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两种新型含铜催化剂对RDX/AP催化热分解的研究
引用本文:陈力,龚华,刘训恩,唐松青,田德余,朱慧,曾志成,徐文英.两种新型含铜催化剂对RDX/AP催化热分解的研究[J].推进技术,1995,16(5):82-85.
作者姓名:陈力  龚华  刘训恩  唐松青  田德余  朱慧  曾志成  徐文英
作者单位:中国科学院上海有机化学研究所,国防科技大学材料科学与应用化学系
摘    要:通过热分解试验,系统地研究了两种新型含铜催化剂对RDX,AP,RDX/AP的催化作用,由热分析图谱及动力学计算结果可以看出:YB对AP,QC对RDX及YB+QC对RDX/AP的热分解有明显的催化作用,其推进剂的燃速测定结果也进一步证明其催化效果。

关 键 词:燃烧催化剂  热分解  催化  硝胺推进剂  固体推进剂

A RESEARCH ON CATALYTIC THERMAL DECOMPOSITION OF RDX/AP BY TWO COPPER-CONTAINING CATALYSTS
Chen Li,Gong Hu,Liu Xunen,Tang Songqing,Tian Deyu,Zhu Hui,Zeng Zhicheng and Xu Wengying.A RESEARCH ON CATALYTIC THERMAL DECOMPOSITION OF RDX/AP BY TWO COPPER-CONTAINING CATALYSTS[J].Journal of Propulsion Technology,1995,16(5):82-85.
Authors:Chen Li  Gong Hu  Liu Xunen  Tang Songqing  Tian Deyu  Zhu Hui  Zeng Zhicheng and Xu Wengying
Institution:Shanghai Inst.of Organic Chemistry,Chinese Academy of Sciences, Shanghai. 200032;Shanghai Inst.of Organic Chemistry,Chinese Academy of Sciences, Shanghai. 200032;Shanghai Inst.of Organic Chemistry,Chinese Academy of Sciences, Shanghai. 200032;Shanghai Inst.of Organic Chemistry,Chinese Academy of Sciences, Shanghai. 200032;Depart. of Material Science and Applied Chemistry,National Univ. of Defense Techno;Depart. of Material Science and Applied Chemistry,National Univ. of Defense Techno;Depart. of Material Science and Applied Chemistry,National Univ. of Defense Techno;Depart. of Material Science and Applied Chemistry,National Univ. of Defense Techno
Abstract:This paper describes the catalytic effect of two copper-containing catalysts on the thermal decomposition of RDX, AP and RDX/AP. The thermal analysis figures and the dynamic computation show that YB, QC and YB QC have obviously catalytic effects on AP, RDX and RDX/AP respectively. The burning rates of propellants containing YB, QC and YB QC respectively also show their catalytic effects.
Keywords:Combustion Catalyst  Thermal Decomposition  Catalysis  Nitramine Propellant
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