| TDE—85/芳香族胺固化体系动力学研究 |
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| 引用本文： | 郑亚萍%宁荣昌%乔生儒.TDE—85/芳香族胺固化体系动力学研究[J].宇航材料工艺,2000,30(4):41-44. |
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| 作者姓名： | 郑亚萍%宁荣昌%乔生儒 |
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| 作者单位： | 西北工业大学化工系 西安 710072 |
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| 摘 要： | 测试了TDE—85/芳香族胺体系在不同升温速率下的DTA曲线，通过Ozawa方程、Kissinger方程计算各体系的活化能，利用Crane方程计算各体系的反应级数。结果表明，DTA曲线均呈单峰，两种计算活化能的方法近似，TDE—85中两种环氧基反应活性近似，各体系反应级数均接近于1级反应。
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| 关 键 词： | 脂环族环氧树脂，活化能，反应级数 |
| 修稿时间： | 1999年11月17 |
A Study on Curing Kinetics of TDE-85/Aromatic Amine |
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| Zheng Yaping,Ning Rongchang,Qiao Shengru.A Study on Curing Kinetics of TDE-85/Aromatic Amine[J].Aerospace Materials & Technology,2000,30(4):41-44. |
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| Authors: | Zheng Yaping Ning Rongchang Qiao Shengru |
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| Abstract: | TDE 85/amine systems are studied by DTA at different heating rates. Activaticn energy is calculated by kissinger and Ozawa methods, and order of reaction is computed by Crane method .It is indicated that both activation energy calculating methods will result in almost the same value, and alomost same curing activation of two functional epoxy groups of TDE 85 resin with near one order of reaction will be considered for studied resin systems in this paper. |
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| Keywords: | Lycloaliphatic epoxy resin Activation energy Order of reaction |
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