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醇胺类助剂对丁羟推进剂药浆流变性能的影响
引用本文:鲁国林,王北海.醇胺类助剂对丁羟推进剂药浆流变性能的影响[J].推进技术,2000,21(4):77-80.
作者姓名:鲁国林  王北海
作者单位:湖北红星化学研究所,湖北,襄樊,441003
摘    要:采用旋转粘度计研究了助剂三乙醇胺 (TEA) ,三氟化硼 (BF3) ,三乙醇胺三氟化硼络合物 (TEA·BF3)对Al/HTPB ,AP/HTPB和AP/Al/HTPB复合物药浆流变性能的影响。结果表明 ,TEA/Al反应 (BF3存在时 )以及氢键缔合作用使药浆的切应变速率指数n值降低 ,HTPB/BF3相互作用使药浆的稠度系数K值增大 ,两者综合作用使含TEA·BF3的丁羟推进剂药浆在低切变力下的表观粘度急剧增大 ,从而导致药浆的流动和流平性变差

关 键 词:端羟基聚丁二烯推进剂  流变性能  醇胺

Effect of ethanolamine derivative aids on rheological properties of HTPB propellant slurry
Lu Guolin and Wang Beihai.Effect of ethanolamine derivative aids on rheological properties of HTPB propellant slurry[J].Journal of Propulsion Technology,2000,21(4):77-80.
Authors:Lu Guolin and Wang Beihai
Institution:Hubei Red-Star Chemical Inst.,Xiangfan 441003,China;Hubei Red-Star Chemical Inst.,Xiangfan 441003,China
Abstract:The effects of TEA(triethanolamine),BF 3 and TEA·BF 3 complex on rheological properties of Al/HTPB, AP/HTPB, AP/Al/HTPB composites slurry were studied by rotational viscometer.The results show that shear rate exponent n decreases due to the hydrogen bonding effect and TEA-Al reaction in presence of BF 3, and the coefficient K of shear viscosity increases with HTPB-BF 3 interaction,so that the apparent viscosity increase sharply under low shear stress and the flowability and leveling of HTPB propelland slurry is poor.
Keywords:Hydroxyl terminated polybutadiene propellant  Rheological performance  Ethanolamine aids
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