| 偶氮呋咱和氧化偶氮呋咱的合成及表征 |
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| 引用本文： | 雷晴,陶永杰,何金选.偶氮呋咱和氧化偶氮呋咱的合成及表征[J].固体火箭技术,2006,29(5):354-357. |
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| 作者姓名： | 雷晴 陶永杰 何金选 |
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| 作者单位： | 中国航天科技集团公司四院四十二所,襄樊,441003 |
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| 摘 要： | 介绍了高能材料二氨基偶氮呋咱(DAAF)、二氨基氧化偶氮呋咱(DAOAF)及二硝基氧化偶氮呋咱(DNOAF)的合成。其中,采用新型氧化剂制备DAAF,得率提高至65.60%。通过DSC-TG、元素分析、IR、1H NMR和MS等方法,对其结构进行了鉴定,并进行了常规的感度测试。感度数据表明,无氢炸药DNOAF的摩擦感度较大,与C-12相当,而DAAF和DAOAF为低感度炸药。
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| 关 键 词： | 含能材料 合成 二氨基呋咱(DAF) 二氨基偶氮呋咱(DAAF) 二氨基氧化偶氮呋咱(DAOAF) 二硝基氧化偶 |
| 文章编号： | 1006-2793（2006）05-0354-04 |
| 收稿时间： | 2005-08-18 |
| 修稿时间： | 2005-10-31 |
Synthesis and characterization of azofurazan and azoxyfurazan |
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| LEI Qing,TAO Yong-jie,HE Jin-xuan.Synthesis and characterization of azofurazan and azoxyfurazan[J].Journal of Solid Rocket Technology,2006,29(5):354-357. |
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| Authors: | LEI Qing TAO Yong-jie HE Jin-xuan |
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| Institution: | The 42nd Institute of the Fourth Academy of CASC, Xiangfan 441003,China |
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| Abstract: | The synthesis of high energy materials(HEMs)such as 3,3'-diamino-4,4'-azofurazan(DAAF),3,3'-diamino-4,4'-azoxyfurazan(DAOAF)and 3,3'-dinitro-4,4'-azoxyfurazan(DNOAF)was introduced,and the productivity of the prepared DAAF by using a new oxidant can reach 65.60%.The product structure was evaluated by DSC-TG elemental analysis,IR,1H NMR and MS methods,moreover the sensitivity were normally measured.The results show that the sensitivity of DNOAF explosive is high,which is equivalent to that of C-12,but DAAF and DAOAF explosive have low sensitivity. |
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| Keywords: | energy material synthesis diaminofurazan(DAF) 3 3'-diamino-4 4'-azofurazan(DAAF) 3 3'-diamino-4 4'-azoxyfurazan(DAOAF) 3 3'-dinitro-4 4'-azoxyfurazan(DNOAF) |
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