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难熔金属化合物掺杂对先驱体转化2D C/SiC复合材料抗氧化性能影响
引用本文:王其坤,陈朝辉,胡海峰,张玉娣.难熔金属化合物掺杂对先驱体转化2D C/SiC复合材料抗氧化性能影响[J].航空材料学报,2008,28(5).
作者姓名:王其坤  陈朝辉  胡海峰  张玉娣
作者单位:国防科技大学,航天与材料工程学院,长沙,410073
摘    要:提出在2D C/SiC复合材料基体中掺杂难熔金属化合物ZrB2,TaC,ZrC,制备了2D C/SiC-ZrB2,2D C/SiC-ZrC和2D C/SiC-TaC新型复合材料,考察了难熔金属化合物的引入对材料力学性能、抗氧化性能和微观结构的影响.结果表明,ZrB2和TaC的引入,能明显提高2DC/SiC复合材料的抗氧化性能;ZrC的引入对2D C/SiC复合材料的抗氧化性能极其不利.这归结于高温下ZrB2和TaC有助于在复合材料表层氧化形成ZrO2,B2O3和Ta2O5保护膜,阻止了材料内部的进一步氧化,从而提高了复合材料的抗氧化性能.

关 键 词:先驱体转化  难熔金属化合物  抗氧化性能

Influence of Refractory Compounds Introduction on Oxidation Resistant Performance of 2D C/SiC Composites via Precursor Infiltration and Pyrolysis
WANG Qi-kun,CHEN Zhao-hui,HU Hai-feng,ZHANG Yu-di.Influence of Refractory Compounds Introduction on Oxidation Resistant Performance of 2D C/SiC Composites via Precursor Infiltration and Pyrolysis[J].Journal of Aeronautical Materials,2008,28(5).
Authors:WANG Qi-kun  CHEN Zhao-hui  HU Hai-feng  ZHANG Yu-di
Institution:WANG Qi-kun,CHEN Zhao-hui,HU Hai-feng,ZHANG Yu-di(College of Aerospace , Materials Engineering,National University of Defense Technology,Changsha 410073,China)
Abstract:Three composites of 2D C/SiC-ZrB2(TaC,ZrC) were prepared via introducing of refractory compounds(ZrB2,TaC,ZrC) into 2D C/SiC composites,and the influences upon mechanical,oxidation resistant performance and microstructures of 2D C/SiC composites were investigated.The results showed that the introduction of ZrB2 and TaC significantly increased the oxidation resistance performance of 2D C/SiC,while the introduction of ZrC decreased the oxidation resistance performance.The improved oxidation resistance perform...
Keywords:C/SiC
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