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2D C/SiC-ZrB2复合材料的烧蚀性能
引用本文:童长青,成来飞,刘永胜,张立同.2D C/SiC-ZrB2复合材料的烧蚀性能[J].航空材料学报,2012,32(2):69-74.
作者姓名:童长青  成来飞  刘永胜  张立同
作者单位:1. 龙岩学院化学与材料学院,福建龙岩364000;西北工业大学超高温结构复合材料国防科技重点实验室,西安710072
2. 西北工业大学超高温结构复合材料国防科技重点实验室,西安,710072
基金项目:国家自然科学基金,国家杰出青年科学基金
摘    要:用ZrB2微粉对2D C/SiC基体进行改性,研究了化学气相渗透结合浆料浸渍及先驱体浸渍裂解工艺制备2DC/SiC-ZrB2复合材料在氧-乙炔焰和1800℃甲烷风洞环境中的烧蚀行为.结果表明:在氧-乙炔环境中,2D C/SiC-ZrB2的线烧蚀率和质量烧蚀率分别为6.1×10-2 mm/s和1.0×10 -2g/s,相对2D C/SiC复合材料而言,ZrB2微粉并没有提高C/SiC复合材料的抗烧蚀性能.在1800℃甲烷风洞环境中,涂层致密度起主要作用,涂层致密度相同时,复合材料的开气孔率越大,质量烧蚀率越大,ZrB2微粉的渗入对C/SiC复合材料的烧蚀性能影响不大.

关 键 词:C/SiC-ZrB2复合材料  氧-乙炔焰  甲烷风洞  烧蚀性能

Ablation Properties of 2D C/SiC-ZrB2 Composite
TONG Chang-qing , CHENG Lai-fei , LIU Yong-sheng , ZHANG Li-tong.Ablation Properties of 2D C/SiC-ZrB2 Composite[J].Journal of Aeronautical Materials,2012,32(2):69-74.
Authors:TONG Chang-qing  CHENG Lai-fei  LIU Yong-sheng  ZHANG Li-tong
Institution:1.College of Chemistry & Materials Science,Longyan University,Longyan 364000,Fujian China;2.National Key Laboratory of Thermostructure Composite Materials,Northwestern Polytechnical University,Xi′an 710072,China)
Abstract:2D C/SiC-ZrB2 composite was fabricated by combining chemical vapor infiltration,ZrB2 slurry infiltration and polymer infiltration and pyrolysis method.The ablation properties of the composite under oxyacetylene flame and 1800℃ methane combustion wind tunnel were studied.The results show that under the oxyacetylene flame environment,the linear ablation rate and the mass ablation rate of the 2D C/SiC-ZrB2 are 6.1×10-2mm/s and 1.0×10-2g/s respectively.The anti-ablation performance is improved by infiltrated ZrB2 particles into C/SiC matrix.Under the 1800℃methane combustion wind tunnel,the coating density plays a major role on the ablation behavior.At the same coating density,the mass ablation rate increases with the open porosity of the composites.The addition of ZrB2 to C/SiC has little effect on the anti-ablation performance.
Keywords:C/SiC-ZrB2 composite  oxyacetylene flame  methane combustion wind tunnel  ablation properties
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