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混配型吸热碳氢燃料热裂解及催化裂解
引用本文:咸春雷,方文军,张波,王彬成,林瑞森.混配型吸热碳氢燃料热裂解及催化裂解[J].推进技术,2003,24(2):179-182.
作者姓名:咸春雷  方文军  张波  王彬成  林瑞森
作者单位:浙江大学,化学系,浙江,杭州,310027
基金项目:国家“八六三”基金(863-2-1-1-7)
摘    要:为提高吸热型碳氢燃料的吸热能效,将辅助燃料Y按不同比例与碳氢燃料混合,配制成新的混配型YNNJ—150燃料,利用连续流吸热型碳氢燃料裂解微型反应色谱评价装置,考察了它的热裂解转化率和低碳烯烃的选择性,并在HZSM—5分子筛上进行了催化裂解评价。结果表明混配型YNNJ—150燃料不仅降低了裂解温度,同时提高了燃料裂解的低碳烯烃的选择性,增加了燃料的吸热能力,且混合辅助燃料Y的比例为15%时的混配燃料YcNNJ—150的效果最好。混配型燃料可成为今后研究的一个重要方向。

关 键 词:吸热燃料  烃类燃料  混合燃料  热降解  催化裂解
文章编号:1001-4055(2003)02-0179-04
修稿时间:2002年5月8日

Thermal cracking and catalytic cracking of the mixing endothermic hydrocarbon fuel
XIAN Chun-lei,FANG Wen-jun,ZHANG Bo,WANG Bin-cheng and LIN Rui-sen.Thermal cracking and catalytic cracking of the mixing endothermic hydrocarbon fuel[J].Journal of Propulsion Technology,2003,24(2):179-182.
Authors:XIAN Chun-lei  FANG Wen-jun  ZHANG Bo  WANG Bin-cheng and LIN Rui-sen
Institution:Dept. of Chemistry, Zhejiang Univ. , Hangzhou 310027, China;Dept. of Chemistry, Zhejiang Univ. , Hangzhou 310027, China;Dept. of Chemistry, Zhejiang Univ. , Hangzhou 310027, China;Dept. of Chemistry, Zhejiang Univ. , Hangzhou 310027, China;Dept. of Chemistry, Zhejiang Univ. , Hangzhou 310027, China
Abstract:In order to improve the endothermtic capability of endothermtic hydrocarbon fuels, new YNNJ-150 fuel was prepared by adding Y additive to NNJ-150. Cracking conversion and selectivity of light carbon olefins of mixing endothermic hydrocarbon fuels was investigated by the microreative chromatogram installation. Results show that the mixing YNNJ- 150 not only decreases the temperature of cracking, but also improves the selectivity of light olefins and endothermic capability. Mixing fuel of containing percent 15 Y is best in all different proportions. Cracking performance of mixing fuel on HZSM-5 was further studied. The mixing endothermic hydrocarbon fuels may be the focus of future research.
Keywords:Endothermic fuel  Hydrocarbon fuel  Mixed fuel  Thermal degradation  Catalytic cracking
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