From Titan’s tholins to Titan’s aerosols: Isotopic study and chemical evolution at Titan’s surface

In the present work, we focused on the possible isotopic fractionation of carbon during the processes involved in the formation of Titan’s tholins. We present the first results obtained on the ¹²C/¹³C isotopic ratios measured on Titan’s tholins synthesized in laboratory with cold plasma discharges. Measurements of isotopic ratio ¹²C/¹³C, done both on tholins and on the initial gas mixture (N₂:CH₄ (98:2)) used to produce them, do not show any evident deficit or enrichment in ¹³C relatively to ¹²C in the synthesized tholins, compared to the initial gas mixture. This observation allows to go further in the analyses of the ACP experiment data, including part of the Cassini–Huygens mission.