| 棉纤维素闪爆预处理对NC性能影响分析 |
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| 引用本文： | 邵自强,徐坤,王飞俊,王继勋,谌凡更.棉纤维素闪爆预处理对NC性能影响分析[J].推进技术,2002,23(6):525-528. |
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| 作者姓名： | 邵自强 徐坤 王飞俊 王继勋 谌凡更 |
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| 作者单位： | 1. 北京理工大学,材料科学与工程学院,北京,100081
2. 中国科学院广州化学研究所,广东,广州,510650 |
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| 基金项目： | 兵器工业部预研基金资助项目(Y2002—2)，中国科学院广州化学所纤维素重点实验室基金资助项目 |
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| 摘 要： | 采用高压蒸汽闪爆技术对天然棉纤维素进行预改性处理，以硝酸混酸作为硝化剂，对改性后的纤维素进行硝化，并对硝化产物的含氮量，硝酸酯基分布的均匀性以及在有机溶剂中的溶解度进行测试。结果表明：与未经改性处理的纤维素制得的产物相比，利用闪爆改性后的纤维素制得的硝化纤维素含氮量有一定的提高，氮量分布的均匀性有较大程度的提高，但当闪爆压力超过一定的值时，会导致纤维原料发生类酸解和机械降解，对硝化产物溶解度有较大的影响。
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| 关 键 词： | 棉纤维素 闪爆 预处理 影响分析 硝化纤维素 推进剂 |
| 文章编号： | 1001-4055(2002)06-0525-04 |
| 修稿时间： | 2001年12月14 |
Effect of pretreatment of cotton cellulose by steam explosion on properties of nitrocellulose |
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| SHAO Zi-qiang,XU Kun,WANG Fei-jun,WANG Ji-xun and CHEN Fan-gen.Effect of pretreatment of cotton cellulose by steam explosion on properties of nitrocellulose[J].Journal of Propulsion Technology,2002,23(6):525-528. |
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| Authors: | SHAO Zi-qiang XU Kun WANG Fei-jun WANG Ji-xun and CHEN Fan-gen |
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| Institution: | School of Material Science and Engineering, Beijing Inst. of Technology, Beijing 100081 , China;School of Material Science and Engineering, Beijing Inst. of Technology, Beijing 100081 , China;School of Material Science and Engineering, Beijing Inst. of Technology, Beijing 100081 , China;School of Material Science and Engineering, Beijing Inst. of Technology, Beijing 100081 , China;Guangzhou Inst of Chemistry, Academia Sinica, Guangzhou 510650, China |
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| Abstract: | Cotton cellulose was pre-treaded by high-pressure high-temperature steam; the regenerated cellulose after such pre-treatment was nitrified in sulphonitric medium. Analyses on nitrogen content of products, uniformity of nitrate group, and its solubility in organic solvents of nitrocellulose indicate that the nitrogen content of the products after pretreatment was improved than that in the product without such pretreatment, and that the uniformity of the N02 on the NC chains was enhanced. When steam pressure exceeds a certain value, polymerization of cotton cellulose is reduced because of like-acid degradation and machine breaking, which has an significant impact on NC solubility. |
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| Keywords: | Nitration Cellulose Steam explosion+ Nitrogen Homogeneity |
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