times as long. Titan’ haze exhibits an albedo contrast (NSA for North-South Asymmetry) that is changing seasonally. From the analysis of Voyager and Hubble Space Telescope data, we learned that at short visible wavelengths, the albedo of the winter hemisphere is lower by 10-20% than that of the summer hemisphere. This asymmetry peaks at 450 nm and reaches maximum amplitude around Titan’ equinoxes. It reverses in about five years, faster than a season which spans seven years. At longer wavelengths, longward of 700 nm, the asymmetry is inverted. The NSA reversal process in the red and in the UV seems to lead the reversal in the blue by 1 or 2 years. No valid explanation exists for this lag, at least in the red. The results from a recent model which couples atmospheric dynamics, haze microphysics and transport, as well as photochemistry, show that the NSA and its seasonal changes can be explained by an accumulation of haze particles at the winter pole. This is due to the pole-to-pole Hadley circulation pattern that is present during most of Titan’ year and rapidly disrupts at the time of the equinoxes. This model can also explain the observed cooler stratospheric temperatures and higher abundances of heavy hydrocarbons and nitriles in the winter polar region. In addition, it provides a mechanism for the formation of a detached haze layer around 300–400 km altitude, as well as the existence of a polar hood. Thus, it appears that the latitudinal contrasts we observe on Titan are conveniently tracing for us the dynamical behavior of its atmosphere.     

Energy Deposition in Planetary Atmospheres by Charged Particles and Solar Photons

We discuss here the energy deposition of solar FUV, EUV and X-ray photons, energetic auroral particles, and pickup ions. Photons and the photoelectrons that they produce may interact with thermospheric neutral species producing dissociation, ionization, excitation, and heating. The interaction of X-rays or keV electrons with atmospheric neutrals may produce core-ionized species, which may decay by the production of characteristic X-rays or Auger electrons. Energetic particles may precipitate into the atmosphere, and their collisions with atmospheric particles also produce ionization, excitation, and heating, and auroral emissions. Auroral energetic particles, like photoelectrons, interact with the atmospheric species through discrete collisions that produce ionization, excitation, and heating of the ambient electron population. Auroral particles are, however, not restricted to the sunlit regions. They originate outside the atmosphere and are more energetic than photoelectrons, especially at magnetized planets. The spectroscopic analysis of auroral emissions is discussed here, along with its relevance to precipitating particle diagnostics. Atmospheres can also be modified by the energy deposited by the incident pickup ions with energies of eV’s to MeV’s; these particles may be of solar wind origin, or from a magnetospheric plasma. When the modeling of the energy deposition of the plasma is calculated, the subsequent modeling of the atmospheric processes, such as chemistry, emission, and the fate of hot recoil particles produced is roughly independent of the exciting radiation. However, calculating the spatial distribution of the energy deposition versus depth into the atmosphere produced by an incident plasma is much more complex than is the calculation of the solar excitation profile. Here, the nature of the energy deposition processes by the incident plasma are described as is the fate of the hot recoil particles produced by exothermic chemistry and by knock-on collisions by the incident ions.