Photochemistry of planetary ionospheres

The basic photochemical processes in the upper atmospheres and ionospheres of the various bodies in our solar system (planets, moons and comets) are similar. However, there are many different factors (e.g. gas composition, energy input, gravity) which control/change the relative importance of these controlling processes. The photo-chemistry of the inner planets is reasonably well understood at this time, thus there is good agreement between model calculations and most of the observational data base. The extremely limited information that we have available on the ionospheres of the outer planets leads to significant uncertainties about some of the controlling processes. Some important questions (e.g. Is the charge exchange process H⁺ + H₂(v≥4) → H₂⁺ + H important? Is water vapor influx from the rings important?) remain unanswered at this time. In cometary atmospheres the freshly evaporated parent molecules are rapidly photodissociated and photoionized, therefore most of the chemical kinetics of cometary ionospheres involve these rapidly moving and highly reactive ions and radicals.