Abstract: | The paper examines the limitations of quasi-steady autoignition theory in providing information needed for the characterization of autoignition temperature fields. Time-dependent autoignition theory is then utilized to examine the autoignition behavior of a reactive system where both wall catalysis and gas phase kinetic rates are significant. It is found that a diverse range of space-time temperature-composition-pressure histories is possible, depending on the system's thermo-kinetic characteristics. |