The basic thermodynamical equations of surface phases

The basic thermodynamical equations for values which characterize the surface (as curvatures, thickness, surface density of extensive value and its fluxes) are derived with real thickness of the surface being taken into consideration. The terms in the equations connect the thickness with the curvature as well as with the fluxes, surface densities and production of extensive properties. The extended thermodynamical fluxes contain terms in which the thickness and curvature of surface are explicitly expressed.