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纤维素甘油醚硝酸酯在双基推进剂中的应用
引用本文:袁荃,邵自强,张有德.纤维素甘油醚硝酸酯在双基推进剂中的应用[J].固体火箭技术,2012,35(1):83-87,103.
作者姓名:袁荃  邵自强  张有德
作者单位:1. 太原市塑料研究所,太原,030024
2. 北京理工大学材料科学与工程学院,北京,100081
3. 山西北方兴安化学工业有限公司,太原,030008
摘    要:纤维素甘油醚硝酸酯NGEC是一种改性硝化棉,以NGEC为粘合剂代替NC,采用传统的无溶剂法制备了NGEC基改性双基推进剂。研究了以NGEC为粘合剂的改性双基推进剂的力学、燃烧和弹道性能及燃烧波结构。结果表明,NGEC具有较好的热塑性,NGEC基改性双基推进剂加工性能优良,其低温-40℃延伸率可达相同配方NC基改性双基推进剂的1.5倍以上,其推进剂弹道性能稳定,燃烧性能和燃烧波结构与NC基推进剂相似。因此,NGEC作为含能粘合剂代替NC,可用于改善改性双基推进剂性能的研究。

关 键 词:改性硝化棉  改性双基推进剂  力学性能  燃烧性能  燃烧波结构

Application of nitrate ester of cellulose glycidyl ether in propellant
YUAN Quan , SHAO Zi-qiang , ZHANG You-de.Application of nitrate ester of cellulose glycidyl ether in propellant[J].Journal of Solid Rocket Technology,2012,35(1):83-87,103.
Authors:YUAN Quan  SHAO Zi-qiang  ZHANG You-de
Institution:1.Taiyuan Institute of Plastics,Taiyuan 030024,China; 2.School of Materials Science and Engineering,Beijing Institute of Technology,Beijing 100081,China; 3.Shanxi Northern Xing’an Chemical Industrial Co.,Ltd.,Taiyuan 030008,China)
Abstract:Nitrate ester of cellulose glycidyl ether(NGEC) is one kind of modified nitrocelluloses.The NGEC-modified double-base propellants were prepared by using traditional solvent-free method.The properties of NGEC modified double base propellant including mechanical,combustion,ballistic and combustion wave structure were investigated.The results show that NGEC has good thermoplastic and NGEC modified double base propellant exhibits a better processing property.Compared with NC-based propellant,NGEC modified double base propellant possesses 1.5 times higher elongation at low temperature(-40 ℃),stable ballistic performance and similar combustion properties and combustion waves structure.So,as an energetic thermoplastic binder instead of NC,NGEC can be used in new modified double base propellant research.
Keywords:modified nitrocellulose  the high-solid modified double base propellant  mechanical properties  combustion performance  combustion waves structure
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