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合金元素Al对Cr-20Nb合金高温抗氧化性能的影响
引用本文:黄毅,鲁世强,郑海忠.合金元素Al对Cr-20Nb合金高温抗氧化性能的影响[J].航空材料学报,2009,29(6):8-12.
作者姓名:黄毅  鲁世强  郑海忠
作者单位:南昌航空大学,材料科学与工程学院,南昌,330063
基金项目:国家自然科学基金,航空科学基金,江西省自然科学基金 
摘    要:采用机械合金化+热压烧结工艺制备了掺杂合金元素Al的Cr-20Nb合金,研究Al对Cr-20Nb合金在1100℃和1200℃下高温抗氧化性的影响。结果表明,合金元素Al能促进Cr-20Nb合金氧化时生成AlNbO4复合型氧化物,该复合型氧化物能有效抑制Cr2O3,的挥发反应,从而改善Cr2O3,氧化层的致密性,并提高氧化膜的粘附性,导致合金抗氧化性显著提高。不同Al含量的Cr-20Nb合金氧化增重均近似于抛物线规律。

关 键 词:Cr-20Nb合金  合金元素A1  高温抗氧化

Effect of Al on High Temperature Oxidation Resistance of Cr-20Nb Alloy
HUANG Yi,LU Shi-qiang,ZHENG Hai-zhong.Effect of Al on High Temperature Oxidation Resistance of Cr-20Nb Alloy[J].Journal of Aeronautical Materials,2009,29(6):8-12.
Authors:HUANG Yi  LU Shi-qiang  ZHENG Hai-zhong
Institution:HUANG Yi,LU Shi-qiang,ZHENG Hai-zhong(Department of Material Science and Engineering,Nanchang Hangkong University,Nanchang 330063,China)
Abstract:The influence of Al on the high temperature oxidation of Cr-20Nb alloys, which were fabricated by mechanical alloy and hot press, has been studied at 1100℃ and 1200℃ in air, respectively. The results indicate that the proper addition of Al promote the formation of AlNbO_4 complex oxide which retard the volatilization of Cr_2O_3 scales. Thus the compactability of Cr_2O_3 scales and the adherence of the oxide scale are improved, which lead to the oxidation resistance remarkably improved. The results also show that the oxidation kinetics of Cr-20Nb alloys with different Al content is similar to parabolic law.
Keywords:Cr-20Nb alloys  Al addition  high temperature oxidation resistance
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