| 高氯酸铵与HMX和RDX的相互作用 |
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| 引用本文： | 刘子如,阴翠梅,孔扬辉,赵凤起,罗阳,周琥.高氯酸铵与HMX和RDX的相互作用[J].推进技术,2000,21(6):70-73. |
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| 作者姓名： | 刘子如 阴翠梅 孔扬辉 赵凤起 罗阳 周琥 |
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| 作者单位： | 1. 西安近代化学研究所,陕西,西安,710065
2. 华中理工大学,煤燃烧国家实验室,湖北,武汉,430074 |
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| 摘 要： | 用热重－微商热重分析（ＴＧ－ＤＴＧ）、高压差示扫描量热仪ＰＤＳＣ和差热分析－热重分析－傅立叶红外联用技术（ＤＴＡ－ＴＧＡ－ＦＴＩＲ），研究了高氯酸铵（ＡＰ）与ＨＭＸ和ＲＤＸ的互相作用。热分析和分解气体原位实时红外跟踪分析的结果表明，ＡＰ与ＨＭＸ和ＲＤＸ之间存在着强烈的作用。提高压力使ＡＰ对ＨＭＸ的加速分解作用减弱，而地ＡＰ分解作用增强。从它们的分解机理解释了这些结果。
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| 关 键 词： | 高氯酸铵 硝胺 热分析 复合固体推进剂 RDX HMX |
Interaction of ammonium perchlorate with HMX and RDX during decomposition |
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| Liu Ziru,Yin Cuimei,Kong Yanghui,Zhao Fengqi,Luo Yang and Zhou Hu.Interaction of ammonium perchlorate with HMX and RDX during decomposition[J].Journal of Propulsion Technology,2000,21(6):70-73. |
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| Authors: | Liu Ziru Yin Cuimei Kong Yanghui Zhao Fengqi Luo Yang and Zhou Hu |
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| Abstract: | The TG-DTG, PDSC and DTA-TGA-FTIR coupling were used to an investigation of the interactions of AP with HMX and RDX The results show that there is a strong interreaction of AP with HMX and RDX during thermal decompositions HMX decomposition accelerated by AP is weakened while the AP decomposition accelerated by HMX is boosted up as pressure increases These results are interpreted by the mechanism of their decomposition |
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| Keywords: | Ammoniun perchlorate Nitramine Thermal decomposition Thermal analysis Infrared techniq? |
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