The N4,5 - OO Auger and “N3” N4,5O2,3 Coster-Kronig spectra of xenon induced by electron impact

The N_4,5OO Auger electron spectrum in the kinetic energy region (14–37) eV has been measured with high resolution at electron incident energies between 71 eV and 2019 eV. The Auger and satellite lines are assigned by comparison with previous literature data. Several states which correspond to the resonant Auger transitions from the 4d_{3/2, 5/2} 6p states are observed. The PCI effects on the N₅-O_2,3O_2,3(¹S₀) Auger peak when the incident electron energy approaches to the N₅ edge (67.55 eV) is investigated and it is found that the dependence of the energy shift on the excess energy, E_exc, is well represented by the function E_exc^β with β = (-1.40 ± 0.05). The ^“N₃^” N_4,5O_2,3 Coster-Kronig spectrum is measured at various electron incident energies. The assignments of the features are made in comparison with a similar spectrum from synchrotron radiation measured by Kivimäki et al. J. Electron Spectrosc. Relat. Phenom. 1999, 101–103, 43–47]. The Auger spectrum in the kinetic energy regions (68–78) eV and (90–138) eV is observed for the first time in an electron impact experiment and a comparison is made with the photoionization experiment by Hikosaka et al. Phys. Rev. A 2007, 76, 032708].