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PVC 阻燃酚醛纤维的制备及其性能
引用本文:党江敏,任蕊,刘春玲,董文生.PVC 阻燃酚醛纤维的制备及其性能[J].宇航材料工艺,2011,41(5).
作者姓名:党江敏  任蕊  刘春玲  董文生
作者单位:陕西师范大学应用表面与胶体化学教育部重点实验室,西安,710062
摘    要:以聚氯乙烯(PVC)改性酚醛树脂为原料,采用熔融纺丝法制备出PVC阻燃酚醛纤维.通过SEM、DMA、TG、Fr-IR等分析手段,对PVC阻燃酚醛纤维的结构和性能进行了研究.与纯酚醛纤维相比,PVC阻燃纤维的韧性和阻燃性提高,但其热稳定性和残碳率稍有降低.当PVC含量为0.5wt%时,其拉伸强度从123 MPa提高至150 MPa,极限氧指数从32.1%提高至38.5%,在空气气氛下600℃的残碳率从87.4%降至70.9%,在氮气气氛下1 000℃的残碳率从62.8%降至59.7%.

关 键 词:PVC阻燃酚醛纤维  PVC  阻燃性  热稳定性

Preparation and Properties of PVC Flame Retardant Phenolic Fibers
Dang Jiangmin,Ren Rui,Liu Chunling,Dong Wensheng.Preparation and Properties of PVC Flame Retardant Phenolic Fibers[J].Aerospace Materials & Technology,2011,41(5).
Authors:Dang Jiangmin  Ren Rui  Liu Chunling  Dong Wensheng
Institution:Dang Jiangmin Ren Rui Liu Chunling Dong Wensheng Key Laboratory of Applied Surfaceand Colloid Chemistry(Shaanxi Normal University),Ministry of Education,Xi'an 710062
Abstract:Phenolic fibers modified by PVC(Polyvinyl Chloride) have been prepared by melt-spinning.SEM(Scanning Electron Microscope),DMA(Dynamic Mechanical Analysis),TG(Thermogravimetric Analysis) and FT-IR(Fourier Transform Infrared Spectrometer) were employed to characterize the structure and performance of the PVC flame-retardant phenolic fibers.In comparison the PVC flame-retardant phenolic fibers with the pure phenolic fibers,the addition of 0.5wt% PVC in the precursor resin obviously increases mechanical strengt...
Keywords:PVC flame-retardant phenolic fibers  PVC  Flame resistance  Thermal stability  
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