Vertical profiles of halocarbons in the stratosphere

Stratospheric air samples collected between 10 and 35 km altitude my means of a cryogenic sampler were analyzed by gaschromatography. Thus vertical profiles of source gases for halogen radicals were derived, such as CCl₄, CCl₃F, CCl₂F₂, CClF₃, CF₄, C₂F₃Cl₃, C₂F₄Cl₂, C₂F₅Cl, C₂F₆, CH₃Cl, CH₃CCl₃, CHF₂Cl, CH₃Br, CBrF₃, and CBrCl₂F. Systematic discrepancies between measured and modelled halocarbon profiles point to deficiencies of present one- and two-dimensional models. Measurements of fully halogenated hydrocarbons provide a tool for systematically studying these deficiencies and thus improving the models.