| Abstract: | Spherical detonations have been initiated by solid explosive (Tetryl) charges in well-mixed stoicheiometric air mixtures with each of the hydrocarbons, ethane, propane, n-butane, isobutane and ethylene at atmospheric pressure. Prior to initiation, the gases were contained in plastic bags; total gas volume and available path length were up to 1.6 m3 and 2 m, respectively. The detonations were shown to be self-sustained by continuous measurement of detonation velocity using X-band microwave interferometry. Measured detonation velocities were in all cases close to calculated C-J values.In a few experiments close to the limits of detonability, velocity and blast pressure/time records indicated that the propagating wave system is sometimes irregular. The irregularity that occurs just after initiation is characterised by a reaction front velocity very much lower than the constant detonation velocity, but subsequently attaining the latter by an acceleration process. These observations indicate the existence of a dissociated phase in which shock and reaction fronts may no longer be coupled.Because similar experimental conditions were used throughout, it was possible to establish the relative susceptibilities of the various fuel gases to detonation. Comparison is made with the Zeldovich criterion and a detonation kernel theory of Lee. |
