| 复杂固态反应动力学的热分析研究 |
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| 引用本文： | 杜廷发.复杂固态反应动力学的热分析研究[J].推进技术,1990,11(1):62-66,84. |
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| 作者姓名： | 杜廷发 |
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| 作者单位： | 国防科技大学 |
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| 摘 要： | 本文从独立平行反应和竞争反应两种模型出发,对TG和DSC研究复杂固态反应动力学作了分析.指出了不能用等转化率一类多升温速率法求取动力学参数的情况及其主要原因.
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| 关 键 词： | 固体推进剂 热分析 固态反应动力学 |
THERMAL ANALYSIS ON KINETICS OF COMPLEX SOLID STATE REACTIONS |
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| Du Tingfa.THERMAL ANALYSIS ON KINETICS OF COMPLEX SOLID STATE REACTIONS[J].Journal of Propulsion Technology,1990,11(1):62-66,84. |
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| Authors: | Du Tingfa |
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| Institution: | National University of Defence Technology |
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| Abstract: | In this paper, the composite reaction kinetics of complex solid state reactions, based on both models of the mutually individual reaction and the competitive reaction are discussed by means of TG and DSC.The cases in which the methods such as multiple heating rates and the isoconversion method are inapplicable to estimate the kinetic parameters are pointed out and the reasons for those are also explained. |
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| Keywords: | Solid state Reaction Solid propellant Thermal analysis |
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