The organic matter of comet Halley as inferred by joint gas phase and solid phase analyses

During encounters with comet Halley, the experiment PICCA onboard GIOTTO measured the gas phase organic ion composition of the coma and the experiment PUMA onboard VEGA-1 measured the dust composition. Joining both results, we obtain a consistent picture of the parent organic matter from which dust and gas is produced. One recognizes a complex unsaturated polycondensate, which splits during coma-formation into the more refractory C=C,C-N-containing dust part, and the more volatile C=C,C-O-containing gas part. The responsible exothermal chemical reactions, which are triggered by the sunlight, may play a major role in the dynamics of coma formation.This paper is a shortened and upgraded version of Krueger, F.R., Korth, A., and Kissel, J.: 1989, in S. Chang (ed.) Proc. of the ROSETTA Conf., Milpitas CA, January 1989, submitted.