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TiAlB合金中初生TiB2的形貌及其形成机理
引用本文:张虎,高文理,张二林,曾松岩.TiAlB合金中初生TiB2的形貌及其形成机理[J].北京航空航天大学学报,2002,28(5):540-542.
作者姓名:张虎  高文理  张二林  曾松岩
作者单位:1. 北京航空航天大学,材料科学与工程系;2. 哈尔滨工业大学,材料科学与工程学院
摘    要:用原位自生法制备了Ti-53Al-xB合金,并用X射线衍射仪、扫描电镜对合金的相组成和微观组织进行了研究.结果表明:该合金主要由TiAl和TiB2两相组成;初生TiB2呈六面棱柱状,在TiAlB合金凝固过程中,Al原子富集在初生TiB2固-液界面前沿,导致固-液界面上B原子过饱和度不均匀性增加,使固-液界面变得不稳定, 从而在TiB2(0001)面上产生凸台或柱棒状分枝;分枝的各晶面取向与母体的取向一致,在初生TiB2(0001)面的凸台状或柱棒状分枝上能观察到清晰的台阶.

关 键 词:钛合金  金属基复合材料  硼化物  晶体生长
文章编号:1001-5965(2002)05-0540-03
收稿时间:2001-01-15
修稿时间:2001年1月15日

Morphology and Formation Mechanism of Primary TiB2 in TiAlB Alloys
ZHANG Hu,GAO Wen-li,ZHANG Er-lin,ZENG Song-yan.Morphology and Formation Mechanism of Primary TiB2 in TiAlB Alloys[J].Journal of Beijing University of Aeronautics and Astronautics,2002,28(5):540-542.
Authors:ZHANG Hu  GAO Wen-li  ZHANG Er-lin  ZENG Song-yan
Institution:1. Beijing University of Aeronautics and Astronautics, Dept. of Materials Science and Engineering;
2. Harbin Institute of Technology, School of Materials Science and Engineering
Abstract:Microstructure and phase constitution of Ti 53Al x B alloys produced by an in situ growing method were investigated by X ray diffraction and scanning electron microscope respectively. The results show that these alloys are composed of TiAl and TiB 2 phase, while the primary hexagonal prism TiB 2 exhibits pyramidal protrusion or rod shape dendrites on its basal facets. The protrusions or rods exhibit facets which parallel to that of the primary TiB 2. The solid liquid interface stability of primary TiB 2 was discussed and the formation mechanism of the morphology of primary TiB 2 was investigated.
Keywords:titanium alloys  metallic matrix composites  boride  crystal growth
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