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POLYMERIZATION PROCESSES OF EPOXY PLASTIC IN SIMULATED FREE SPACE CONDITIONS
Institution:1. Institute of Technical Chemistry, RAS, 13, Lenin Str., 614000 Perm, Russia;2. Institute of Continuous Media Mechanics, RAS, Perm, Russia;3. Perm State University, Perm, Russia;1. Department of Biomedical Sciences, University of Antwerp, Universiteitsplein 1, Antwerp 2610, Belgium;2. Department of Medicine/Physiology, University of Fribourg, Chemin du Musée 5, CH 1700 Fribourg, Switzerland;1. BGN Jamsil Lotte Tower Eye Clinic, Seoul, Republic of Korea;2. Department of Ophthalmology, Korea University Ansan Hospital, Gyeonggi-do, Republic of Korea;3. Department of Ophthalmology, Korea University College of Medicine, Seoul, Republic of Korea;1. Department of Biochemistry, Maria Curie-Sklodowska University, Akademicka 19, 20-031 Lublin, Poland;2. Department of Biotechnology, Chemistry and Pharmacy, University of Siena, Via A. Moro 2, 53100 Siena, Italy;1. Departamento de Biocatálisis, Instituto de Catálisis-CSIC, Campus UAM-CSIC Madrid, Spain;2. Food Biotechnology Division, Biotechnology Research Center (CRBt), Algeria;3. Agrobiotechnology and Nutrition in Semi-Arid Zones Laboratory, Ibn Khalboun University, Algeria
Abstract:This paper presents the results of laboratory modeling of polymerization under the action of free-space factors. The relationships between temperature and stoichiometric ratios were obtained for different sublimation parameters of the reaction mixture components and rates of matrix polymerization. It was shown that there exists an optimal relation between the rates of polymerization and sublimation of low-molecular mixture components. The possibility of using low-molecular components with high sublimation rates under certain conditions of reaction development was experimentally verified.Two options for triggering the reaction have been tested—raising the temperature to the value at which polymerization begins and by means of sunlight photoinitiation (ultraviolet spectrum). It was shown that both variants can be used in the conditions of free space.
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