含催化剂RDXCMDB推进剂燃烧机理研究

利用常压ＤＳＣ及ＴＧ／ＤＴＧ，高压ＤＳＣ，单幅照相和燃烧波温度分布测试技术对含ＲＤＸ的复合改性双基推进剂（ＲＤＸＣＭＤＢ）含和不含催化剂时的燃烧机理进行了研究，得到了该种推进剂在热分解和燃烧方面的一些重要结果。     

吸热型碳氢燃料催化裂解热沉测定

报道了一套高温下测量吸热型碳氢燃料催化裂解热沉的稳态热导型流动热量计，仪器常数标定结果线性关系良好，符合Tian’s方程，可以正常工作；测定了500℃和600℃下吸热型碳氢燃料RL7及NNJ-150在SAPO-34分子筛催化剂上的催化裂解热沉，并与相同条件下热裂解热沉相比较，结果表明，吸热型碳氢燃料在SAPO-34分子筛催化剂上发生催化裂解能够比热裂解获得更高的热沉，燃料吸热工作温度可降低100℃。     

两种新型含铜催化剂对RDX／AP催化热分解的研究

通过热分解试验，系统地研究了两种新型含铜催化剂对ＲＤＸ，ＡＰ，ＲＤＸ／ＡＰ的催化作用，由热分析图谱及动力学计算结果可以看出：ＹＢ对ＡＰ，ＱＣ对ＲＤＸ及ＹＢ＋ＱＣ对ＲＤＸ／ＡＰ的热分解有明显的催化作用，其推进剂的燃速测定结果也进一步证明其催化效果。     

Numerical analysis of hypersonic thermochemical non-equilibrium environment for an entry configuration in ionized flow

A theoretical methodology for thermochemical non-equilibrium flow combing with the HLLC (Harten-Lax-van Leer Contact) scheme was applied to study the hypersonic thermochemical non-equilibrium environment of an entry configuration in ionized flow. A two-temperature controlling model was utilized and the Gupta’s 11 species (N₂, O₂, NO, O, N, NO⁺, N₂⁺, O₂⁺, N⁺, O⁺, e^?) thermochemical non-equilibrium model was taken. Firstly, numerical calculations of hypersonic thermochemical non-equilibrium environments for different aerodynamic shapes were carried out to verify the reliability of the method above. Then, the method was used to research the effects of ionization and wall catalysis on the hypersonic thermochemical non-equilibrium environment of the entry configuration in ionized flow. The shock stand-off distance can be reduced by thermochemical reactions but doesn’t continue to decrease significantly when ionization occurs. The shock stand-off distance calculated by the 11 species model is 4.2% smaller than that calculated by the 5 species (N₂, O₂, NO, O, N) thermochemical non-equilibrium model without considering ionization. Ionization reduces wall heat flux but increases wall pressure a little. The effect of ionization on aerothermal loads is greater than that of aerodynamic loads. The thermochemical reactions of electrons and ions catalyzed at the wall increase wall heat flux significantly but make a small change in wall pressure. The maximum wall heat flux obtained by only considering the electrons and ions catalyzed at the partially catalytic wall condition is 11.8% less than that calculated at the super-catalytic wall condition.     

有机硅工业中的铂催化剂研究进展

铂催化硅氢加成反应,广泛用于含Ｓｉ－Ｃ单体的制备及聚合物的交联,本文综述了铂催化剂的组成,表征,抑制剂的作用及铂催化剂催化机理。     

固体超强酸TiO2／SO4^2—催化合成苹果酯—B

使用ＴｉＯ２／ＳＯ４＾－２为催化剂，催化乙酰乙酸乙酯和１，２－丙醇反应合成苹果酯－Ｂ。结果表明：使用该催化剂１．０ｇ，乙酰乙酸乙酯（０．０７７ｍｏｌ）与１，２－丙二醇摩尔比为１：１．２，环已烷１５ｍｌ，反应２．５ｈ，苹果酯－Ｂ产率达７３％。产品经理化检验确认。     

复合固体推进剂中CaCO3作用的实验研究和机理分析

本文通过试件燃烧表面激光阴影高速摄影、燃面扫描电镜分析和X光电子能谱测试结果,提出了CaCO_3与过氯酸铵(AP)的作用机理,解释了CaCO_3对AP的低压(<1.96MPa)增速高压(>1.96MPa)降速的现象.     

过渡金属/稀土金属氧化物纳米粒子催化AP热分解研究

1引言纳米材料由于特殊的表面特性而作为催化剂被广泛地研究。按一定的比例将不同的催化剂进行掺杂混合,有可能获得优于单一催化剂的催化性能。如Cu-Zn纳米催化剂就可替代昂贵的铂或钯催化剂实现对某些有机化合物氢化反应的催化[1]。随着纳米技术的发展,纳米过渡金属氧化物[2](     

吸热型碳氢燃料催化脱氢的研究述评

概述了吸热型碳氢燃料的性能特点和开发应用前景,介绍了其催化脱氢方法,指出了今后的研究方向。     

PDADN-RDX-CMDB推进剂催化燃烧特性研究

采用热分析、微热电偶技术、燃速测试、熄火表面的扫描电镜观测等实验方法，研究了不同类型的复合催化剂对PDADN－RDX－CMDB推进剂燃烧特性的影响。结果发现，邻苯二甲酸铅／雷索辛酸铜／炭黑与雷索辛酸铅铜／炭黑两类复合催化剂可较好地改善PDADN－RDX－CMDB推进剂的燃烧特性，明显降低其压强指数且同时提高燃速，基于实现现象的观测结果分析，提出了“气泡－凝取相反应”理论，解释了该类推进剂在中枢 压区发生的“超速燃烧”现象。