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炭黑填充导电硅橡胶的结构与性能
引用本文:张继华,任灵,王立峰,赵云峰.炭黑填充导电硅橡胶的结构与性能[J].宇航材料工艺,2011,41(2).
作者姓名:张继华  任灵  王立峰  赵云峰
作者单位:航天材料及工艺研究所,北京,100076
摘    要:采用SEM、TGA等表征了炭黑填充导电硅橡胶的性能及结构,并研究其导电机理.结果表明,乙炔炭黑含量对导电硅橡胶的力学性能有明显影响.含量超过45 phr后,其体积电阻率变化不明显,炭黑在橡胶内部形成"球簇"和"簇链"结构,因而炭黑的增多,增加了"导电通路",降低橡胶的体积电阻率;导电硅橡胶的最佳耐热性填充量为50 phr,此时随温度的增加,其拉伸强度下降;在100℃下长期老化后的导电性能下降.

关 键 词:硅橡胶  乙炔炭黑  导电  性能

Structure and Properties of Electric Conducting SiliconRubber Filled With Carbon Black
Zhang Jihua,Ren Ling,Wang Lifeng,Zhao Yunfeng.Structure and Properties of Electric Conducting SiliconRubber Filled With Carbon Black[J].Aerospace Materials & Technology,2011,41(2).
Authors:Zhang Jihua  Ren Ling  Wang Lifeng  Zhao Yunfeng
Institution:Zhang Jihua Ren Ling Wang Lifeng Zhao Yunfeng (Aerospace Research Institute of Material & Processing Technology,Beijing 100076)
Abstract:Electric conducting silicon rubber was prepared by filling acetylene carbon black into the rubber.The structures of the conducting rubbers were characterized by SEM and TGA.Then their conducting mechanism was investigated in detail.The results show that the content of carbon black obviously affects mechanical properties of the conducting silicon rubber.But the change of volume resistivity is not obvious when the carbon black content is beyond 45 phr.The structure of grain/cluster and chain/cluster formed in...
Keywords:Silicon rubber  Acetylene carbon black  Electric conducting  Property  
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